Citation: LI Wei-Bing, BU Yu-Yu, YU Jian-Qiang. Preparation of ZnO/In₂O₃ Composite Hollow Spheres and Their Photoelectrocatalytic Properties to Glucose Degradation[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201207101 shu

Preparation of ZnO/In₂O₃ Composite Hollow Spheres and Their Photoelectrocatalytic Properties to Glucose Degradation

1.
1. Faculty of Environment and Safety, Qingdao University of Science and Technology, Qingdao 266042, China;
2. Key Laboratory of New Fiber Materials and Modern Textile, Qingdao University, Qingdao 266071, Shandong Province, P. R. China

Received Date: 26 March 2012
Available Online: 10 July 2012
Fund Project: 国家自然科学基金(20973097) (20973097)国家重点基础研究发展规划项目(973) (2009CB220000)资助 (973) (2009CB220000)

A series of materials consisting of ZnO/In₂O₃ composite hollow spheres were successfully prepared by a two-step process involving D-glucose-assisted hydrothermal and annealing treatments. X-ray diffraction (XRD) patterns suggested that ZnO semiconductors formed in these materials were amorphous, the annealing temperatures were lower than 500 ℃, however, they converted to a wurtzite structure with higher annealing temperatures. Examination by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) confirmed the hollow sphere morphology of these materials. In addition, the ZnO and In₂O₃ nanoparticles within the spheres were found to interact closely. The photoelectrocatalytic properties of these materials with regard to glucose decomposition were investigated by depositing samples onto indium tin oxide (ITO) glass to fabricate thin-film photoelectrodes. The highest photo-induced degradation current density was observed with the film annealed at 700 ℃. Photoluminescence (PL) spectra clearly showed quenching of the luminescence intensity of these ZnO/ In₂O₃ composite hollow spheres. The p-n junction at the interface between the ZnO and In₂O₃ nanoparticles evidently reduced the recombination of photogenerated electron and holes, enhancing electron transfer to the surface of the photoelectrode.
- ZnO/In₂O₃,
- Composite hollow sphere,
- Photoelectrochemical,
- Catalysis degradation
1. [1]
  
  (1) Shen,W. H.; Zhu, Y. F.; Dong, X. P.; Gu, J. L.; Shi, J. L. Chem. Lett. 2005, 34 (6), 840. doi: 10.1246/cl.2005.840
2. [2]
  (2) Wang, X.; Hu, P.; Yuan, F. L.; Yu, L. J. J. Phys. Chem. C 2007,111 (17), 6706.
3. [3]
  (3) Li, X. L.; Lou, T. J.; Sun, X. M.; Li, Y. D. Inorg. Chem. 2004,43 (17), 5442. doi: 10.1021/ic049522w
4. [4]
  (4) Wu, L. Z.; Zhi, J. F. Acta Phys. -Chim. Sin. 2007, 23, 1173.[吴良专, 只金芳. 物理化学学报, 2007, 23, 1173.] doi: 10.3866/PKU.WHXB20070807
5. [5]
  (5) Salgueirino-Maceira, V.; Spasova, M.; Farle, M. Adv. Funct. Mater. 2005, 15 (6), 1036. doi: 10.1002/adfm.200400469
6. [6]
  (6) Shiho, H.; Kawahashi, N. Colloid & Polymer Science 2000, 278 (3), 270. doi: 10.1007/s003960050043
7. [7]
  (7) Caruso, F.; Spasova, M.; Saigueirino-Maceira, V.; Liz-Marzan,L. M. Adv. Mater. 2001, 13 (14), 1090. doi: 10.1002/1521-4095(200107)13:14<1090::AID-ADMA1090>3.0.CO;2-H
8. [8]
  (8) Kawahashi, N.; Persson, C.; Matijevic, E. J. Mater. Chem. 1991,1 (4), 577. doi: 10.1039/jm9910100577
9. [9]
  (9) Xia, Y. D.; Mokaya, R. J. Mater. Chem. 2005, 15 (30), 3126.doi: 10.1039/b502558c
10. [10]
  (10) Sun, X. M.; Li, Y. D. Angew. Chem. Int. Edit. 2004, 43 (5), 597.doi: 10.1002/anie.200352386
11. [11]
  (11) Yu, S. H.; Cui, X. J.; Li, L. L.; Li, K.; Yu, B.; Antonietti, M.;Colfen, H. Adv. Mater. 2004, 16 (18), 1636. doi: 10.1002/adma.200400522
12. [12]
  (12) Titirici, M. M.; Antonieti, M.; Thomas, A. Chem. Mater. 2006,18, 3808. doi: 10.1021/cm052768u
13. [13]
  (13) Sakthivel, S.; Neppolian, B.; Shankar, M. V.; Arabindoo, B.;Palanichamy, M.; Murugesan, V. Sol. Energy Mater. Sol. Cells2003, 77, 65. doi: 10.1016/S0927-0248(02)00255-6
14. [14]
  (14) Khodja, A. A.; Sehili, T.; Pilichowski, J. F.; Boule, P.J. Photochem. Photobiol. A 2001, 141, 231. doi: 10.1016/S1010-6030(01)00423-3
15. [15]
  (15) Wang, X. Y.; Dong, G. F.; Qiao, J.; Duan, L.;Wang, L. D.; Qiu,Y. Acta Phys. -Chim. Sin. 2010, 26, 2049. [王小燕, 董桂芳,乔娟, 段炼, 王立铎, 邱勇. 物理化学学报, 2010, 26,2049.] doi: 10.3866/PKU.WHXB20100631
16. [16]
  (16) Xiao, L. X.; Duan, L. Q.; Chai, J. Y.;Wang, Y., Chen, Z. J.; Qu,B.; ng, Q. H. Acta Phys. -Chim. Sin. 2011, 27, 749. [肖立新, 段来强, 柴俊一, 王芸, 陈志坚, 曲波, 龚旗煌. 物理化学学报, 2011, 27, 749.] doi: 10.3866/PKU.WHXB20110310
17. [17]
  (17) Wang, Z. Y.; Huang, B. B.; Dai, Y.; Qin, X. Y.;Wang, P.; Liu, H.X.; Yu, J. X. J. Phys. Chem. C 2009, 113, 4612. doi: 10.1021/jp8107683
18. [18]
  (18) Zhang, S. Q.;Wen,W.; Zhang, H. Z.; Zhao, H. J. J. Photochem. Photobiol. A 2009, 208, 97. doi: 10.1016/j.jphotochem.2009.09.001
19. [19]
  (19) Wang, J.; Han, Y. H.; Feng, M. Z.; Chen, J. Z.; Li, X. J.; Zhang,S. Q. J. Mater. Sci. 2011, 46, 416. doi: 10.1007/s10853-010-4863-z
1. [1]
  Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, doi: 10.12461/PKU.DXHX202403060
2. [2]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230293
3. [3]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202407002
4. [4]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, doi: 10.3866/PKU.DXHX202310013
5. [5]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230488
6. [6]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230435
7. [7]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230253
8. [8]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230480
9. [9]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240086
10. [10]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240022
11. [11]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240115
12. [12]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230252
13. [13]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202403005
14. [14]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230398
15. [15]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240170
16. [16]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230421
17. [17]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230349
18. [18]
  Ping Lu , Baoyin Du , Ke Liu , Ze Luo , Abiduweili Sikandaier , Lipeng Diao , Jin Sun , Luhua Jiang , Yukun Zhu . Heterostructured In2O3/In2S3 hollow fibers enable efficient visible-light driven photocatalytic hydrogen production and 5-hydroxymethylfurfural oxidation. Chinese Journal of Structural Chemistry, doi: 10.1016/j.cjsc.2024.100361
19. [19]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202310013
20. [20]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202406027

Get Citation

PDF

XML

Metrics

PDF Downloads(1028)
Abstract views(2105)
HTML views(37)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of ZnO/In2O3 Composite Hollow Spheres and Their Photoelectrocatalytic Properties to Glucose Degradation

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of ZnO/In₂O₃ Composite Hollow Spheres and Their Photoelectrocatalytic Properties to Glucose Degradation