Citation: LU Huai-Qian, SHI Lei, HE Chong, WENG Wei-Zheng, HUANG Chuan-Jing, WAN Hui-Lin. Highly-Dispersed NiO Nanoparticles on SBA-15 for Oxidative Dehydrogenation of Propane to Propylene[J]. Acta Physico-Chimica Sinica, ;2012, 28(11): 2697-2704. doi: 10.3866/PKU.WHXB201207091 shu

Highly-Dispersed NiO Nanoparticles on SBA-15 for Oxidative Dehydrogenation of Propane to Propylene

1.
State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Labo-ratory for Green Chemical Productions of Alcohols, Ethers and Esters, Department of Chem-istry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received Date: 25 May 2012
Available Online: 9 July 2012
Fund Project: 国家重点基础研究发展计划(973) (2010CB732303) (973) (2010CB732303) 国家自然科学基金(21173173, 21073148, 21033006) (21173173, 21073148, 21033006) 教育部创新团队项目(IRT1036) (IRT1036)福建省重大科技专项(2009HZ0002-1)资助项目 (2009HZ0002-1)

A series of NiO/SBA-15 (w_NiO=20%) catalysts were prepared by impregnating SBA-15 with an aqueous solution of nickel nitrate followed by calcining under three different atmospheres. The resulting materials were studied with regard to the oxidative dehydrogenation of propane (ODHP) to propylene. Compared to the catalysts calcined under either static or moving air, the NiO/SBA-15-NO catalyst calcined under flowing 1%NO/He (V_NO/V_He=1:99) atmosphere demonstrated greater activity for this reaction at low temperature. Propylene yield of ~13% with propane conversion of ~29% was obtained at 350 ℃ and the propylene selectivity remained at about 45% even when the reaction temperature was raised to 450 ℃. X-ray diffraction (XRD), transmission electron microscopy (TEM), H₂-temperature program reduction (H₂-TPR), and O₂-temperature program desorption (O₂-TPD) characterizations were used to investigate the intrinsic differences between these NiO/SBA-15 catalysts. It was found that NiO species in the catalyst calcined under 1%NO/He atmosphere were highly dispersed inside the mesopores of SBA-15. With the increasing of NiO dispersion on the support, the quantity of NiO species with a reduction temperature above 450 ℃ increased significantly. In addition, the density of O-species on the catalyst calcined under 1%NO/He was much higher than that in the case of the other two samples. These factors are responsible for the superior performance of the NiO/SBA-15-NO catalyst for the ODHP reaction over the temperature range 350 to 450 ℃.
- NiO/SBA-15,
- Propane,
- Oxidative dehydrogenation,
- Propylene,
- Calcination atmosphere
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