Citation: XIE Ting, LIU Hao-Wen, YANG Han-Min. Control Synthesis of Branched Palladium Nanostructures and the Catalytic Activity on Hydrogenation Reaction of Nitrobenzene[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201207031 shu

Control Synthesis of Branched Palladium Nanostructures and the Catalytic Activity on Hydrogenation Reaction of Nitrobenzene

1.
College of Chemistry and Material Science, South-Central University for Nationalities, Wuhan 430074, P. R. China

Received Date: 15 May 2012
Available Online: 3 July 2012
Fund Project: 中央高校基本科研业务费用专项基金(ZZY10004)资助 (ZZY10004)

Branched palladium nanostructures were synthesized under microwave irradiation using polyvinylpyrrolidone (PVP) as stabilizer and benzyl glycol as the reducing agent of H₂PdCl₄. Morphology and structure were characterized by transmission electron microscopy (TEM), X-ray powder diffraction (XRD), and X-ray photoelectron spectroscopy (XPS), and showed that the branched Pd nanostructures were self-assemblies of hundreds of small spherical nanoparticles. Furthermore, catalytic properties of the branched Pd nanostructures were investigated for the hydrogenation of nitrobenzene, which indicated that the catalytic activity of the branched Pd nanostructures for this reaction is higher than that of a conventional Pd/C catalyst.
- Palladium,
- Nanostructure,
- Microwave irradiation,
- Hydrogenation of nitrobenzene,
- Growth process
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沈阳化工大学材料科学与工程学院沈阳 110142