Citation: AN Ting, CAO Hui-Qun, ZHAO Feng-Qi, REN Xiao-Ning, TIAN De-Yu, XU Si-Yu, GAO Hong-Xu, TAN Yi, XIAO Li-Bai. Preparation and Characterization of Ag/CNTs Nanocomposite and Its Effect on Thermal Decomposition of Cyclotrimethylene Trinitramine[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201206292 shu

Preparation and Characterization of Ag/CNTs Nanocomposite and Its Effect on Thermal Decomposition of Cyclotrimethylene Trinitramine

AN Ting ¹ ,
CAO Hui-Qun ^2, ,
ZHAO Feng-Qi ¹ ,
REN Xiao-Ning ¹ ,
TIAN De-Yu ² ,
XU Si-Yu ¹ ,
GAO Hong-Xu ¹ ,
TAN Yi ¹ ,
XIAO Li-Bai ¹

1.
1. Science and Technology on Combustion and Explosion Laboratory, Xi?an Modern Chemistry Research Institute, Xi?an 710065, P. R. China;
2. Shenzhen Key Laboratory of New Lithium-ion Battery and Mesoporous Materials, College of Chemistry and Chemical Engineering, Shenzhen 518060, Guangdong Province, P. R. China

Received Date: 9 March 2012
Available Online: 29 June 2012
Fund Project: 国家自然科学基金(21173163) (21173163)燃烧与爆炸技术重点实验室基金(9140C3501041001)资助项目 (9140C3501041001)

Two kinds of Ag/CNTs (carbon nanotubes) nanocomposite materials were successfully prepared by silver mirror reaction and hydrothermal methods. Their physical phase, composition, morphology, and structure were characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), transmission electron microscopy (TEM), and scanning electron microscope-energy dispersive spectrometry (SEM-EDS). Catalytic effects of the Ag/CNTs nanocomposite on the thermal decomposition of cyclotrimethylene trinitramine (RDX) were investigated by differential scanning calorimetry (DSC). Our results indicated that the irregularly globose nano-Ag particles attached to the surface of the nano CNTs evenly. The nanocomposite product prepared hydrothermally had the highest loading of nano-Ag particles and largest Ag particle size. Both Ag/CNTs nanocomposites influenced the thermal decomposition of RDX, changing the primary decomposition of the liquid phase to a secondary gas phase reaction and resulting in obvious change in the shape of the main decomposition peak. The catalytic effect of Ag/CNTs nanocomposite on the thermal decomposition of RDX was mainly exhibited at lower decomposition temperature.
- Carbon nanotube,
- Nanocomposite,
- Cyclotrimethylene trinitramine,
- Silver mirror reaction,
- Hydrothermal method,
- Thermal decomposition
1. [1]
  
  (1) Zhu, H.W.;Wu, D. H.; Xu, C. L. Carbon Nanotubes; ChinaMachine Press: Beijing, 2003. [朱宏伟, 吴德海, 徐才录. 碳纳米管. 北京: 机械工业出版社, 2003.]
2. [2]
  (2) An, T.; Zhao, F. Q.; Xiao, L. B. Chin. J. Explos. Propell. 2010,33 (3), 55. [安亭, 赵凤起, 肖立柏. 火炸药学报, 2010, 33 (3), 55.]
3. [3]
  (3) Wang, X. F.; Cai, X. L. Powder Metallurgy Industry 2010, 20 (6), 41. [王晓飞, 蔡晓兰. 粉末冶金工业, 2010, 20 (6), 41.]
4. [4]
  (4) Chen, H. Z.; Zhou, R. J.;Wang, M. In situ Preparation inSolution Method of Carbon Nanotube Complexes Coated with ld Nanoparticles Uniformly. CN Patent 1994625,2007-07-11. [陈红征, 周仁甲, 汪茫. 纳米金粒子均匀包覆的碳纳米管复合物的原位溶液制备方法: 中国, CN1994625[P]. 2007-07-11.]
5. [5]
  (5) Erik, T. T.; Ren, Z. F.; Chou, T.W. Composites Science and Technology 2001, 61 (13), 1899. doi: 10.1016/S0266-3538(01)00094-X
6. [6]
  (6) Hansang, K.; Christopher, R. B.; Marc, L. Advanced Engineering Materials 2011, 13 (4), 325. doi: 10.1002/adem.201000251
7. [7]
  (7) Alba, L. R.; Pamela, K. Weaponization and Characterization of Nanoenergetics; Oxford University Press: Oxford, 2003.
8. [8]
  (8) Miziolek, A.W. The Amptica Newsletter 2002, 6 (1), 43.
9. [9]
  (9) Huang, H.;Wang, Z. S.; Huang, H. J.; Li, J. S. Chin. J. Explos. Propell. 2005, 28 (4), 9. [黄辉, 王泽山, 黄亨建, 李金山.火炸药学报, 2005, 28 (4), 9.]
10. [10]
  (10) Liu, X.; Hong,W. L.; Zhao, F. Q.; Tian, D. Y.; Zhang, J. X.; Li,Q. S. Journal of Solid Rocket Technology 2008, 31 (5), 508.[刘翔, 洪伟良, 赵凤起, 田德余, 张金霞, 李启舜. 固体火箭技术, 2008, 31 (5), 508.]
11. [11]
  (11) Li, C. Y.; Chou, T.W. Journal of Nanoscience and Nanotechnology 2003, 3 (5), 423. doi: 10.1166/jnn.2003.233
12. [12]
  (12) Wang, X. Y.; Zhang, J. C.; Zhu, H. Chinese Journal of Catalysis2011, 32 (1), 74. [王秀瑜, 张敬畅, 朱红. 催化学报, 2011,32 (1), 74.] doi: 10.1016/S1872-2067(10)60163-5
13. [13]
  (13) Lei, Z. X.; Li, X. K.;Wang, H. Z.; Hong, X. Q.; Chen, J.W.New Carbon Materials 2002, 17 (4), 67. [雷中兴, 李轩科, 汪厚植, 洪学勤, 陈家唯. 新型炭材料, 2002, 17 (4), 67.]doi: 10.3321/j.issn:1007-8827.2002.04.014
14. [14]
  (14) Nan, C.W.; Liu, G.; Lin, Y. H.; Li, M. Applied Physics Letters2004, 85 (16), 3549. doi: 10.1063/1.1808874
15. [15]
  (15) Huang, J. H.; Sun, X. G.; Li, J.; Cao, S. Z. Materials Review2008, (1), 109. [黄建华, 孙晓刚, 李静, 曹素芝. 材料导报,2008, (1), 109.]
16. [16]
  (16) Cao, H. Q.;Wei, B.;Wang, Y. Z.; Li, Y. G.; Zhu, M. F. Journal of the Chinese Ceramic Society 2009, 37 (10), 1772. [曹慧群,魏波, 王银治, 李耀刚, 朱美芳. 硅酸盐学报, 2009, 37 (10),1772.] doi: 10.3321/j.issn:0454-5648.2009.10.034
17. [17]
  (17) Wu, Y. C.; Liu, X. L.; Ye, M.; Xie, T.; Huang, X. M. Acta Phys. -Chim. Sin. 2008, 24, 97. [吴玉程, 刘晓璐, 叶敏,解挺, 黄新民. 物理化学学报, 2008, 24, 97.] doi: 10.3866/PKU.WHXB20080117
18. [18]
  (18) Zhou, L. M.; Hou, L. Q.; Liu, H. Y.; Li, F. S. Acta Chim. Sin.2006, 64 (15), 1548. [周龙梅, 侯立权, 刘宏英, 李凤生. 化学学报, 2006, 64 (15), 1548.]
19. [19]
  (19) Jiang,W.; Liu, J. X.; Liu, Y.; Cui, P.; Li, F. S. Journal of Solid Rocket Technology 2008, 31 (1), 65. [姜炜, 刘建勋, 刘永, 崔平, 李凤生. 固体火箭技术, 2008, 31 (1), 65.]
20. [20]
  (20) Hong,W. L.; Zhu, X. Y.; Zhao, F. Q.; Yi, J. H.; Gao, H. X.; Tian,D. Y. Chin. J. Explos. Propell. 2010, 33 (6), 83. [洪伟良, 朱秀英, 赵凤起, 仪建华, 高红旭, 田德余. 火炸药学报, 2010, 33 (6), 83.]
21. [21]
  (21) Zhang, J. X.; Hong,W. L.; Zhao, F. Q.; Liu, J. H.; Tian, D. Y.;Zhu, X. Y.; Ma, Y. Q. Chin. J. Explos. Propell. 2011, 34 (2), 47.[张金霞, 洪伟良, 赵凤起, 刘剑洪, 田德余, 朱秀英, 马永强. 火炸药学报, 2011, 34 (2), 47.]
22. [22]
  (22) Liu, Z. R. Thermal Analyses for Energetic Materials; NationalDefence Industry Press: Beijing, 2008. [刘子如. 含能材料热分析. 北京: 国防工业出版社, 2008.]
23. [23]
  (23) Hu, R. Z.; Gao, S. L.; Zhao, F. Q.; Shi, Q. Z.; Zhang, T. L.;Zhang, J. J. Thermal Analysis Kinetics, 2nd ed.; Science Press:Beijing, 2008. [胡荣祖, 高胜利, 赵凤起, 史启祯, 张同来,张建军. 热分析动力学(第二版). 北京: 科学出版社, 2008]
24. [24]
  (24) An, T.; Zhao, F. Q.; Yi, J. H.; Fan, X. Z.; Gao, H. X.; Hao, H.X.;Wang, X. H.; Hu, R. Z.; Pei, Q. Acta Phys. -Chim. Sin. 2011,27, 281. [安亭, 赵凤起, 仪建华, 樊学忠, 高红旭, 郝海霞,王晓红, 胡荣祖, 裴庆. 物理化学学报, 2011, 27, 281.] doi: 10.3866/PKU.WHXB20110213
25. [25]
  (25) Chang, J. H.; Dong, Q. G. Principle and Analysis of Spectroscopy, 2nd ed.; Science Press: Beijing, 2005. [常建华,董绮功. 波谱原理及解析(第二版). 北京: 科学出版社, 2005.]
26. [26]
  (26) Fukushima, T.; Kosaka, A.; Ishimura, Y.; Yamamoto, T.;Takigawa, T.; Ishii, N.; Aida, T. Science 2003, 300, 2072.
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230402
2. [2]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240067
3. [3]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, doi: 10.12461/PKU.DXHX202405100
4. [4]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, doi: 10.3866/PKU.DXHX202308025
5. [5]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230312
6. [6]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, doi: 10.3866/PKU.DXHX202311033
7. [7]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240216
8. [8]
  Yang Lv , Yingping Jia , Yanhua Li , Hexiang Zhong , Xinping Wang . Integrating the Ideological Elements with the “Chemical Reaction Heat” Teaching. University Chemistry, doi: 10.12461/PKU.DXHX202402059
9. [9]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230459
10. [10]
  Hui Shi , Shuangyan Huan , Yuzhi Wang . Ideological and Political Design of Potassium Permanganate Oxidation-Reduction Titration Experiment. University Chemistry, doi: 10.3866/PKU.DXHX202308042
11. [11]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, doi: 10.3866/PKU.DXHX202308049
12. [12]
  Feng Liang , Desheng Li , Yuting Jiang , Jiaxin Dong , Dongcheng Liu , Xingcan Shen . Method Exploration and Instrument Innovation for the Experiment of Colloid ζ Potential Measurement by Electrophoresis. University Chemistry, doi: 10.3866/PKU.DXHX202312009
13. [13]
  Wei Peng , Baoying Wen , Huamin Li , Yiru Wang , Jianfeng Li . Exploration and Practice on Raman Scattering Spectroscopy Experimental Teaching. University Chemistry, doi: 10.3866/PKU.DXHX202312062
14. [14]
  Yujia Luo , Yunpeng Qi , Huiping Xing , Yuhu Li . The Use of Viscosity Method for Predicting the Life Expectancy of Xuan Paper-based Heritage Objects. University Chemistry, doi: 10.3866/PKU.DXHX202401037
15. [15]
  Tiejun Su . The Construction and Application of the Calculation Formula for Endpoint Error in Precipitation Titration: A Case Study of the Mohr Method. University Chemistry, doi: 10.12461/PKU.DXHX202402039
16. [16]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, doi: 10.12461/PKU.DXHX202404023
17. [17]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240036
18. [18]
  Bingliang Li , Yuying Han , Dianyang Li , Dandan Liu , Wenbin Shang . One-Step Synthesis of Benorilate Guided by Green Chemistry Principles and in vivo Dynamic Evaluation. University Chemistry, doi: 10.3866/PKU.DXHX202311070
19. [19]
  Mengyao Shi , Kangle Su , Qingming Lu , Bin Zhang , Xiaowen Xu . Determination of Potassium Content in Tobacco Stem Ash by Flame Atomic Absorption Spectroscopy. University Chemistry, doi: 10.12461/PKU.DXHX202404105
20. [20]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, doi: 10.3866/PKU.DXHX202312016

Get Citation

PDF

XML

Metrics

PDF Downloads(828)
Abstract views(2464)
HTML views(30)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142