Citation: WANG Xian-Zhong, KANG Wan-Li, MENG Xiang-Can, FAN Hai-Ming, XU Hai, HUANG Jing-Wei, FU Jian-Bin, ZHANG Yi-Nuo. Ultra-Low Interfacial Tension in High Salinity Reservoir Driven by Synergistic Interaction of Zwitterionic and Anionic Surfactants[J]. Acta Physico-Chimica Sinica, ;2012, 28(10): 2285-2290. doi: 10.3866/PKU.WHXB201206291 shu

Ultra-Low Interfacial Tension in High Salinity Reservoir Driven by Synergistic Interaction of Zwitterionic and Anionic Surfactants

1.
College of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266555, Shandong Province, P. R. China

Received Date: 7 May 2012
Available Online: 29 June 2012
Fund Project: 建设工程(ts20070704) (ts20070704) 国家自然科学基金(51104169) (51104169) 山东省自然科学基金(ZR2010BQ003, ZR2010EZ006)与中央高校基本科研业务费专项资金(11CX06028A)资助项目 (ZR2010BQ003, ZR2010EZ006)与中央高校基本科研业务费专项资金(11CX06028A)

The present work investigates the use of synergistic interactions between zwitterionic and anionic surfactants to obtain ultra-low interfacial tension (IFT) in a high salinity reservoir. Zwitterionic surfactant N-hexadecyl-N,N-dimethyl-3-ammonio-1-propanesulfonate was found to be compatible with simulated high salinity water, reducing crude oil/water interfacial tension to a magnitude of 10^-2 mN·m^-1 in a surfactant concentration range of 0.07%-0.39% (mass fraction), whereas ultra-low IFT was obtained by adding anionic surfactant sodium dodecyl sulfate. Furthermore, the effects of total surfactant concentration, metal ion concentration, and molar ratio on the dynamic interfacial tension of zwitterionic/anionic surfactant mixtures were studied. Results showed that 10^-5 mN·m^-1 magnitude ultra-low IFT was obtained over a wide range of surfactant concentrations from as low as 0.04% and up to 0.37% in high salinity water. The synergistic mechanism of ultra-low IFT formed in zwitterionic/anionic surfactant systems was further analyzed.
- Zwitterionic surfactant,
- Anionic surfactant,
- Synergistic effect,
- Ultra-low interfacial tension,
- Salt tolerance
1. [1]
  
  (1) Song,W. D.; Fang, T.;Wang, Q. K.; Zhou, Y. B. Energy Technology and Economics 2010, 22, 18. [宋卫东, 方彤,王乾坤, 周原冰. 能源技术经济, 2010, 22, 18.]
2. [2]
  (2) Zhao, F. L. Principles of Enhanced Oil Recovery; ChinaUniversity of Petroleum Press: Dongying, 2006; pp 1-2.[赵福麟. EOR 原理. 东营: 石油大学出版社, 2006: 1-2.]
3. [3]
  (3) Krumrine, P. H.; Falcone, J. S., Jr. Surfactant, Polymer, and Alkali Interactions in Chemical Flooding Processes, paper SPE11778 presented at the International Symposium on Oilfield andGeothermal Chemistry, Denver, Texas, June 1-3, 1983.
4. [4]
  (4) Delshad, M.; Han,W.; Pope, G. A.; Sepehrnoori, K.;Wu,W.;Yang, R.; Zhao, L. Alkaline/Surfactant/Polymer Flood Predictions for the Karamay Oil Field, paper SPE 39610presented at the SPE/DOE Symposium on Improved OilRecovery, Tulsa, Oklahoma, April 19-22, 1998.
5. [5]
  (5) Qu, Z. J.; Zhang, Y. G.; Zhang, X. S.; Dai, J. L. A Successful ASP Flooding Pilot in Gudong Oil Field, paper SPE 39613presented at the SPE/DOE Symposium on Improved OilRecovery, Tulsa, Oklahoma, April 19-22, 1998.
6. [6]
  (6) Wang, D. M.; Cheng, J. C.;Wu, J. Z.; Yang, Z. Y.; Yao, Y. M.;Li, H. F. Summary of ASP Pilots in Daqing Oil Field, paper SPE57288 presented at the SPE Asia Pacific Improved Oil RecoveryConference, Kuala Lumpur, Malaysia, October 25-26, 1999.
7. [7]
  (7) Green, D.W.;Willhite, G. P. Enhanced Oil Recovery; Henry, L.Ed., Doherty Memorial Fund of AIME, Society of PetroleumEngineers: Richardson, 1998; pp 12-35.
8. [8]
  (8) Kang,W. L.; Liu, Y. J. China Surfactant Detergent & Cosmetics2000, 4, 30. [康万利, 刘永建. 日用化学工业, 2000, 4, 30.]
9. [9]
  (9) Zhang, L.; Luo, L.; Zhao, S.; Xu, Z. C.; An, J. Y.; Yu, J. Y.J. Petro. Sci. Eng. 2004, 41, 189. doi: 10.1016/S0920-4105(03)00153-0
10. [10]
  (10) Chu, Y. P.; ng, Y.; Tan, X. L.; Zhang, L.; Zhao, S.; An, J. Y.;Yu, J. Y. J. Colloid Interface Sci. 2004, 276, 182. doi: 10.1016/j.jcis.2004.03.007
11. [11]
  (11) Zhang, S.; Xu, Y.; Qiao,W.; Li, Z. Fuel 2004, 83, 2059. doi: 10.1016/j.fuel.2004.04.001
12. [12]
  (12) Guo, D. H.; Xin, H. C.; Cui, X. D.; Xie, H. Z. Petroleum Processing and Petrochemicals 2005, 12, 41. [郭东红, 辛浩川, 崔晓东, 谢慧专. 石油炼制与化工, 2005, 12, 41.]
13. [13]
  (13) Zhao, Z. K.; Li, Z. S.; Zhao, S.; Qiao,W. H.; Cheng, L. B.Colloid Surf. A: Physicochem. Eng. Asp. 2005, 259, 71. doi: 10.1016/j.colsurfa.2005.02.012
14. [14]
  (14) ng, H. J.; Xia, X.; Xu, G.;Wang, Y. J. Colloids Surf. A: Physicochem. Eng. Asp. 2008, 317, 522. doi: 10.1016/j.colsurfa.2007.11.034
15. [15]
  (15) Han, X.; Cheng, X. H.;Wang, J.; Huang, J. B. Acta Phys. -Chim. Sin. 2012, 28, 146. [韩霞, 程新皓, 王江, 黄建滨. 物理化学学报, 2012, 28, 146.] doi: 10.3866/PKU.WHXB201228146
16. [16]
  (16) Hou, J. R.; Liu, Z. C.; Yue, X. A. Petroleum Geology & Oilfield Development in Daqing 2006, 25, 82. [侯吉瑞, 刘中春, 岳湘安. 大庆石油地质与开发, 2006, 25, 82.]
17. [17]
  (17) Yuan, X. Q.; Li, B. G.; Zhao, J. Y. Oilfield Chemistry 2008, 25,170. [袁新强, 李佰广, 赵劲毅. 油田化学, 2008, 25, 170.]
18. [18]
  (18) Sheng, D. Q. Well Testing and Production Technology 1995, 16,60. [绳德强. 试采技术, 1995, 16, 60.]
19. [19]
  (19) Chen, S. Y.; Liu, A. F.; Sun, X. N.; Liu, M. T.; Lin, T. Petroleum Geology & Oilfield Development in Daqing 2006, 25, 97. [陈仕宇, 刘安芳, 孙雪娜, 刘明涛, 林涛. 大庆石油地质与开发,2006, 25, 97.]
20. [20]
  (20) Zaitoun, A.; Fonseca, C.; Berger, P.; Baizin, B.; Monin, N. New Surfactant for Chemical Flood in High-Salinity Reservoir, paperSPE 80237 presented at the SPE International Symposium onOilfield Chemistry, Houston, Texas, February 5-7, 2003.
21. [21]
  (21) Chen, H.; Han, L.; Luo, P.; Ye, Z. Journal of Colloid and Interface Science 2005, 285, 872. doi: 10.1016/j.jcis.2004.11.066
22. [22]
  (22) Chen, H.; Han, L.; Luo, P.; Ye, Z. Surface Science 2005, 552,L53.
23. [23]
  (23) Wu,W. X.; Zhang,W.; Liu, C. D. Oilfield Chemistry 2007, 24,60. [吴文祥, 张武, 刘春德. 油田化学, 2007, 24, 60.]
24. [24]
  (24) Wang, D. M.; Liu, C. D.;Wu,W. X. Development of an Ultra-Low Interfacial Tension Surfactant in a System with No-alkali for Chemical Flooding, paper SPE 109017 presentedat the SPE/DOE Improved Oil Recovery, Tulsa, Oklahoma,April 19-23, 2008.
25. [25]
  (25) Wu,W. X.; Yin, Q. G.; Liu, C. D. Petroleum Geology and Recovery Efficiency 2009, 16, 67. [吴文祥, 殷庆国, 刘春德.油气地质与采收率, 2009, 16, 67.]
26. [26]
  (26) Zhao, G. X.; Zhu, B. Y. Principles of Surfactant Action; Chinalight Industry Press: Beijing, 2003; pp 356-382. [赵国玺, 朱瑶. 表面活性剂作用原理. 北京: 中国轻工业出版社, 2003:356-382.]
27. [27]
  (27) Rubin, E.; Radke, C. J. Chemical Engineering Science 1980, 5,1129.
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