Citation: YANG Fang, XU Xiang-Sheng, GU Hui-Zi, CHEN Ao-Ang, YAN Xin-Huan. Heterogeneously Catalyzed One-Pot Synthesis of N-alkyl anilines from Nitroaromatics by Assembled Pt₃Sn/Al₂O₃ Catalyst[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201206201 shu

Heterogeneously Catalyzed One-Pot Synthesis of N-alkyl anilines from Nitroaromatics by Assembled Pt₃Sn/Al₂O₃ Catalyst

1.
State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, P. R. China

Received Date: 6 April 2012
Available Online: 20 June 2012
Fund Project: 国家自然科学基金(21076197) (21076197) 浙江省自然科学基金(Y4090440) (Y4090440)浙江省钱江人才项目(2010R10038)资助 (2010R10038)

N-alkyl anilines were obtained from nitroaromatics by a one-pot method using assembled Pt₃Sn/Al₂O₃ catalyst for heterogeneous in situ hydrogenation in a continuous-flow fixed-bed reactor. At the optimum reaction conditions (503 K, liquid hourly space velocity (LHSV) of 7.5 h^-1, 5% (volume fraction) water, 1% (mass fraction) Pt₃Sn/Al₂O₃ catalyst), nitrobenzene conversion was 100%, with a total N-ethyl and N,N-diethyl aniline yield of 98.2%. Moreover, the Pt₃Sn/Al₂O₃ catalyst had a great conjoint effect for all in situ hydrogenation reactions for N-alkylation. High yields of N-alkylation products were obtained in aliphatic alcohol/water systems for 14 selected nitroaromatics.
- N-alkylation,
- In situ liquid hydrogenation,
- Nitroaromatic,
- N-alkyl aniline,
- Pt-Sn bimetallic catalyst
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Heterogeneously Catalyzed One-Pot Synthesis of N-alkyl anilines from Nitroaromatics by Assembled Pt3Sn/Al2O3 Catalyst

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通讯作者: 陈斌, bchen63@163.com

Heterogeneously Catalyzed One-Pot Synthesis of N-alkyl anilines from Nitroaromatics by Assembled Pt₃Sn/Al₂O₃ Catalyst