Citation: REN Chun-Yan, LU Hai, JIA Ming, ZHANG Zhi-An, LAI Yan-Qing, LI Jie. Application of 1,2-Dimethoxy-4-nitro-benzene and 1,4-Dimethoxy- 2-nitro-benzene as Overcharge Protection Additives in Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201206142 shu

Application of 1,2-Dimethoxy-4-nitro-benzene and 1,4-Dimethoxy- 2-nitro-benzene as Overcharge Protection Additives in Lithium-Ion Batteries

REN Chun-Yan ¹ ,
LU Hai ² ,
JIA Ming ^1,2 ,
ZHANG Zhi-An ^1, ,
LAI Yan-Qing ^1,2 ,
LI Jie ^1,2

1.
1. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, P. R. China;
2. Engineering Research Center of Advanced Battery Materials, the Ministry of Education, Changsha 410083, P. R. China

Received Date: 10 April 2012
Available Online: 14 June 2012
Fund Project: 国家科技支撑计划(2007BAE12B01) (2007BAE12B01)国家自然科学基金(20803095)资助项目 (20803095)

1,2-Dimethoxy-4-nitro-benzene (DMNB1) and 1,4-dimethoxy-2-nitro-benzene (DMNB2) were selected as new redox shuttle additives for overcharge protection in lithium-ion batteries. The base electrolyte is 1 mol·L^-1 LiPF₆/(ethylene carbonate (EC)+diethyl carbonate (DEC)+ethyl-methyl carbonate (EMC) (1:1:1, by volume)). Cyclic voltammetry (CV), charge-discharge cycle performance, overcharge tests, electrochemical impedance spectra (EIS), and scanning electron microscopy (SEM) were used to investigate the electrochemical performances of DMNB1 and DMNB2. The overcharge protection of DMNB1 and DMNB2 on lithium-ion batteries and the compatibility of both additives with the LiNi_1/3CoMn_1/3O₂ electrode have been studied. The results show that the working potentials of the both additives are above 4.3 V (vs Li/Li⁺), and thus are suitable for overcharge protection in lithium-ion batteries. Lithium-ion batteries with DMNB1 and DMNB2 have an improved overcharging tolerance. DMNB1 shows better overcharge protective performance, in the 100% overcharge and 5 V cutoff voltage tests, than DMNB2. After 100 cycles at 0.2C rate, the capacity retention rates of the LiNi_1/3Co_1/3Mn_1/3O₂/Li cells with the base electrolyte and the electrolyte with DMNB1 and DMNB2 are 98.4%, 95.9%, and 68.1%, respectively. The electrochemical properties and the location of the nitro-group on the benzene of the overcharge protection additives are closely linked.
- Overcharge,
- Redox,
- Dimethoxy-benzene,
- Electrolyte,
- Safety additive
1. [1]
  
  (1) Chen, Y. S.; Hu, C. C.; Li, Y. Y. J. Power Sources 2008, 181, 69.doi: 10.1016/j.jpowsour.2008.03.015
2. [2]
  (2) Chen, L.; Buhrmester, C.; Dahn, J. R. Electrochem. Solid-State Lett. 2005, 8, A59.
3. [3]
  (3) Balakrishnan, P. G.; Ramesh, R. T.; Kumar, P. J. Power Sources2006, 155, 401. doi: 10.1016/j.jpowsour.2005.12.002
4. [4]
  (4) Lan, X.; Li, S. L.; Ai, X. P.; Yang, H. X.; Cao, Y. L. Energy Environ. Sci. 2011, 4, 2845. doi: 10.1039/c0ee00590h
5. [5]
  (5) Kise, M.; Yoshioka, S.; Hamano, K.; Kuriki, H.; Nishimura, T.;Urushibata, H.; Yoshiyasu, H. J. Electrochem. Soc. 2005, 152,A1516.
6. [6]
  (6) Chen, Z.; Amine, K. Electrochem Commun. 2007, 9, 703. doi: 10.1016/j.elecom.2006.11.002
7. [7]
  (7) Watanabe, Y.; Yamazaki, Y.; Yasuda, K.; Morimoto, H.;Tobishima, S. I. J. Power Sources 2006, 160, 1375. doi: 10.1016/j.jpowsour.2006.03.007
8. [8]
  (8) Zhang, S. S. J. Power Sources 2006, 162, 1379. doi: 10.1016/j.jpowsour.2006.07.074
9. [9]
  (9) Guo, Y. J.; Chen, H.; Qi, L. Acta Phys. -Chim. Sin. 2007, 23 (supp.), 80. [郭营军, 晨辉, 其鲁. 物理化学学报, 2007,23 (supp.), 80.] doi: 10.3866/PKU.WHXB2007Supp17
10. [10]
  (10) Wang, B.; Xia, Q.; Zhang, P.; Li, G. C.;Wu, Y. P.; Luo, H. J.;Zhao, S. Y.; Ree, T. Electrochem. Commun. 2008, 10, 727.doi: 10.1016/j.elecom.2008.02.011
11. [11]
  (11) Xiong, L. Q.; Zhang, Y. J.; Dong, P.; Yang, R. M.; Xia, S. B.Chem. Ind. Eng. Prog. 2011, 30, 1198. [熊琳强, 张英杰, 董鹏, 杨瑞明, 夏书标. 化工进展, 2011, 30, 1198.]
12. [12]
  (12) Xu, M. Q.; Xing, L. D.; Li,W. S.; Zuo, X. X.; Shu, D.; Li, G. L.J. Power Sources 2008, 184, 427. doi: 10.1016/j.jpowsour.2008.03.036
13. [13]
  (13) Guo, Y. X.; Yin, Z. G.; Tao, Z. Y.; Li, X. H. Trans. Nonferrous Met. Soc. China 2008, 18, 2025. [郭永兴, 殷振国, 陶芝勇, 李新海. 中国有色金属学报, 2008, 18, 2025.]
14. [14]
  (14) Zhang, Q. Y.; Qiu, C. C.; Fu, Y. B.; Ma, X. H. Chin. J. Power Sources 2009, 33, 774. [张千玉, 秋沉沉, 付延鲍, 马晓华. 电源技术, 2009, 33, 774.]
15. [15]
  (15) Xiao, L.; Ai, X.; Cao, Y.; Yang, H. Electrochim. Acta 2004, 49,4189. doi: 10.1016/j.electacta.2004.04.013
16. [16]
  (16) Buhrmester, C.; Moshurchak, L.;Wang, R. L.; Dahn, J. R.J. Electrochem. Soc. 2006, 153, A288.
17. [17]
  (17) Wang, R. L.; Buhrmester, C.; Dahn, J. R. J. Electrochem. Soc.2006, 153, A445.
18. [18]
  (18) Luo, H. J.; Zhang, X. G.; Chen, L. Chin. J. Power Sources 2012,36, 172. [骆宏钧, 张校刚, 陈黎. 电源技术, 2012, 36, 172]
19. [19]
  (19) Feng, J. K.; Ai, X. P.; Cao, Y. L.; Yang, H. X. Electrochem. Commun. 2007, 9, 25. doi: 10.1016/j.elecom.2006.08.033
20. [20]
  (20) Moshuchak, L. M.; Bulinski, M.; Lamanna,W. M.;Wang, R. L.;Dahn, J. R. Electrochem. Commun. 2007, 9, 1497. doi: 10.1016/j.elecom.2007.01.059
21. [21]
  (21) Han, Y. K.; Jung, J.; Yu, S.; Lee, H. J. Power Sources 2009, 187,581. doi: 10.1016/j.jpowsour.2008.10.137
22. [22]
  (22) Chen, Z.; Qin, Y.; Amine, K. Electrochim. Acta 2009, 54, 5605.doi: 10.1016/j.electacta.2009.05.017
23. [23]
  (23) Li, T. T.;Wang, C. Y.; Xing, L. D.; Li,W. S.; Peng, B.; Xu, M.Q.; Gu, F. L.; Hu, S. J. Acta Phys. -Chim. Sin. 2012, 28, 818.[李田田, 王朝阳, 刑丽丹, 李伟善, 彭彬, 许梦清, 顾凤龙,胡社军. 物理化学学报, 2012, 28, 818.] doi: 10.3866/PKU.WHXB201201132
24. [24]
  (24) Dahn, J. R.; Jiang, J.; Moshurchak, L. M.; Fleischauer, M. D.;Buhrmester, C.; Krause, L. J. Electrochem. Soc. 2005, 152,A1283.
25. [25]
  (25) Weng,W.; Zhang, Z.; Redfern, P. C.; Curtiss, L. A.; Amine, K.J. Power Sources 2011, 196, 1530. doi: 10.1016/j.jpowsour.2010.08.049
26. [26]
  (26) Zhang, S. S.; Xu, K.; Jow, T. R. Electrochim. Acta 2004, 49,1057. doi: 10.1016/j.electacta.2003.10.016
27. [27]
  (27) Zhang, S. S. J. Power Source 2007, 163, 713. doi: 10.1016/j.jpowsour.2006.09.040
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