Citation: YANG Zhi-Wang, CHEN Li-Na, HONG Wei, KANG Rui-Xue, WANG Jia, JIA Na, ZHAO Lei, MA Heng-Chang. Baeyer-Villiger Oxidation and Acetalization of Cyclic Ketones on SO₄^2-/SnO₂-Fe₂O₃ Solid Acid Catalysts[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201206121 shu

Baeyer-Villiger Oxidation and Acetalization of Cyclic Ketones on SO₄^2-/SnO₂-Fe₂O₃ Solid Acid Catalysts

1.
Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, P. R. China

Received Date: 26 March 2012
Available Online: 12 June 2012
Fund Project: 国家自然科学基金(21163016, 21174114) (21163016, 21174114) 甘肃省自然科学基金(1010RJZA024) (1010RJZA024)(NWNU-KJCXGC-03-63)资助 (NWNU-KJCXGC-03-63)

Fe-doped SO₄^2-/SnO₂ (STF) solid acid catalysts with different amounts of iron were prepared via co-condensation, followed by sulfation and calcination. These materials were characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray powder diffraction (XRD), N₂ adsorption-desorption analysis (BET), thermogravimetric (TG) analysis, and scanning electron microscopy (SEM). The Fe-doped catalysts exhibited more activity than undoped catalysts in acetalization reactions of 4-tert-butylcyclohexanone and diols. The catalytic acetalization of several ketones and 1,2-diols with the SO₄^2-/SnO₂-Fe₂O₃ catalysts (with the Fe/Sn molar ratio of 0.5) were studied. The influence of the reaction time and the amount of the catalysts on the acetalization were also investigated. In addition, the high performance of this Fe-modified catalyst was demonstrated in the Baeyer-Villiger oxidation of cyclic ketones. The catalyst can be recycled several times without any significant loss in catalytic activity.
- Solid acid,
- Acetalization,
- Baeyer-Villiger oxidation,
- Fe₂O₃-doping,
- Sulfated tin oxide
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沈阳化工大学材料科学与工程学院沈阳 110142

Baeyer-Villiger Oxidation and Acetalization of Cyclic Ketones on SO42-/SnO2-Fe2O3 Solid Acid Catalysts

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通讯作者: 陈斌, bchen63@163.com

Baeyer-Villiger Oxidation and Acetalization of Cyclic Ketones on SO₄^2-/SnO₂-Fe₂O₃ Solid Acid Catalysts