Citation: ZHENG Bin, ZHANG An-Feng, LIU Min, DING Fan-Shu, DAI Cheng-Yi, SONG Chun-Shan, GUO Xin-Wen. Properties of the Nano-Particle Fe-based Catalyst for the Hydrogenation of Carbon Dioxide to Hydrocarbons[J]. Acta Physico-Chimica Sinica, ;2012, 28(08): 1943-1950. doi: 10.3866/PKU.WHXB201206051 shu

Properties of the Nano-Particle Fe-based Catalyst for the Hydrogenation of Carbon Dioxide to Hydrocarbons

1.
1. State Key Laboratory of Fine Chemicals, Department of Catalysis Chemistry and Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, P. R. China;
2. EMS Energy Institute and Department of Energy and Mineral Engineering, Pennsylvania State University, University Park, Pennsylvania, 16802, USA

Received Date: 10 March 2012
Available Online: 5 June 2012

Combining co-precipitation-gelation, mechanical mixing and impregnation methods, a series of catalysts of FeK-M/γ-Al₂O₃(M=Cd or Cu) have been attained. The catalysts were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), N₂ physisorption, X-ray diffraction (XRD) and temperature-programmed reduction of hydrogen (H₂-TPR). The hydrogenation of carbon dioxide over these catalysts was also investigated in a fixed bed. Given a reaction time of 100 h, CO₂ conversion over a 15%Fe/10%K/γ-Al₂O₃ catalyst reached 51.3 %, with a selectivity towards C₂₊ of 62.6 % at 3 MPa, 673 K, a space velocity of 3600 h-1 and at a molar ratio of H₂/CO₂ of 3. At the lower Fe content of 2.5%, the selectivity towards C₂₊ was still greater than 60.0%. Increasing the potassium content from 0% to 10%, increased the selectivity towards C₂-C₄⁼ and the molar ratio of C₂-C₄⁼ /C₂-C₄⁰ increased to 3.6. The addition of Cd and Cu improved the reduction and catalytic activities. Specifically, Cu improved the molar ratio of C₂-C₄⁼ /C₂-C₄⁰ from 3.6 to 5.4, and the Cd increased the selectivity of C₅₊ by 12%.
- Carbon dioxide,
- Hydrogenation,
- Fe-based catalyst,
- Precipitation,
- Light hydrocarbons
1. [1]
  
  (1) rdon, D.W.; Calvin, H. B. J. Catal. 1984, 87, 352. doi: 10.1016/0021-9517(84)90196-9
2. [2]
  (2) Song, C. S. Catal. Today 2006, 115, 2. doi: 10.1016/j.cattod.2006.02.029
3. [3]
  (3) Martin, P. R.; Dominik, U.; Georg, S. Ind. Eng. Chem. Res.2005, 44, 9653. doi: 10.1021/ie050289z
4. [4]
  (4) King, D. L.; Cusumano, J. A.; Garten, R. L. Cat. Rev. -Sci. Eng.1981, 23, 233. doi: 10.1080/03602458108068077
5. [5]
  (5) Srivastava, R. D.; Rao, V. U. S.; Cinquegrane, G.; Stiegel, G. J.Hydrocarbon Process 1990, 69, 59.
6. [6]
  (6) Choi, P. H.; Jun, K.W.; Lee, S. J.; Choi, M. J.; Lee, K.W. Catal. Lett. 1996, 40, 115. doi: 10.1007/BF00807467
7. [7]
  (7) Soled, S.; Iglesia, E.; Fiato, R. A. Catal. Lett. 1990, 7, 271.
8. [8]
  (8) Raje, A. P.; O'Brien, R. J.; Davis, B. H. J. Catal. 1998, 180, 36.doi: 10.1006/jcat.1998.2259
9. [9]
  (9) Mostafa, F.; Mohsen, I.; Ali, A. M. Fuel Process. Technol. 2011,92, 1136. doi: 10.1016/j.fuproc.2011.01.010
10. [10]
  (10) Luo, X.; Hou, C. P.;Wu, Y.; Xia, G. F.; Nie, H. Acta Petrolei. Sinica 2011, 27 (1), 26. [罗熙, 侯朝鹏, 吴玉, 夏国富,聂红. 石油学报, 2011, 27 (1), 26.]
11. [11]
  (11) Dorner, R.W.; Hardy, D. R.;Williams, F.W.;Willauer, H. D.Catal. Commun. 2010, 11, 816. doi: 10.1016/j.catcom.2010.02.024
12. [12]
  (12) Dorner, R.W.; Hardy, D. R.;Williams, F.W.;Willauer, H. D.Appl. Catal. A 2010, 373, 112. doi: 10.1016/j.apcata.2009.11.005
13. [13]
  (13) Yu,W. Q.;Wu, B. S.; Xu, J.; Tao, Z. C.; Xiang, H.W. Catal. Lett. 2008, 125, 116. doi: 10.1007/s10562-008-9524-3
14. [14]
  (14) Wang, H.; Hao, Q. L.; Liu, F. X.; Zhang, C. H.; Yang, Y.; Tian,L.; Bai, L.; Xiang, H.W.; Li, Y.W.; Xu, B. F.; Yi, F. J. Fuel Chem. Tech. 2005, 33 (1) 89. [王洪, 郝庆兰, 刘福霞, 张承华, 杨勇, 田磊, 白亮, 相宏伟, 李永旺, 徐斌富, 易凡.燃料化学学报, 2005, 33 (1), 89.]
15. [15]
  (15) Wang, L. L.;Wu, B. S.; Li, Y.W. Chin . J. Catal. 2011, 32, 495.[王立丽, 吴宝山, 李永旺. 催化学报, 2011, 32, 495.]
16. [16]
  (16) Wang, H. L.; Yang, Y.;Wang, H.; Qing, M.; Xiang, H.W.; Li, Y.W. Chin. J. Catal. 2010, 31, 809. [王虎林, 杨勇, 王洪,青明, 相宏伟, 李永旺. 催化学报, 2010, 31, 809.]
17. [17]
  (17) Dorner, R.W.; Hardy, D. R.;Williams, F.W.;Willauer, H. D.Energ. Environ. Sci. 2010, 3, 884. doi: 10.1039/c001514h
18. [18]
  (18) Dorner, R.W.; Hardy, D. R.;Williams, F.W.;Willauer, H. D.Catal. Commun. 2011, 15, 88. doi: 10.1016/j.catcom.2011.08.017
19. [19]
  (19) Xu, L. Y.;Wang, Q. X.; Lin, L.W.; Liang, D. B.; Yang, L. Nat. Gas. Chem. Ind. 1997, 22, 10. [徐龙伢, 王清遐, 林励吾, 梁东白, 杨力. 天然气化工, 1997, 22, 10.]
20. [20]
  (20) Ren, D. M.; Zhou, Y. S. Ind. Catal. 2004, 12, 32. [任冬梅, 周亚松. 工业催化, 2004, 12, 32.]
21. [21]
  (21) Sarkar, A.; Seth, D.; Dozier, A. K.; Neathery, J. K.; Hamdeh, H.H.; Davis, B. H. Catal. Lett. 2007, 117 (1), 1.
22. [22]
  (22) Pour, A. N.; Housaindokht, M. R.; Tayyari, S. F.; Zarkesh, J.J. Nat. Gas. Chem. 2010, 19, 284. doi: 10.1016/S1003-9953(09)60059-1
23. [23]
  (23) Liu, C.; Zou, B.; Rondinone, A. J.; Zhang, Z. J. J. Phys. Chem. B 2000, 104, 1141. doi: 10.1021/jp993552g
24. [24]
  (24) Eriksson, S.; Nylen, U.; Rojas, S.; Boutonnet, M. Appl. Catal. A2004, 265, 207. doi: 10.1016/j.apcata.2004.01.014
25. [25]
  (25) Pour, A. N.; Housaindokht, M. R.; Babakhani, E. G.; Irani, M.;Shalri, S. M. K. J. Ind. Eng. Chem. 2011, 17, 596. doi: 10.1016/j.jiec.2011.05.002
26. [26]
  (26) Guo, X. H.; Zhong, S. L.; Zhang, J.;Wang,W.; Mao, J. J.; Xie.G. J. Mater. Sci. 2010, 45, 6467. doi: 10.1007/s10853-010-4733-8
27. [27]
  (27) Sai-Prasad, P. S.; Jong,W. B.; Ki,W. J.; Kyu,W. L. Catal. Surv. Asia 2008, 12, 170. doi: 10.1007/s10563-008-9049-1
28. [28]
  (28) Schulz, H.; Riedel, T.; Schaub, G. Top. Catal. 2005, 32, 117.doi: 10.1007/s11244-005-2883-8
29. [29]
  (29) Mao, D. S.; Guo, Q. S.; Yu, J.; Han, L. P.; Lu, G. Z. Acta Phys. -Chim. Sin. 2011, 27, 2639. [毛东森, 郭强胜, 俞俊,韩璐蓬, 卢冠忠. 物理化学学报, 2011, 27, 2639.] doi: 10.3866/PKU.WHXB20111125
30. [30]
  (30) Li, S. Z.; Krishnamoorthy, S.; Li, A.W.; Meitzner, G. D.;Iglesia, E. J. Catal. 2002, 206, 202. doi: 10.1006/jcat.2001.3506
31. [31]
  (31) Lox, E. S.; Froment, G. F. Ind. Eng. Chem. Res. 1993, 32, 71.doi: 10.1021/ie00013a011
32. [32]
  (32) Riedel, T.; Schulz, H.; G. Schaub, G.; Jun, K.W.; Hwang, J. S.;Lee, K.W. Top. Catal. 2003, 26, 41. doi: 10.1023/B:TOCA.0000012986.46680.28
33. [33]
  (33) Zhang, C. H.; Yang, Y.; Teng, B. T.; Li, T. Z.; Zheng, H. Y.;Xiang, H.W.; Li, Y.W. J. Catal. 2006, 237, 405. doi: 10.1016/j.jcat.2005.11.004
34. [34]
  (34) Ding, M. Y.; Yang, Y.; Xiang, H.W.; Li, Y.W. Chin. J. Catal.2010, 31, 1145. [定明月, 杨勇, 相宏伟, 李永旺. 催化学报,2010, 31, 1145].
35. [35]
  (35) Dalai, A. K.; Davis, B. H. Appl. Catal. A 2008, 348 (1), 1.
36. [36]
  (36) Riedel, T.; Schaub, G.; Jun, K.W.; Lee, K.W. Ind. Eng. Chem. Res. 2001, 40, 1355. doi: 10.1021/ie000084k
37. [37]
  (37) Rohde, M. P.; Unruh, D.; Schaub, G. I. Ind. Eng. Chem. Res.2005, 44, 9653.
38. [38]
  (38) Temkin, O. N.; Zeigarnik, A. V.; Kuzmin, A. E.; Bruk, L. G.;Slivinskii, E. V. Russ. Chem. Bull. 2002, 51 (1), 1.
39. [39]
  (39) Chang, J.; Teng, B. T.; Bai, L.; Zhang, R. L.; Xiang, H.W.; Li,Y.W.; Sun, Y. H. Coal Convers. 2005, 28 (2), 1. [常杰, 滕波涛, 白亮, 张荣乐, 相宏伟, 李永旺, 孙予罕. 煤炭转化, 2005,28 (2), 1.]
40. [40]
  (40) Zhi, P. L.; Hu, P. J. Am. Chem. Soc. 2002, 124, 39.
41. [41]
  (41) Schulz, H.; Claeys, M. Appl. Catal. A 1999, 186, 91. doi: 10.1016/S0926-860X(99)00166-0
42. [42]
  (42) Blyholder, G. J. Phys. Chem. 1964, 68, 2772. doi: 10.1021/j100792a006
43. [43]
  (43) Pichler, H.; Schulz, H. Chem. Ing. Tech. 1970, 12, 1160.
44. [44]
  (44) Han, J. L.; Chun, C. C.; Jia, J. H. J. Phys. Chem. C 2011, 115,11045.
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