Citation: YANG Xiao-Yan, SUN Song, DING Jian-Jun, ZHANG Yi, ZHANG Man-Man, GAO Chen, BAO Jun. Preparation, Structure and Performance of [CuO-ZnO-Al₂O₃]/ [HZSM-5] Core-Shell Bifunctional Catalysts for One-Step Synthesis of Dimethyl Ether from CO₂+H₂[J]. Acta Physico-Chimica Sinica, ;2012, 28(08): 1957-1963. doi: 10.3866/PKU.WHXB201206011 shu

Preparation, Structure and Performance of [CuO-ZnO-Al₂O₃]/ [HZSM-5] Core-Shell Bifunctional Catalysts for One-Step Synthesis of Dimethyl Ether from CO₂+H₂

1.
National Synchrotron Radiation Laboratory & School of Nuclear Science and Technology, University of Science and Technology of China, Hefei 230029, P. R.China

Received Date: 23 April 2012
Available Online: 1 June 2012
Fund Project: 国家自然科学基金(11179034, 20903084)资助项目 (11179034, 20903084)

A series of core-shell bifunctional catalysts [CuO-ZnO-Al₂O₃]/[HZSM-5] for one-step synthesis of dimethyl ether from CO₂ hydrogenation were prepared by a hydrothermal synthesis method, and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS). The catalyst has a core-shell structure with an integral and compact shell of HZSM-5 coated on the surface of a pre-shaped CuO-ZnO-Al₂O₃ pellet. The crystallite size and thickness of the zeolite shell can be controlled by the crystallization time. Compared with the mechanically mixed catalyst, the core-shell catalyst shows much higher selectivity for dimethyl ether synthesis from CO₂ + H₂. The core-shell catalyst with a crystallization time of 3 d shows the best catalytic performance, with a CO₂ conversion of 38.9% and a dimethyl ether selectivity of 77.0%.
- Core-shell bifunctional catalysts,
- CO₂hydrogenation,
- Dimethyl ether,
- Selectivity
1. [1]
  
  (1) Liu, C. X.; Ding, P.; Liu,W. Y.;Wang,W. T.; Liu, J. Renewable Energy 2006, 4, 54. [刘存祥, 丁攀, 刘文艺, 王文堂, 刘杰. 可再生能源, 2006, 4, 54.]
2. [2]
  (2) Sidhu, S.; Graham, J.; Striebich, R. Chemosphere 2001, 42, 681.doi: 10.1016/S0045-6535(00)00242-3
3. [3]
  (3) Demirbas, A. Energy Sources Part A 2008, 30, 1473. doi: 10.1080/15567030701258519
4. [4]
  (4) Omata, K.;Watanabe, Y.; Umegaki, T.; Ishiguro, G.; Yamada,M. Fuel 2002, 81, 1605. doi: 10.1016/S0016-2361(02)00080-7
5. [5]
  (5) Stryjek, R.; Bobbo, S.; Camporese, R.; Zilio, C. J. Chem. Eng. Data 1999, 44, 568. doi: 10.1021/je980240i
6. [6]
  (6) Bobbo, S.; Camporese, R.; Stryjeck, R. Fluid Phase Equilib.1999, 161, 305. doi: 10.1016/S0378-3812(99)00194-6
7. [7]
  (7) Chang, Y. H.; Han, Y. Z.;Wang, X. K.; Yang, C. H.; Li,W. B.Petrochem. Technol. 2000, 29, 829. [常雁红, 韩怡卓, 王心葵,杨彩虹, 李文彬. 石油化工, 2000, 29, 829.]
8. [8]
  (8) Man, J. M.; Zhang, Q. D.; Xie, H. J.; Pan, J. X.; Tan, Y. S.; Han,Y. Z. J. Fuel Chem. Technol. 2011, 39, 42. [满建明, 张清德,解红娟, 潘俊轩, 谭猗生, 韩怡卓. 燃料化学学报, 2011, 39, 42.]doi: 10.1016/S1872-5813(11)60008-X
9. [9]
  (9) Li, J.; Tan, Y. S.; Han, Y. Z. Chem. Ind. Eng. Prog. 2010, 29 (Suppl. 3), 466. [李剑, 谭猗生, 韩怡卓. 化工进展, 2010,29 (增刊3), 466.]
10. [10]
  (10) Xia, J. C.; Mao, D. S.; Chen, Q. L.; Tang, Y. Petrochem. Technol. 2004, 33, 788. [夏建超, 毛东森, 陈庆铃, 唐颐.石油化工, 2004, 33, 788.]
11. [11]
  (11) Pontzen, F.; Liebner,W.; Gronemann, V.; Rothaemel, M.;Ahlers, B. Catal. Today 2011, 171, 242. doi: 10.1016/j.cattod.2011.04.049
12. [12]
  (12) Olah, G. A.; Prakash, G. K.S.; eppert, A. J. Am. Chem. Soc.2011, 133, 12881. doi: 10.1021/ja202642y
13. [13]
  (13) Dubois, J. L.; Sayama, K.; Arakawa, H. Chem. Lett. 1992, 21,1115.
14. [14]
  (14) Wang, J. Y.; Zeng, C. Y.;Wu, C. Z. Chin. J. Catal. 2006, 27,927. [王继元, 曾崇余, 吴昌子. 催化学报, 2006, 27, 927.]
15. [15]
  (15) Zhao, Y. Q.; Chen, J. X.; Zhang, J. X.; Zhang, J. Y. J. Fuel Chem. Technol. 2005, 33, 334. [赵彦巧, 陈吉祥, 张建祥,张继炎. 燃料化学学报, 2005, 33, 334.]
16. [16]
  (16) Sun, K. P.; Lu,W.W.;Wang, M.; Xu, X. L. Catal. Commun.2004, 5, 367. doi: 10.1016/j.catcom.2004.03.012
17. [17]
  (17) He, J. J.; Liu, Z. L.; Yoneyama, Y.; Nishiyama, N.; Tsubaki, N.Chem. Eur. J. 2006, 12, 8296. doi: 10.1002/chem.200501295
18. [18]
  (18) He, J. J.; Yoneyama, Y.; Xu, B. L.; Nishiyama, N.; Tsubaki, N.Langmuir 2005, 21, 1699. doi: 10.1021/Ia047217h
19. [19]
  (19) Yang, G. H.; He, J. J.; Yoneyama, Y.; Tan, Y. S.; Han, Y. Z.;Tsubaki, N. Appl. Catal. A 2007, 329, 99. doi: 10.1016/j.apcata.2007.06.028
20. [20]
  (20) Deng, J. F.; Sun, Q.; Zhang, Y. L. Appl. Catal. A 1996, 139, 75.doi: 10.1016/0926-860X(95)00324-X
21. [21]
  (21) Yang, G. H.; Tsubaki, N.; Shamoto, J.; Yoneyama, Y.; Zhang, Y.J. Am. Chem. Soc. 2010, 132, 8129. doi: 10.1021/ja101882a
22. [22]
  (22) Naik, S.P.; Ryu, T.; Bui, V.; Miller, J. D.; Drinnan, N. B.;Zmierczak,W. Chem. Eng. J. 2011, 167, 362. doi: 10.1016/j.cej.2010.12.087
23. [23]
  (23) Zha, F.; Ding, J.; Chang, Y.; Ding, J. F.;Wang, J. Y.; Ma. J. Ind. Eng. Chem. Res. 2012, 51, 345. doi: 10.1021/ie202090f
24. [24]
  (24) Bao, J.; He, J. J.; Zhang, Y.; Nishiyama, N.; Tsubaki, N. Angew. Chem. Int. Edit. 2008, 47, 353. doi: 10.1002/anie.200703335
25. [25]
  (25) Nie, R. F.; Lei, H.; Pan, S. Y.;Wang, L. N.; Fei, J. H.; Hou, Z. Y.Fuel 2012, 96, 419. doi: 10.1016/j.fuel.2011.12.048
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation, Structure and Performance of [CuO-ZnO-Al2O3]/ [HZSM-5] Core-Shell Bifunctional Catalysts for One-Step Synthesis of Dimethyl Ether from CO2+H2

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通讯作者: 陈斌, bchen63@163.com

Preparation, Structure and Performance of [CuO-ZnO-Al₂O₃]/ [HZSM-5] Core-Shell Bifunctional Catalysts for One-Step Synthesis of Dimethyl Ether from CO₂+H₂