Citation:
LIANG Gui-Jie, ZHONG Zhi-Cheng, XU Jie, XU Wei-Lin, CHEN Mei-Hua, ZHANG Zeng-Chang, LI Wen-Lian. Formation Mechanism, Structure Model and Electrochemical Performance of an In situ Cross Linking Hybrid Polymer Electrolyte Membrane[J]. Acta Physico-Chimica Sinica
doi:
10.3866/PKU.WHXB201205251
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A Nano-TiO2/poly(citric acid titanium complex-polyethylene glycol)/LiI/I2 crosslinked hybrid polymer electrolyte membrane has been prepared via in-situ polymerization and compositing. Specifically, the method used the synthesized crosslinked network of poly(citric acid titanium complex-polyethylene glycol) containing the Ti(VI) hybrid center as a substrate, the hydrolyzed Nano-TiO2 as fillers and LiI/I2 as conductive ionics. The formation mechanism of the crosslinked hybrid polymer matrix is discussed. A structural model was established with a local density approximation (LDA) method. The influence of Ti(iOPr)4 content on the structure and electrochemical performance of the electrolyte membrane were investigated with Raman spectra, Fourier transform infrared spectra (FTIR), transmission electron microscopy (TEM), and an energy dispersive X-ray analysis (EDXA) technique. It was found that when the Ti(iOPr)4 content was higher than 12% (w), the combined action of Nano-TiO2 particles and the Ti(VI) hybrid center improved not only the room-temperature ionic conductivity (σ), but also the interfacial stability. At 48% (w) Ti(iOPr)4 content, the value of σ reached a maximum of 9.72×10-5 S·cm-1 and the interface resistance became stable after 6 d.
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