Citation: LIANG Gui-Jie, ZHONG Zhi-Cheng, XU Jie, XU Wei-Lin, CHEN Mei-Hua, ZHANG Zeng-Chang, LI Wen-Lian. Formation Mechanism, Structure Model and Electrochemical Performance of an In situ Cross Linking Hybrid Polymer Electrolyte Membrane[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201205251 shu

Formation Mechanism, Structure Model and Electrochemical Performance of an In situ Cross Linking Hybrid Polymer Electrolyte Membrane

1.
1. Research Center for Materials Science & Engineering, Hubei University of Arts and Science, Xiangyang 441053, Hubei Province, P. R. China;
2. State Key Laboratory for Mechanical Behavior of Materials, Xi'an JiaoTong University, Xi'an 710049, P. R. China;
3. Key Laboratory of Green Processing and Functional Textiles of New Textile Materials, Ministry of Education, Wuhan Textile University, Wuhan 430073, P. R. China

Received Date: 30 March 2012
Available Online: 25 May 2012
Fund Project: 国家自然科学基金 (51003082) (51003082)教育部科学技术研究重点项目(208089) (208089)湖北省自然科学基金 (2011CDC062) 资助项目 (2011CDC062)

A Nano-TiO₂/poly(citric acid titanium complex-polyethylene glycol)/LiI/I₂ crosslinked hybrid polymer electrolyte membrane has been prepared via in-situ polymerization and compositing. Specifically, the method used the synthesized crosslinked network of poly(citric acid titanium complex-polyethylene glycol) containing the Ti(VI) hybrid center as a substrate, the hydrolyzed Nano-TiO₂ as fillers and LiI/I₂ as conductive ionics. The formation mechanism of the crosslinked hybrid polymer matrix is discussed. A structural model was established with a local density approximation (LDA) method. The influence of Ti(iOPr)₄ content on the structure and electrochemical performance of the electrolyte membrane were investigated with Raman spectra, Fourier transform infrared spectra (FTIR), transmission electron microscopy (TEM), and an energy dispersive X-ray analysis (EDXA) technique. It was found that when the Ti(iOPr)₄ content was higher than 12% (w), the combined action of Nano-TiO₂ particles and the Ti(VI) hybrid center improved not only the room-temperature ionic conductivity (σ), but also the interfacial stability. At 48% (w) Ti(iOPr)₄ content, the value of σ reached a maximum of 9.72×10^-5 S·cm^-1 and the interface resistance became stable after 6 d.
- Polymer electrolyte,
- Dye-sensitized solar cells,
- Titanium tetraisopropoxide,
- Ionic conductivity,
- Interface stability
1. [1]
  
  (1) Fenton, D. E.; Parker, J. M.;Wright, P. V. Polymer 1973, 14,589.
2. [2]
  (2) Li, X. L.; Guo, J.;Wu, Q.; Cheng, Y.; Long, Y. C.; Jiang, Z. Y.Acta Phys. -Chim. Sin. 2005, 21, 397. [李雪莉, 郭娟, 吴强, 程岩, 龙英才, 江志裕. 物理化学学报, 2005, 21, 397.]doi: 10.3866/PKU.WHXB20050411
3. [3]
  (3) Li, Y. J.; Zhan, H.; Liu, S. Q.; Huang, K. L.; Zhou, Y. H. Acta Phys. -Chim. Sin. 2010, 26, 2387. [李亚娟, 詹晖, 刘素琴,黄可龙, 周运鸿. 物理化学学报, 2010, 26, 2387.] doi: 10.3866/PKU.WHXB20100818
4. [4]
  (4) Quartarone, E.; Mustarelli, P.; Magistris, A. Solid State Ion1998, 110, 1. doi: 10.1016/S0167-2738(98)00114-3
5. [5]
  (5) Robitaille, C. D.; Fauteux, D. J. Electrochem. Soc. 1986, 133,315. doi: 10.1149/1.2108569
6. [6]
  (6) Wieczorek,W.; Raducha, D.; Zalewska, A.; Stevens, J. R.J. Phys. Chem. B 1998, 102, 8725. doi: 10.1021/jp982403f
7. [7]
  (7) Yang, H.; Liu, J.; Lin, Y.; Zhang, J.; Zhou, X. Electrochim. Acta2011, 56, 6271.
8. [8]
  (8) Stephan, A. M. Eur. Polym. J. 2006, 42, 21. doi: 10.1016/j.eurpolymj.2005.09.017
9. [9]
  (9) Kumar, M.; Sekhon, S. S. Eur. Polym. J. 2002, 38, 1297. doi: 10.1016/S0014-3057(01)00310-X
10. [10]
  (10) Wu, X. L.; Xin, S.; Seo, H. H.; Kim, J.; Guo, Y. G.; Lee, J. S.Solid State Ion. 2011, 186, 1.
11. [11]
  (11) Chu, P. P.; Reddy, M. J. J. Power Sources 2003, 115, 288. doi: 10.1016/S0378-7753(02)00717-6
12. [12]
  (12) Johan, M. R.; Fen, L. B. Ionics 2010, 16, 335.
13. [13]
  (13) Zhang, J.; Han, H.W.;Wu, S. J.; Xu, S.; Yang, Y.; Zhou, C. H.;Zhao, X. Z. Solid State Ion. 2007, 178, 1595. doi: 10.1016/j.ssi.2007.10.009
14. [14]
  (14) Geng, Y.; Shi, Y. T.;Wang, L. D.; Ma, B. B.; Gao, R.; Zhu, Y. F.;Dong, H. P.; Qiu, Y. Phys. Chem. Chem. Phys. 2011, 13, 2417.
15. [15]
  (15) Lee, R. H.; Cheng, T. F.; Chang, J.W.; Ho, J. H. Colloid Polym. Sci. 2011, 289, 817.
16. [16]
  (16) Zhang, D.W.; Li, X. D.; Huang, S. M.;Wang, Z. A.; Shi, J. H.;Sun, Z.; Yin, X. J. International Journal of Nanoscience 2010,9, 257.
17. [17]
  (17) Basak, P.; Manorama, S. V. Eur. Polym. J. 2004, 40, 1155. doi: 10.1016/j.eurpolymj.2004.01.013
18. [18]
  (18) Kuo, P. L.; Hou, S. S.; Lin, C. Y.; Chen, C. C.;Wen, T. C. J. Polym. Sci. Pol. Chem. 2004, 42, 2051. doi: 10.1002/pola.20056
19. [19]
  (19) Liang, G. J.; Xu, J.; Xu,W. L.; Shen, X. L.; Zhang, H.; Yao, M.Polym. Compos. 2011, 32, 511.
20. [20]
  (20) Liang, G.; Xu, J.; Xu,W. L.; Shen, X. L.; Bai, Z. K.; Yao, M.Polym. Eng. Sci. 2011, 51, 2526.
21. [21]
  (21) Liang, G.; Xu,W. L.; Xu, J.; Shen, X. L.; Yao, M. Influence ofWeight Ratio of Citric Acid Cross Linker on the Structure andConductivity of the Crosslinked Polymer Electrolytes. InAdvanced Materials Research, International Symposium onChemical Engineering and Material Properties, Shenyang,China, Nov 4-6, 2011; Zhang, H. M.,Wu, B., Eds.; Trans TechPublications Ltd: Switzerland, 2011; pp 391-392.
22. [22]
  (22) Kefalas, E. T.; Panagiotidis, P.; Raptopoulou, C. P.; Terzis, A.;Mavromoustakos, T.; Salifoglou, A. Inorg. Chem. 2005, 44,2596. doi: 10.1021/ic049276o
23. [23]
  (23) Deng, Y. F.; Zhou, Z. H.;Wan, H. L. Inorg. Chem. 2004, 43,6266. doi: 10.1021/ic0496018
24. [24]
  (24) Collins, J. M.; Uppal, R.; Incarvito, C. D.; Valentine, A. M.Inorg. Chem. 2005, 44, 3431. doi: 10.1021/ic048158y
25. [25]
  (25) Feng, M.;Wang, Y. F.;Wang, H.; Cao, X.W.; Lan, G. X.; Fan,X. J. Chinese Journal of Light Scattering 2008, 20, 265. [冯敏, 王玉芳, 王翚, 曹学伟, 蓝国祥, 范秀菊. 光散射学报,2008, 20, 265.]
26. [26]
  (26) Zampieri, M.; Lazaro, S. R.; Paskocimas, C. A.; Ferreira, A. G.;Lon , E.; Varela, J. A. J. Sol-Gel Sci. Technol. 2006, 37, 9. doi: 10.1007/s10971-005-4892-2
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