Citation: LIANG Gui-Jie, ZHONG Zhi-Cheng, XU Jie, XU Wei-Lin, CHEN Mei-Hua, ZHANG Zeng-Chang, LI Wen-Lian. Formation Mechanism, Structure Model and Electrochemical Performance of an In situ Cross Linking Hybrid Polymer Electrolyte Membrane[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201205251 shu

Formation Mechanism, Structure Model and Electrochemical Performance of an In situ Cross Linking Hybrid Polymer Electrolyte Membrane

1.
1. Research Center for Materials Science & Engineering, Hubei University of Arts and Science, Xiangyang 441053, Hubei Province, P. R. China;
2. State Key Laboratory for Mechanical Behavior of Materials, Xi'an JiaoTong University, Xi'an 710049, P. R. China;
3. Key Laboratory of Green Processing and Functional Textiles of New Textile Materials, Ministry of Education, Wuhan Textile University, Wuhan 430073, P. R. China

Received Date: 30 March 2012
Available Online: 25 May 2012
Fund Project: 国家自然科学基金 (51003082) (51003082)教育部科学技术研究重点项目(208089) (208089)湖北省自然科学基金 (2011CDC062) 资助项目 (2011CDC062)

A Nano-TiO₂/poly(citric acid titanium complex-polyethylene glycol)/LiI/I₂ crosslinked hybrid polymer electrolyte membrane has been prepared via in-situ polymerization and compositing. Specifically, the method used the synthesized crosslinked network of poly(citric acid titanium complex-polyethylene glycol) containing the Ti(VI) hybrid center as a substrate, the hydrolyzed Nano-TiO₂ as fillers and LiI/I₂ as conductive ionics. The formation mechanism of the crosslinked hybrid polymer matrix is discussed. A structural model was established with a local density approximation (LDA) method. The influence of Ti(iOPr)₄ content on the structure and electrochemical performance of the electrolyte membrane were investigated with Raman spectra, Fourier transform infrared spectra (FTIR), transmission electron microscopy (TEM), and an energy dispersive X-ray analysis (EDXA) technique. It was found that when the Ti(iOPr)₄ content was higher than 12% (w), the combined action of Nano-TiO₂ particles and the Ti(VI) hybrid center improved not only the room-temperature ionic conductivity (σ), but also the interfacial stability. At 48% (w) Ti(iOPr)₄ content, the value of σ reached a maximum of 9.72×10^-5 S·cm^-1 and the interface resistance became stable after 6 d.
- Polymer electrolyte,
- Dye-sensitized solar cells,
- Titanium tetraisopropoxide,
- Ionic conductivity,
- Interface stability
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