Citation: LI Hui-Quan, CUI Yu-Min, WU Xing-Cai, HUA Lin, HONG Wen-Shan. Structure and Properties of BiOI/TiO₂ (A) Photocatalysts with Different Bi/Ti Molar Ratios[J]. Acta Physico-Chimica Sinica, ;2012, 28(08): 1985-1991. doi: 10.3866/PKU.WHXB201205161 shu

Structure and Properties of BiOI/TiO₂ (A) Photocatalysts with Different Bi/Ti Molar Ratios

LI Hui-Quan ^1,2 ,
CUI Yu-Min ^1,2, ,
WU Xing-Cai ^3, ,
HUA Lin ⁴ ,
HONG Wen-Shan ¹

1.
1. School of Chemistry and Chemical Engineering, Fuyang Normal College, Fuyang, 236041, Anhui Province, P. R. China;
2. Anhui Provincical Key Laboratory for Degradation and Monitoring of Pollution of the Environment, Fuyang 236041, P. R. China;
3. The State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China;
4. R&D center, Singapore Linovus Technology Pte Ltd, 059818, Singapore

Received Date: 19 March 2012
Available Online: 16 May 2012
Fund Project: 国家自然科学基金(21171091) (21171091)安徽省高校省级自然科学基金(KJ2012A217, KJ2012B136)资助项目 (KJ2012A217, KJ2012B136)

BiOI-sensitized nano-anatase (TiO₂ (A)) photocatalysts were prepared by a deposition method at room temperature, and characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and photoluminescence (PL), and UV-Vis diffuse reflectance spectra (UV-Vis DRS). The photocatalytic activities were evaluated by photo-degradation experiments of rhodamine B. With increasing BiOI content, the absorption intensity of BiOI/TiO₂ (A) increases in the 370-630 nm region and the absorption band edge redshifts. The UV and visible light photocatalytic activities increase, reaching a maximum when the Bi/Ti molar ratio is 1.7% . The 1.7% BiOI/TiO₂ (A) catalyst exhibits much higher visible-light photoactivity than P25, and its UV-light photoactivity is slightly higher than that of P25. The UV and visible light photocatalytic activities of BiOI/TiO₂ (A) with similar BiOI content are lower than those of BiOI/P25 catalysts. Compared with TiO₂ (A), 1.7% BiOI/TiO₂ (A) shows higher UV and visible light photoactivities. This is attributed to the strong absorption in the 370-630 nm region, the redshift of the absorption band edge, and the effective transfer of the photogenerated electrons and holes, which reduces the recombination of electron-hole pairs.
- Deposition method,
- Sensitized,
- Anatase,
- BiOI content,
- Photocatalysis
1. [1]
  
  (1) Chen, X. B.; Liu, L.; Yu, P. Y.; Mao, S. S. Science 2011, 331,746. doi: 10.1126/science.1200448
2. [2]
  (2) Qiu,W.; Ren, C. J.; ng, M. C.; Hou, Y. Z.; Chen, Y. Q. Acta Phys. -Chim. Sin. 2011, 27, 1487. [仇伟, 任成军, 龚茂初,侯云泽, 陈耀强. 物理化学学报, 2011, 27, 1487.] doi: 10.3866/PKU.WHXB20110621
3. [3]
  (3) Tong, X.; Chen, R.; Chen, T. H. Acta Phys. -Chim. Sin. 2011, 27,1941. [佟欣, 陈睿, 陈铁红. 物理化学学报, 2011, 27,1941.] doi: 10.3866/PKU.WHXB20110836
4. [4]
  (4) Chen, S. F.; Zhao,W.; Liu,W.; Zhang, S. J. Appl. Surf. Sci.2008, 255, 2478. doi: 10.1016/j.apsusc.2008.07.115
5. [5]
  (5) Chen, S. F.; Zhang, S. J.; Liu,W.; Zhao,W. J. Hazard. Mater.2008, 155, 320. doi: 10.1016/j.jhazmat.2007.11.063
6. [6]
  (6) Li, Y. Z.; Kim, S. J. J. Phys. Chem. B 2005, 109 (25), 12309.doi: 10.1021/jp0512917
7. [7]
  (7) Wu, J. M.; Yao, J. J.; Yang, H. P.; Fan, Y. N.; Xu, B. L. Acta. Chim. Sin. 2010, 68 (14), 1349. [吴俊明, 姚俊杰, 杨汉培, 范以宁, 许波连. 化学学报, 2010, 68 (14), 1349.]
8. [8]
  (8) Li, Y. Z.; Lee, N. H.; Hwang, D. S.; Song, J. S.; Lee, E. G.;Kim, S. J. Langmuir 2004, 20 (25), 10838.
9. [9]
  (9) Sério, S.; Jorge, M. E. M.; Coutinho, M. L.; Hoffmann, S. V.;Limao-Vieira, P.; Nunes, Y. Chem. Phys. Lett. 2011, 508, 71.doi: 10.1016/j.cplett.2011.04.002
10. [10]
  (10) Sun,W. T.; Yu, Y.; Pan, H. Y.; Gao, X. F.; Chen, Q.; Peng, L. M.J. Am. Chem. Soc. 2008, 130, 1124. doi: 10.1021/ja0777741
11. [11]
  (11) Morikawa, T.; Ohwaki, T.; Suzuki, K. I.; Shinya, M.;Tero-Kubota, S. Appl. Catal. B: Environ. 2008, 83, 56. doi: 10.1016/j.apcatb.2008.01.034
12. [12]
  (12) Mitoraj, D.; Kisch, H. Angew. Chem. Int. Edit. 2008, 47, 9975.doi: 10.1002/anie.200800304
13. [13]
  (13) Li, G. S.; Zhang, D. Q.; Yu, J. C. Environ. Sci. Technol. 2009,43, 7079. doi: 10.1021/es9011993
14. [14]
  (14) Li, L.; Rohrer, G. S.; Salvador, P. A. J. Am. Ceram. Soc. 2012,95, 1414. doi: 10.1111/j.1551-2916.2012.05076.x
15. [15]
  (15) Zyoud, A. H.; Zaatar, N.; Saadeddin, I.; Ali, C.; Park, D.;Campet, G.; Hilal, H. S. J. Hazard. Mater. 2010, 173, 318. doi: 10.1016/j.jhazmat.2009.08.093
16. [16]
  (16) Xia, J. X.; Yin, S.; Li, H. M.; Xu, H.; Xua, L.; Zhang, Q.Colloids and Surfaces A: Physicochem. Eng. Aspects 2011, 387,23. doi: 10.1016/j.colsurfa.2011.07.023
17. [17]
  (17) Li, Y. Y.;Wang, J. S.; Yao, H. C.; Dang, L. Y.; Li, Z. J. J. Mol. Catal. A: Chem. 2011, 334, 116. doi: 10.1016/j.molcata.2010.11.005
18. [18]
  (18) Wang, Y. N.; Deng, K. J.; Zhang, L. Z. J. Phys. Chem. C 2011,115, 14300 doi: 10.1021/jp2042069
19. [19]
  (19) Zhang, X.; Zhang, L. Z.; Xie, T. F.;Wang, D. J. J. Phys. Chem. C 2009, 113, 7371. doi: 10.1021/jp900812d
20. [20]
  (20) Galceran, M.; Pujol, M. C.; Zaldo, C.; Díaz, F.; Aguiló, M.J. Phys. Chem. C 2009, 113, 15497. doi: 10.1021/jp901109a
21. [21]
  (21) Huang, G. L.; Zhu, Y. F. J. Phys. Chem. C 2007, 111, 11952.doi: 10.1021/jp071987v
22. [22]
  (22) Hua, X.; Zhang, L. Z. J. Phys. Chem. C 2009, 113, 1785.
23. [23]
  (23) Bakardjieva, S.; Subrta, J.; Štengla, V.; Dianez, M. J.; Sayagues,M. J. Appl. Catal. B: Environ. 2005, 58, 193.
24. [24]
  (24) Chen, C. C.; Zhao,W.; Li, J. Y.; Zhao, J. C. Environ. Sci. Technol. 2002, 36, 3604. doi: 10.1021/es0205434
25. [25]
  (25) Cao, J.; Xu, B. Y.; Lin, H. L.; Luo, B. D.; Chen, S. F. Chem. Eng. J. 2012, 185/186, 91.
26. [26]
  (26) Lee, Y. L.; Lo, Y. S. Adv. Funct. Mater. 2009, 19, 604. doi: 10.1002/adfm.200800940
27. [27]
  (27) Li, Y. Y.;Wang, J. S.; Liu, B.; Dang, L. Y.; Yao, H. C.; Li, Z. J.Chem. Phys. Lett. 2011, 508, 102. doi: 10.1016/j.cplett.2011.04.019
28. [28]
  (28) Robel, I.; Kuno, M.; Kamat, P. V. J. Am. Chem. Soc. 2007, 129,4136. doi: 10.1021/ja070099a
29. [29]
  (29) Kongkanand, A.; Tvrdy, K.; Takechi, K.; Kuno, M.; Kamat, P. V.J. Am. Chem. Soc. 2008, 130, 4007. doi: 10.1021/ja0782706
30. [30]
  (30) Yu, J. G.; Yu, H. G.; Cheng, B.; Zhao, X. J.; Yu, J. C.; Ho,W. K.J. Phys. Chem. B 2003, 107 (50), 13871. doi: 10.1021/jp036158y
31. [31]
  (31) Li, X. Z.; Li, F. B.; Yang, C. L.; Ge,W. K. J. Photochem. Photobiol. A 2001, 141 (2-3), 209. doi: 10.1016/S1010-6030(01)00446-4
32. [32]
  (32) Jing, L. Q.; Qu, Y. C.;Wang, B. Q.; Li, S. D.; Jiang, B. J.;Yang,L. B.; Fu,W.; Fu, H. G.; Sun, J. Z. Sol. Energy Mat. Sol. Cells2006, 90, 1773. doi: 10.1016/j.solmat.2005.11.007
33. [33]
  (33) Baiju, K. V.; Zachariah, A.; Shukla, S.; Biju, S.; Reddy, M. L. P.;Warrier, K. G. K. Catal. Lett. 2009, 130, 130. doi: 10.1007/s10562-008-9798-5
1. [1]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
2. [2]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
3. [3]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
4. [4]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
5. [5]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
6. [6]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
7. [7]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
8. [8]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
9. [9]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
10. [10]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
11. [11]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
12. [12]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
13. [13]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
14. [14]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
15. [15]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
16. [16]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
17. [17]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
18. [18]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
19. [19]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
20. [20]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007

Get Citation

PDF

XML

Metrics

PDF Downloads(799)
Abstract views(2818)
HTML views(40)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Structure and Properties of BiOI/TiO2 (A) Photocatalysts with Different Bi/Ti Molar Ratios

Metrics

通讯作者: 陈斌, bchen63@163.com

Structure and Properties of BiOI/TiO₂ (A) Photocatalysts with Different Bi/Ti Molar Ratios