Citation: ZHANG Chao, AO Jian-Ping, WANG Li, JIANG Tao, SUN Guo-Zhong, HE Qing, ZHOU Zhi-Qiang, SUN Yun. Electrodepositied Gallium on Gallium and Copper/Indium Substratess[J]. Acta Physico-Chimica Sinica, ;2012, 28(08): 1913-1922. doi: 10.3866/PKU.WHXB201205153 shu

Electrodepositied Gallium on Gallium and Copper/Indium Substratess

1.
Key Laboratory of Optoelectronic Information Technology, Ministry of Education, Tianjin Key Laboratory of Photo-Electronic Thin Film Devices and Technology, Institute of Photo-Electronic Thin FilmDevices and Technique, Nankai University, Tianjin 300071, P. R. China

Received Date: 29 March 2012
Available Online: 15 May 2012
Fund Project: 教育部博士点基金(20090031110031)资助项目 (20090031110031)

We investigate the electrodeposition of gallium metallic precursor on gallium and Cu/In substrates from acidic aqueous solutions. The effect of the supporting electrolyte and the solution pH value for the electrodeposition of Ga is investigated by cyclic voltammetry. During Ga electrodeposition, gallium gradually diffuses into the film, and reacts with CuIn alloy to produce CuGae₂ at the Cu/In interface. We use triethanolamine to protect the Cu/In and Ga films from being oxidized, and thus this improves the current efficiency of Ga-electrodeposition. The Cu-In-Ga films are annealed in an Se atmosphere to produce In_1-xGa_xSee₂(CIGS) thin films with high quality, and the efficiency of the solar cell prepared using these films is 9.42%.
- Electrodeposition,
- Cu(In_1-xGa_x)Se₂,
- Cyclic voltammetry,
- Metallic precursor,
- Solar cell
1. [1]
  
  (1) Savado , O. Solar Energy Materials and Solar Cells 1998, 52,361. doi: 10.1016/S0927-0248(97)00247-X
2. [2]
  (2) Viswanathan, S. S.; Choi, I. H.; Lee, C.W. Solar Energy 2011,85, 2666. doi: 10.1016/j.solener.2011.08.003
3. [3]
  (3) Pandey, R. K.; Sahu, S. N.; Chandra, S. Handbook of Semiconductor Electrodeposition; Marcel Dekker Inc.: NewYork, 1996.
4. [4]
  (4) Gutay, L.; Bauer, G. Thin Solid Films 2007, 515, 6212. doi: 10.1016/j.tsf.2006.12.164
5. [5]
  (5) Han, S. H.; Hermann, A.M.; Hasoon, F. S.; Al-Thani, H.A.;Levi, D. H. Appl. Phys. Lett. 2004, 85, 576. doi: 10.1063/1.1776616
6. [6]
  (6) Hermann, A. M.; nzalez, C.; Ramakrishnan, P. A.; Balzar, D.;Popa, N.; Rice, P.; Marshall, C. H.; Hilfiker, J. N.; Tiwald, T.;Sebastian, P. J.; Calixto, M.E.; Bhattacharya, R. N. Sol. Energy Mater. Sol. Cells 2001, 70, 345. doi: 10.1016/S0927-0248(01)00076-9
7. [7]
  (7) Hibberd, C. J.; Chassaing, E.; Liu,W.; Mitzi, D. B.; Lincot, D.;Tiwari, A. N. Prog. Photovolt. Res. Appl. 2010, 18, 434. doi: 10.1002/pip.914
8. [8]
  (8) Bhattacharya, R. N.; Hiltnerb, J. F.; Batchelora,W. Thin Solid Films 2000, 361, 396.
9. [9]
  (9) Ao, J. P.; Yang, L.; Yan, L.; Sun, G. Z.; He, Q.; Zhou, Z. Q.;Sun, Y. Chin. Phys. Soc. 2009, 58(3) 1870. [敖建平, 杨亮,闫礼, 孙国忠, 何青, 周志强, 孙云. 物理学报, 2009, 58 (3) 1870]
10. [10]
  (10) Ao, J. P.; Sun, G. Z.; Yan, L.; Kang, F.;Yang, L.; He, Q.; Zhou,Z. Q.; Li, F. Y.; Sun, Y. Acta Phys. -Chim. Sin. 2008, 24(6),1073. [敖建平, 孙国忠, 闫礼, 康峰, 杨亮, 何青, 周志强; 李凤岩, 孙云, 物理化学学报, 2008, 24(6),1073]
11. [11]
  (11) Ganchev, M.; Kois, J.; Bereznev, S.; Tzvetkova, E. Thin Solid Films 2006, 511, 325. doi: 10.1016/j.tsf.2005.11.076
12. [12]
  (12) Basol, B. M. Roll-to-roll Electroplating for Photovoltaic FilmManufacturing. US20080093221, 2008-04-24.
13. [13]
  (13) Basol, B. M.; Pinarbasi, M.; Aksu, S.;Wang, J.; Matus, Y.;Johnson, T.; Han, Y.; Narasinham, M.; Metin, B. Proc. 23rd European Photovoltaic Solar Energy Conference,Valencia,Spain, 2008.
14. [14]
  (14) Bockris, J. O'M.; Enyo, E. Journal of the Electrochemical Society 1964, 109 (1), 48.
15. [15]
  (15) Flamini, D. O.; Saidman, S. B.; Bessone, J. B. J. Appl. Electrochem. 2007, 37, 467. doi: 10.1007/s10800-006-9277-x
16. [16]
  (16) Ara n, E.; Cazenave-Vergez, L.; Lanza, E.; Giroud, A.;Sebaoun, A. Brit. Corros. J. 1997, 32, 263.
17. [17]
  (17) Muller, S.; Holzer, F.; Desilvestro, J.; Haas, O. J. Appl. Electrochem. 1996, 26, 1217.
18. [18]
  (18) Standard Electrode Potential. http://wenku.baidu.com/view/89fe2f707fd5360cba1adb64.html
19. [19]
  (19) Fang J. L. Theory & Application of Coordination Compounds in Electroplating; Chemical Industry Press, 2007; pp 1-7. [方景礼,电镀配合物——理论与应用. 化学工业出版社, 2007: 1-7.]
20. [20]
  (20) Ribeaucourt, L.; Chassaing, E.; Savidand, G.; Lincot, D. Thin Solid Films 2011, 519, 7241.
21. [21]
  (21) Ribeaucourt, L.; Savidand, G.; Lincot, D.; Chassaing, E.Electrochimica Acta 2011, 56, 6628. doi: 10.1016/j.electacta.2011.05.033
22. [22]
  (22) Li, D. Principles of Electrochemistry; Beihang University Press:Beijing, 1999; pp 162-167. [李荻. 电化学原理. 北京: 北京航空航天大学出版社, 1999: 162-167].
23. [23]
  (23) Zhang, L. M.; Fang, J. L.;Yuan, G.W.; Shen, P. H. Practical Electroplating Additive; Chemical Industry Press: Beijing,2007; pp 418-419. [张立茗, 方景礼, 袁国伟, 沈品华. 实用电镀添加剂. 北京: 化学工业出版社, 2007: 418-419]
24. [24]
  (24) Puigdomenech, Hydra/Medusa Chemical Equilibrium Databaseand Plotting Software. KTH Royal Institute of Technology,2004. http://www.kemi.kth.se/medusa/.
25. [25]
  (25) Marudachalam, M.; Birkmire, R.W.; Hichri, H. J. Appl. Phys.1997, 82 (6), 2896.
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