Citation: LI Jie-Bin, XU You-Long, DU Xian-Feng, SUN Xiao-Fei, XIONG Li-Long. Improved Electrochemical Stability of Zn-Doped LiNi_1/3Co_1/3Mn_1/3O₂ Cathode Materials[J]. Acta Physico-Chimica Sinica, ;2012, 28(08): 1899-1905. doi: 10.3866/PKU.WHXB201205152 shu

Improved Electrochemical Stability of Zn-Doped LiNi_1/3Co_1/3Mn_1/3O₂ Cathode Materials

1.
1. Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education, International Center for Dielectric Research, Xi’an Jiaotong University, Xi’an 710049, P. R. China;
2. Shaanxi Applied Physics and Chemistry Research Institute; Xi'an 710061, P. R. China

Received Date: 15 March 2012
Available Online: 15 May 2012
Fund Project: 国家自然科学基金(50902109)资助项目 (50902109)

Highly stable Li(Ni_1/3Co_1/3Mn_1/3)_1-xZn_xO₂ (x=0, 0.02, 0.05) cathode materials doped with Zn are synthesized by solid-state reactions with co-precipitated precursors. Cyclic voltammetry (CV) curves reveal that the potential difference between oxidation and reduction decreases to 0.09 V, and from electrochemical impedance spectra (EIS) curves, the impedance of LiNi_1/3Co_1/3Mn_1/3O₂ cathode materials is reduced from 266 to 102 Ω. The diffusion coefficients of Li⁺ ions in intercalation processes increase from 1.20×10^-11 to 2.54×10^-11 cm²·s^-1. Li(Ni_1/3Co_1/3Mn_1/3)_0.98Zn_0.02O₂ is stable at 0.3C (constant charge/discharge) at a high cut-off potential of 4.6 V vs Li/Li⁺. It has a second discharge capacity of 176.2 mAh·g^-1 at 0.3C and 142 mAh·g^-1 at 3C, and keep almost no decay after 100 cycles at room temperature. Furthermore, its average capacity loss per cycle at 55 °C is 0.20%, which is lower compared with 0.54% for LiNi_1/3Co_1/3Mn_1/3O₂ and 0.38% for Li(Ni_1/3Co_1/3Mn_1/3)_0.95Zn_0.05O₂ after 100 cycles. The improved electrochemical stability of Zn-doped LiNi_1/3Co_1/3Mn_1/3O₂ is attributed to the reduced electrode polarization and impedance values, and an increased Li+ ion diffusion coefficient.
- Lithium nickel cobalt manganese oxide,
- High cut-off voltage,
- Zn-doping,
- Cathode material,
- Lithium ion battery
1. [1]
  
  (1) Ohzuku, T.; Makimura, Y. Chem. Lett. 2001, 7, 642.
2. [2]
  (2) Hwang, B. J.; Tsai, Y.W.; Carlier, D.; Ceder, G. Chem. Mater.2003, 15, 3676. doi: 10.1021/cm030299v
3. [3]
  (3) Shaju, K. M.; Rao, G. V. S.; Chowdari, B. V. R. Electrochim. Acta 2002, 48, 145. doi: 10.1016/S0013-4686(02)00593-5
4. [4]
  (4) Wu, F.;Wang, M.; Su, Y. F.; Chen, S. Acta Phys. -Chim. Sin.2009, 25, 629. [吴峰, 王萌, 苏岳峰, 陈实. 物理化学学报, 2009, 25, 629.] doi: 10.3866/PKU.WHXB20090411
5. [5]
  (5) Tu, J. P.;Wu, H. M.; Chen, X. T.; Yuan, Y. F.; Li, Y.; Zhao, X.B.; Cao, G. S. J. Power Sources 2006, 159, 291. doi: 10.1016/j.jpowsour.2006.04.032
6. [6]
  (6) Chen, J.;Wang, S.; Whittingham, M. S. J. Power Sources 2007,174, 442. doi: 10.1016/j.jpowsour.2007.06.189
7. [7]
  (7) Reddy, M. V.; Rao, G. V. S.; Chowdari, B. V. R. J. Power Sources 2006, 159, 263. doi: 10.1016/j.jpowsour.2006.04.134
8. [8]
  (8) Koyama, Y.; Tanaka, I.; Adachi, H.; Makimura, Y.; Ohzuku, T.J. Power Sources 2003, 119, 644. doi: 10.1016/S0378-7753(03)00194-0
9. [9]
  (9) Yoon,W. S.; Grey, C. P.; Balasubramanian, M.; Yang, X. Q.;Fischer, D. A.; McBreen, J. Electrochem. Solid State Lett. 2004,7, A53.
10. [10]
  (10) Kim, J. M.; Chung, H. T. Electrochim. Acta 2004, 49, 937. doi: 10.1016/j.electacta.2003.10.005
11. [11]
  (11) Shaju, K. M.; Rao, G. V. S.; Chowdari, B. V. R. J. Electrochem. Soc. 2004, 151, A1324.
12. [12]
  (12) Yabuuchi, N.; Ohzuku, T. J. Power Sources 2003, 119, 171. doi: 10.1016/S0378-7753(03)00173-3
13. [13]
  (13) Chebiam, R. V.; Prado, F.; Manthiram, A. Chem. Mater. 2001,13, 2951. doi: 10.1021/cm0102537
14. [14]
  (14) Kim, H. S.; Kong, M.; Kim, K.; Kim, I. J.; Gu, H. B. J. Power Sources 2007, 171, 917. doi: 10.1016/j.jpowsour.2007.06.028
15. [15]
  (15) Na, S. H.; Kim, H. S.; Moon, S. I. Solid State Ionics 2005, 176,313. doi: 10.1016/j.ssi.2004.08.016
16. [16]
  (16) Sun, Y. K.; Lee, Y. S.; Yoshio, M.; Amine, K. Electrochem. Solid State Lett. 2002, 5, L1.
17. [17]
  (17) Ceder, G.; Chiang, Y. M.; Sadoway, D. R.; Aydinol, M. K.; Jang,Y. I.; Huang, B. Nature 1998, 392, 694. doi: 10.1038/33647
18. [18]
  (18) Zou, M. J.; Yoshio, M.; pukumar, S.; Yamaki, J. Chem. Mater. 2003, 15, 4699. doi: 10.1021/cm0347032
19. [19]
  (19) Chen, Y. H.; Chen, R. Z.; Tang, Z. Y.;Wang, L. J. Alloy. Compd.2009, 476, 539. doi: 10.1016/j.jallcom.2008.09.055
20. [20]
  (20) Ren, H. B.; Li, X.; Peng, Z. H. Electrochim. Acta 2011, 56,7088. doi: 10.1016/j.electacta.2011.05.104
21. [21]
  (21) Milewska, A.; Molenda, M.; Mokenda, J. Solid State Ionics2011, 192, 313. doi: 10.1016/j.ssi.2010.11.026
22. [22]
  (22) Holleman, A. F.;Wiberg, E.;Wiberg, N. Lehrbuch der Anorganischen Chemie; Gruyter: Berlin, 1995.
23. [23]
  (23) Fey, G. T. K.; Chen, J. G.; Subramanian, V.; Osaka, T. J. Power Sources 2002, 112, 384. doi: 10.1016/S0378-7753(02)00400-7
24. [24]
  (24) Li, J. B.; Xu, Y. L.; Xiong, L. L.;Wang, J. P. Acta Phys. -Chim. Sin. 2011, 27, 2593. [李节宾, 徐友龙, 熊礼龙, 王景平. 物理化学学报, 2011, 27, 2593.] doi: 10.3866/PKU.WHXB20111104
25. [25]
  (25) Jouanneau, S.; Eberman, K.W.; Krause, L. J.; Dahn, J. R.J. Electrochem. Soc. 2003, 150, A1637.
26. [26]
  (26) Kim, J. H.; Yoon, C. S.; Sun, Y. K. J. Electrochem. Soc. 2003,150, A538.
27. [27]
  (27) Pouillerie, C.; Perton, F.; Biensan, P.; Peres, J. P.; Broussely, M.;Delmas, C. J. Power Sources 2001, 96, 293. doi: 10.1016/S0378-7753(00)00653-4
28. [28]
  (28) Liu, L.; Sun, K. N.; Zhang, N. Q.; Yang, T. Y. J. Solid State Electrochem. 2009, 13, 1381. doi: 10.1007/s10008-008-0695-z
29. [29]
  (29) Xia, H.; Lu, L.; Lai, M. O. Electrochim. Acta 2009, 54, 5986.doi: 10.1016/j.electacta.2009.02.071
30. [30]
  (30) Xiong, L. L.; Xu, Y. L.; Zhang, C.; Zhang, Z.W.; Li, J. B.J. Solid State Electrochem. 2011, 15, 1263. doi: 10.1007/s10008-010-1195-5
31. [31]
  (31) Bard, A. J.; Faulkner, L. R. Electrochemical Methods, 2nd ed.;Wiley: New York, 2001.
32. [32]
  (32) Jiao, L. F.; Zhang, M.; Yuan, H. T.; Zhao, M.; Guo, H.;Wang,W.; Zhou, X. D.;Wang, Y. M. J. Power Sources 2007, 167, 178.doi: 10.1016/j.jpowsour.2007.01.070
33. [33]
  (33) Ghosh, P.; Mahanty, S.; Basu, R. N. Electrochim. Acta 2009, 54,1654. doi: 10.1016/j.electacta.2008.09.050
34. [34]
  (34) Malik, R.; Burch, D.; Bazant, M.; Ceder, G. Nano Lett. 2010,10, 4123. doi: 10.1021/nl1023595
35. [35]
  (35) Hwang, B. J.; Santhanam, R.; Chen, C. H. J. Power Sources2003, 114, 244. doi: 10.1016/S0378-7753(02)00584-0
36. [36]
  (36) Kyu-Hang, L.; Nam-In, C.; Eui-Jung, Y.; Nam, H. G. Appl. Surf. Sci. 2011, 256, 4241.
37. [37]
  (37) Katsumata, T.; Matsui, Y.; Inaguma, Y.; Itoh, M. Solid State Ionics 1996, 86 (8), 165.
38. [38]
  (38) Wu, F.;Wang, M.; Su, Y. F.; Bao, L. Y.; Chen, S. Electrochim. Acta 2009, 54, 6803. doi: 10.1016/j.electacta.2009.06.075
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沈阳化工大学材料科学与工程学院沈阳 110142

Improved Electrochemical Stability of Zn-Doped LiNi1/3Co1/3Mn1/3O2 Cathode Materials

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Improved Electrochemical Stability of Zn-Doped LiNi_1/3Co_1/3Mn_1/3O₂ Cathode Materials