Citation: PING Li-Na, ZHENG Jia-Ming, SHI Zhi-Qiang, WANG Cheng-Yang. Electrochemical Performance of Lithium Ion Capacitors Using Li⁺-Intercalated Mesocarbon Microbeads as the Negative Electrode[J]. Acta Physico-Chimica Sinica, ;2012, 28(07): 1733-1738. doi: 10.3866/PKU.WHXB201205092 shu

Electrochemical Performance of Lithium Ion Capacitors Using Li⁺-Intercalated Mesocarbon Microbeads as the Negative Electrode

1.
1. Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P. R. China;
2. Tianjin Key Laboratory of Fiber Modification and Functional Fiber, College of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, P. R. China

Received Date: 5 March 2012
Available Online: 9 May 2012
Fund Project: 国家自然科学基金(51172160, 50902102) (51172160, 50902102)国家高技术研究发展计划项目(863) (2011AA11A232)资助 (863) (2011AA11A232)

Lithium ion capacitors (LICs) were fabricated using Li +-intercalated mesocarbon microbeads (LMCMBs) as the negative electrode and commercial activated carbon (AC) as the positive electrode. The phase structure of LMCMB electrodes was characterized by X-ray diffraction (XRD). LMCMB electrodes retain their original graphite crystal structure when the capacity induced by initial Li⁺ intercalation is less than 200 mAh·g^-1. The charge-discharge performances of positive and negative electrodes and LICs were studied using a three-electrode cell. Using an LMCMB electrode as an anode, a stable working potential is obtained at lower voltage than using other electrodes, and the potential range of the positive electrode is extended to a lower range. The electrochemical performance of LMCMB/AC capacitors, including capacitance, cycle life, and efficiency, is improved compared with that of an MCMB/AC capacitor. The efficiency increases from less than 95% to nearly 100%, and the capacity retention is improved from 74.8% to nearly 100% for 100 cycles in a voltage range of 2.0 to 3.8 V. The stable capacity of LMCMB/AC capacitors with cycling is directly correlated to less polarization of AC during the charge storage process, which is caused in turn by the LMCMB negative electrode. Gravimetric energy densities as high as 85.6 and 97.9 Wh·kg^-1 are obtained in voltage ranges of 2.0 to 3.8 V and 1.5 to 3.8 V, respectively.
- Lithium ion capacitor,
- Hybrid capacitor,
- Mesocarbon microbead,
- Activated carbon,
- Li⁺ pre-doping
1. [1]
  
  (1) Zhang, J.; Kong, L. B.; Cai, J. J.; Yang, Z. S.; Luo, Y. C.; Kang,L. Acta Phys. -Chim. Sin. 2010, 26 (6), 1515. [张晶, 孔令斌, 蔡建军, 杨贞胜, 罗永春, 康龙. 物理化学学报, 2010, 26 (6), 1515.] doi: 10.3866/PKU.WHXB20100603
2. [2]
  (2) Yuan, C. Z.; Gao, B.; Zhang, X. G. J. Power Sources 2007, 173,606. 10.1016/j.jpowsour.2007.04.034
3. [3]
  (3) Su, Y. F.;Wu, F.; Bao, L. Y.; Xu, B.; Chen, S. Acta Chim. Sin.2008, 66, 591. [苏岳峰, 吴锋, 包丽颖, 徐斌, 陈实. 化学学报, 2008, 66, 591.]
4. [4]
  (4) Li, B. H.; Ding, S. H.; Liang, K.; Zhuang, K.; Hu, J. Electronic Components and Materials 2006, 25, 4. [李兵红, 丁士华,梁逵, 庄凯, 胡军. 电子元件与材料, 2006, 25, 4.]
5. [5]
  (5) Amatucci, G. G.; Badway, F.; Pasquier, A. D.; Zheng, T.J. Electrochem. Soc. 2001, 148, A930.
6. [6]
  (6) Morimoto, T.; Tsushima, M.; Che, Y. Hybrid Capacitors Usin rganic Electrolytes. In Electrochemical Capacitor and Hybrid Power Sources, Proceedings of the International Symposium,Philadelphia, May 12-17, 2002, Electrochemical Society: NJ,2002.
7. [7]
  (7) Conway, B. E.; Pell,W. G. J. Solid State Electrochem. 2003, 7,637. doi: 10.1007/s10008-003-0395-7
8. [8]
  (8) Khomenko, V.; Raymundo-Piñero, E.; Béguin, F. J. Power Sources 2008, 177, 643. doi: 10.1016/j.jpowsour.2007.11.101
9. [9]
  (9) Aida, T.; Yamada, K.; Morita, M. J. Electrochem. Solid-State Lett. 2006, 9 (12), A534.
10. [10]
  (10) Sivakkumar, S. R.; Pandolfo, A. G. Electrochim. Acta 2012, 65,280. doi: 10.1016/j.electacta.2012.01.076
11. [11]
  (11) Cao, G. F.; Liao, Y.; Zhang, X. H.; Chen, J. H. Acta Phys. -Chim. Sin. 2011, 27 (7), 1679. [曹国飞, 廖奕, 张小华, 陈金华. 物理化学学报, 2011, 27 (7), 1679.] doi: 10.3866/PKU.WHXB20110623
12. [12]
  (12) Sun, X. Z.; Zhang, X.; Zhang, D. C.; Ma, Y.W. Acta Phys. -Chim. Sin. 2012, 28 (2), 367. [孙现众, 张熊, 张大成, 马衍伟. 物理化学学报, 2012, 28 (2), 367.] doi: 10.3866/PKU.WHXB201112131
13. [13]
  (13) Shi, H.; Barker, J.; Koksbang, R. J. Electrochem. Soc. 1996,143, 3466. doi: 10.1149/1.1837238
14. [14]
  (14) Wu, F.; Lu, H. Q.; Su, Y. F.; Chen, S.; Guan, Y. B. Materials Science Forum 2010, 650, 142. doi: 10.4028/www.scientific.net/MSF.650.142
15. [15]
  (15) Wang, H. Y.; Masaki, Y. Electrochem. Commun. 2006, 8 (9),1481. doi: 10.1016/j.elecom.2006.07.016
16. [16]
  (16) Aurbach, D.; Markovsky, B.;Weissman, I.; Levi, E.; Ein-Eli, Y.Electrochim. Acta 1999, 45, 67. doi: 10.1016/S0013-4686(99)00194-2
17. [17]
  (17) Nicotera, I.; McLachlan, G. D.; Bennett, G. D.; Plitz, I.;Badway, F.; Amatucci, G. G.; Greenbaum, S. G. J. Electrochem. Solid-State Lett. 2007, 10 (1), A5.
18. [18]
  (18) Shu, Z. X.; McMillan, R. S.; Murray, J. J. J. Electrochem. Soc.1993, 140 (4), 922. doi: 10.1149/1.2056228
19. [19]
  (19) Dahn, J. R. Phys. Rev. B 1991, 44 (17), 9170.
20. [20]
  (20) Owejan, J. P.; Gagliardo, J. J.; Harris, S. J.;Wang, H.; Hussey,D. S.; Jacobson, D. L. Electrochim. Acta 2012, 66, 94. doi: 10.1016/j.electacta.2012.01.047
21. [21]
  (21) Aida, T.; Murayama, I.; Yamada, K.; Moritab, M.J. Electrochem. Solid-State Lett. 2007, 10 (4), A93.
22. [22]
  (22) Aida, T.; Murayama, I.; Yamada, K.; Moritab, M.J. Electrochem. Soc. 2007, 154 (8), A798.
1. [1]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
2. [2]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
3. [3]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
4. [4]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
5. [5]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
6. [6]
  Guoze Yan , Bin Zuo , Shaoqing Liu , Tao Wang , Ruoyu Wang , Jinyang Bao , Zhongzhou Zhao , Feifei Chu , Zhengtong Li , Yusuke Yamauchi , Saad Melhi , Xingtao Xu . Opportunities and Challenges of Capacitive Deionization for Uranium Extraction from Seawater. Acta Physico-Chimica Sinica, 2025, 41(4): 100032-. doi: 10.3866/PKU.WHXB202404006
7. [7]
  Xiaochen Zhang , Fei Yu , Jie Ma . 多角度数理模拟在电容去离子中的前沿应用. Acta Physico-Chimica Sinica, 2024, 40(11): 2311026-. doi: 10.3866/PKU.WHXB202311026
8. [8]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
9. [9]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
10. [10]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
11. [11]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
12. [12]
  Hong RAO , Yang HU , Yicong MA , Chunxin LÜ , Wei ZHONG , Lihua DU . Synthesis and in vitro anticancer activity of phenanthroline-functionalized nitrogen heterocyclic carbene homo- and heterobimetallic silver/gold complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2429-2437. doi: 10.11862/CJIC.20240275
13. [13]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
14. [14]
  Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2311021-. doi: 10.3866/PKU.WHXB202311021
15. [15]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
16. [16]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
17. [17]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
18. [18]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
19. [19]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
20. [20]
  Ping Ye , Lingshuang Qin , Mengyao He , Fangfang Wu , Zengye Chen , Mingxing Liang , Libo Deng . 荷叶衍生多孔碳的零电荷电位调节实现废水中电化学捕集镉离子. Acta Physico-Chimica Sinica, 2025, 41(3): 2311032-. doi: 10.3866/PKU.WHXB202311032

Get Citation

PDF

XML

Metrics

PDF Downloads(1276)
Abstract views(2565)
HTML views(17)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Electrochemical Performance of Lithium Ion Capacitors Using Li+-Intercalated Mesocarbon Microbeads as the Negative Electrode

Metrics

通讯作者: 陈斌, bchen63@163.com

Electrochemical Performance of Lithium Ion Capacitors Using Li⁺-Intercalated Mesocarbon Microbeads as the Negative Electrode