Citation: PING Li-Na, ZHENG Jia-Ming, SHI Zhi-Qiang, WANG Cheng-Yang. Electrochemical Performance of Lithium Ion Capacitors Using Li⁺-Intercalated Mesocarbon Microbeads as the Negative Electrode[J]. Acta Physico-Chimica Sinica, ;2012, 28(07): 1733-1738. doi: 10.3866/PKU.WHXB201205092 shu

Electrochemical Performance of Lithium Ion Capacitors Using Li⁺-Intercalated Mesocarbon Microbeads as the Negative Electrode

1.
1. Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P. R. China;
2. Tianjin Key Laboratory of Fiber Modification and Functional Fiber, College of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, P. R. China

Received Date: 5 March 2012
Available Online: 9 May 2012
Fund Project: 国家自然科学基金(51172160, 50902102) (51172160, 50902102)国家高技术研究发展计划项目(863) (2011AA11A232)资助 (863) (2011AA11A232)

Lithium ion capacitors (LICs) were fabricated using Li +-intercalated mesocarbon microbeads (LMCMBs) as the negative electrode and commercial activated carbon (AC) as the positive electrode. The phase structure of LMCMB electrodes was characterized by X-ray diffraction (XRD). LMCMB electrodes retain their original graphite crystal structure when the capacity induced by initial Li⁺ intercalation is less than 200 mAh·g^-1. The charge-discharge performances of positive and negative electrodes and LICs were studied using a three-electrode cell. Using an LMCMB electrode as an anode, a stable working potential is obtained at lower voltage than using other electrodes, and the potential range of the positive electrode is extended to a lower range. The electrochemical performance of LMCMB/AC capacitors, including capacitance, cycle life, and efficiency, is improved compared with that of an MCMB/AC capacitor. The efficiency increases from less than 95% to nearly 100%, and the capacity retention is improved from 74.8% to nearly 100% for 100 cycles in a voltage range of 2.0 to 3.8 V. The stable capacity of LMCMB/AC capacitors with cycling is directly correlated to less polarization of AC during the charge storage process, which is caused in turn by the LMCMB negative electrode. Gravimetric energy densities as high as 85.6 and 97.9 Wh·kg^-1 are obtained in voltage ranges of 2.0 to 3.8 V and 1.5 to 3.8 V, respectively.
- Lithium ion capacitor,
- Hybrid capacitor,
- Mesocarbon microbead,
- Activated carbon,
- Li⁺ pre-doping
1. [1]
  
  (1) Zhang, J.; Kong, L. B.; Cai, J. J.; Yang, Z. S.; Luo, Y. C.; Kang,L. Acta Phys. -Chim. Sin. 2010, 26 (6), 1515. [张晶, 孔令斌, 蔡建军, 杨贞胜, 罗永春, 康龙. 物理化学学报, 2010, 26 (6), 1515.] doi: 10.3866/PKU.WHXB20100603
2. [2]
  (2) Yuan, C. Z.; Gao, B.; Zhang, X. G. J. Power Sources 2007, 173,606. 10.1016/j.jpowsour.2007.04.034
3. [3]
  (3) Su, Y. F.;Wu, F.; Bao, L. Y.; Xu, B.; Chen, S. Acta Chim. Sin.2008, 66, 591. [苏岳峰, 吴锋, 包丽颖, 徐斌, 陈实. 化学学报, 2008, 66, 591.]
4. [4]
  (4) Li, B. H.; Ding, S. H.; Liang, K.; Zhuang, K.; Hu, J. Electronic Components and Materials 2006, 25, 4. [李兵红, 丁士华,梁逵, 庄凯, 胡军. 电子元件与材料, 2006, 25, 4.]
5. [5]
  (5) Amatucci, G. G.; Badway, F.; Pasquier, A. D.; Zheng, T.J. Electrochem. Soc. 2001, 148, A930.
6. [6]
  (6) Morimoto, T.; Tsushima, M.; Che, Y. Hybrid Capacitors Usin rganic Electrolytes. In Electrochemical Capacitor and Hybrid Power Sources, Proceedings of the International Symposium,Philadelphia, May 12-17, 2002, Electrochemical Society: NJ,2002.
7. [7]
  (7) Conway, B. E.; Pell,W. G. J. Solid State Electrochem. 2003, 7,637. doi: 10.1007/s10008-003-0395-7
8. [8]
  (8) Khomenko, V.; Raymundo-Piñero, E.; Béguin, F. J. Power Sources 2008, 177, 643. doi: 10.1016/j.jpowsour.2007.11.101
9. [9]
  (9) Aida, T.; Yamada, K.; Morita, M. J. Electrochem. Solid-State Lett. 2006, 9 (12), A534.
10. [10]
  (10) Sivakkumar, S. R.; Pandolfo, A. G. Electrochim. Acta 2012, 65,280. doi: 10.1016/j.electacta.2012.01.076
11. [11]
  (11) Cao, G. F.; Liao, Y.; Zhang, X. H.; Chen, J. H. Acta Phys. -Chim. Sin. 2011, 27 (7), 1679. [曹国飞, 廖奕, 张小华, 陈金华. 物理化学学报, 2011, 27 (7), 1679.] doi: 10.3866/PKU.WHXB20110623
12. [12]
  (12) Sun, X. Z.; Zhang, X.; Zhang, D. C.; Ma, Y.W. Acta Phys. -Chim. Sin. 2012, 28 (2), 367. [孙现众, 张熊, 张大成, 马衍伟. 物理化学学报, 2012, 28 (2), 367.] doi: 10.3866/PKU.WHXB201112131
13. [13]
  (13) Shi, H.; Barker, J.; Koksbang, R. J. Electrochem. Soc. 1996,143, 3466. doi: 10.1149/1.1837238
14. [14]
  (14) Wu, F.; Lu, H. Q.; Su, Y. F.; Chen, S.; Guan, Y. B. Materials Science Forum 2010, 650, 142. doi: 10.4028/www.scientific.net/MSF.650.142
15. [15]
  (15) Wang, H. Y.; Masaki, Y. Electrochem. Commun. 2006, 8 (9),1481. doi: 10.1016/j.elecom.2006.07.016
16. [16]
  (16) Aurbach, D.; Markovsky, B.;Weissman, I.; Levi, E.; Ein-Eli, Y.Electrochim. Acta 1999, 45, 67. doi: 10.1016/S0013-4686(99)00194-2
17. [17]
  (17) Nicotera, I.; McLachlan, G. D.; Bennett, G. D.; Plitz, I.;Badway, F.; Amatucci, G. G.; Greenbaum, S. G. J. Electrochem. Solid-State Lett. 2007, 10 (1), A5.
18. [18]
  (18) Shu, Z. X.; McMillan, R. S.; Murray, J. J. J. Electrochem. Soc.1993, 140 (4), 922. doi: 10.1149/1.2056228
19. [19]
  (19) Dahn, J. R. Phys. Rev. B 1991, 44 (17), 9170.
20. [20]
  (20) Owejan, J. P.; Gagliardo, J. J.; Harris, S. J.;Wang, H.; Hussey,D. S.; Jacobson, D. L. Electrochim. Acta 2012, 66, 94. doi: 10.1016/j.electacta.2012.01.047
21. [21]
  (21) Aida, T.; Murayama, I.; Yamada, K.; Moritab, M.J. Electrochem. Solid-State Lett. 2007, 10 (4), A93.
22. [22]
  (22) Aida, T.; Murayama, I.; Yamada, K.; Moritab, M.J. Electrochem. Soc. 2007, 154 (8), A798.
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Electrochemical Performance of Lithium Ion Capacitors Using Li+-Intercalated Mesocarbon Microbeads as the Negative Electrode

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通讯作者: 陈斌, bchen63@163.com

Electrochemical Performance of Lithium Ion Capacitors Using Li⁺-Intercalated Mesocarbon Microbeads as the Negative Electrode