Citation: MEI Yong-Jun, HAN Yi-Xiu, ZHOU Hong, YAO Lin, JIANG Bo. Synergism between Hydrophobically Modified Polyacrylic Acid and Wormlike Micelles[J]. Acta Physico-Chimica Sinica, ;2012, 28(07): 1751-1756. doi: 10.3866/PKU.WHXB201204233 shu

Synergism between Hydrophobically Modified Polyacrylic Acid and Wormlike Micelles

MEI Yong-Jun ^1,2 ,
HAN Yi-Xiu ² ,
ZHOU Hong ² ,
YAO Lin ¹ ,
JIANG Bo ^1,

1.
1. College of Chemistry, Sichuan University, Chengdu 610065, P. R. China;
2. The Second Research Institute of Civil Aviation Administration of China, Chengdu 610041, P. R. China

Received Date: 15 January 2012
Available Online: 23 April 2012
Fund Project: 国家自然科学基金-民航联合基金(60979020, 60939001)资助项目 (60979020, 60939001)

The synergism between wormlike micelles formed from sodium oleate (NaOA) and hydrophobically modified polyacrylic acid (HMPA) was investigated according to their macroscopic performances and mesoscopic scales, using a combination of viscosity/rheology measurements and dissipative particle dynamics (DPD) molecular simulations. The rheology of NaOA wormlike micelles changed significantly following the addition of a small amount of HMPA, which verified the synergistic effect between them. A peak in the apparent viscosity was observed following an increase in the concentration of HMPA, suggesting that the synergistic effect was restricted by the composition of the mixture. A DPD simulation also confirmed that the solution composition had an influence on the root mean square (RMS) end-to-end distances of HMPA, with the observed value fluctuating according to NaOA and HMPA concentrations. The micellar morphology affected the RMS end-to-end distances of HMPA and the presence of NaOA micelles exerted a significant impact on the extension of HMPA at high HMPA concentrations. A proposed synergistic mechanism has been presented according to the experimental and simulation results.
- Hydrophobically modified polyacrylic acid,
- Wormlike micelle,
- Rheology,
- Apparent viscosity,
- Dissipative particle dynamics molecular simulation,
- Root mean square end-to-end distance
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