Citation: WANG Hui, XI Yan-Yan, ZHOU Jian-Zhang, LIN Zhong-Hua. Electrochemical Synthesis of CdS Nanocrystals on a ld Electrode Modified with a p-Aminothiophenol Self-Assembled Monolayer[J]. Acta Physico-Chimica Sinica, ;2012, 28(06): 1398-1404. doi: 10.3866/PKU.WHXB201204091 shu

Electrochemical Synthesis of CdS Nanocrystals on a ld Electrode Modified with a p-Aminothiophenol Self-Assembled Monolayer

1.
1. State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005, Fujian Province, P. R. China;
2. Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China;
3. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao 266555, Shandong Province, P. R. China

Received Date: 15 December 2011
Available Online: 9 April 2012
Fund Project: 国家自然科学基金(21021002, 20973134)资助项目 (21021002, 20973134)

This work describes the electrochemical synthesis of cadmium sulfide (CdS) nanostructured films by applying a pulsed current technique on the ld electrode modified with a self-assembled p-aminothiophenol monolayer (PATP/Au). Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were used to characterize the morphology and crystal phase of the synthesized samples. An ordered array of CdS nanorods with a relatively higher c-axis preferred orientation was found on the PATP/ Au substrate. The results indicated that the size of the CdS nanorods increased with the increase in the pulse width of the pulsed current, whereas the uniformity decreased. Furthermore, the size and coverage of the CdS nanorods increased with the increase in the pulse height. Thus, the morphology and size of the prepared CdS nanorods could be controlled by adjusting the pulse width and height. Cyclic voltammetry (CV) and chronopotentiometry were also applied to investigate the mechanism of the electrodeposition of CdS on PATP/Au. In accordance with the experimental results, we suggest that the interaction of the －NH₂ in PATP molecules with Cd²⁺ in the solution may have contributed to the passing of electrons along the PATP chain following a modification of the p-aminothiophenol monolayer on the Au substrate. A formation mechanism for the electrochemically synthesized CdS nanorods on the PATP/Au substrate has consequently been proposed.
- Pulsed current technique,
- Cadmium sulfide,
- p-Aminothiophenol,
- Morphology control,
- Nanostructured film,
- Nanorod
1. [1]
  (1) Barrelet, C. J.; Greytak, A. B.; Lieber, C. M. Nano Lett. 2004, 4, 1981.
2. [2]
  (2) Schlamp, M. C.; Peng, X. G.; Alivisatos, A. P. J. Appl. Phys. 1997, 82, 5837.
3. [3]
  (3) Hirai, T.; Suzuki, K.; Komasawa, I. J. Colloid Interface Sci. 2001, 244, 262.
4. [4]
  (4) Cui, H. N.; Xi, S. Q. Thin Solid Films 1996, 288, 325.
5. [5]
  (5) Pan, A. L.; Liu, R. B.; Yang, Q.; Zhu, Y. C.; Yang, G. Z.; Zou, B. S.; Chen, K. Q. J. Phys. Chem. B 2005, 109, 24268.
6. [6]
  (6) Zhai, T. Y.; Fang, X. S.; Bando, Y.; Liao, Q.; Xu, X. J.; Zeng, H. B.; Ma, Y.; Yao, J. N.; lberg, D. ACS Nano 2009, 3, 949.
7. [7]
  (7) Cheng, Y.; Wang, Y. S.; Bao, F.; Chen, D. Q. J. Phys. Chem. B 2006, 110, 9448.
8. [8]
  (8) Liang, Y. Q.; Zhen, C. G.; Zou, D. C.; Xu, D. S. J. Am. Chem. Soc. 2004, 126, 16338. doi: 10.1021/ja044545v
9. [9]
  (9) Wang, C. Z.; E, Y. F.; Fan, L. Z.; Wang, Z. H.; Liu, H. B.; Li, Y. L.; Yang, S. H.; Lin, Y. L. Adv. Mater. 2007, 19, 3677. doi: 10.1002/adma.200701386
10. [10]
  (10) Gao, T.; Wang, T. H. J. Phys. Chem. B 2004, 108, 20045. doi: 10.1021/jp047519s
11. [11]
  (11) Hernandez-Contreras, H.; Mejía-García, C.; Contreras-Puente, G. Thin Solid Films 2004, 451 -452, 203.
12. [12]
  (12) Singh, V.; Singh, B. P.; Sharma, T. P.; Tyagi, R. C. Opt. Mater. 2002, 20, 171. doi: 10.1016/S0925-3467(02)00043-5
13. [13]
  (13) Uda, H.; Yonezawa, H.; Ohtsubo, Y.; Kosaka, M.; Sonomura, H. Sol. Energy Mater. Sol. Cells 2003, 75, 219. doi: 10.1016/S0927-0248(02)00163-0
14. [14]
  (14) Yu, S. H.; Wu, Y. S.; Yang, J.; Han, Z. H.; Xie, Y.; Qian, Y. T.; Liu, X. M. Chem. Mater. 1998, 10, 2309. doi: 10.1021/cm980181s
15. [15]
  (15) Romeo, N.; Bosio, A.; Tedeschi, R.; Canevari, V. Mater. Chem. Phys. 2000, 66, 201. doi: 10.1016/S0254-0584(00)00316-3
16. [16]
  (16) Zhang, Q. B.; Feng, Z. F.; Han, N. N.; Lin, L. L.; Zhou, J. Z.; Lin, Z. H. Acta Phys. -Chim. Sin. 2010, 26, 2927. [张桥保, 冯增芳, 韩楠楠, 林玲玲, 周剑章, 林仲华. 物理化学学报, 2010, 26, 2927.]
17. [17]
  doi: 10.3866/PKU.WHXB20101113
18. [18]
  (17) Cao, W. L.; Zhang, K. H.; Zhang, J. C. Chin. J. Inorg. Chem. 2002, 18, 997. [曹维良, 张凯华, 张敬畅. 无机化学学报, 2002, 18, 997.]
19. [19]
  (18) Xi, Y. Y.; Zhou, J. Z.; Zhang, Y.; Dong, P.; Cai, C. D.; Huang, H. G.; Lin, Z. H. Chem. J. Chin. Univ. 2004, 25, 2322. [席燕燕, 周剑章, 张彦, 董平, 蔡成东, 黄怀国, 林仲华. 高等化学学报, 2004, 25, 2322.]
20. [20]
  (19) Karami, H.; Kaboli, A. Int. J. Electrochem. Sci. 2010, 5, 706.
21. [21]
  (20) Lade, S. J.; Lokhande, C. D. Mater. Chem. Phys. 1997, 49, 160. doi: 10.1016/S0254-0584(97)01881-6
22. [22]
  (21) Kadirgan, F.; Mao, D. L.; Song, W. J.; Ohno, T.; McCandless, B. Turk. J. Chem. 2000, 24, 21.
23. [23]
  (22) Zhang, X. J.; Zhao, Q. R.; Tian, Y. P.; Xie, Y. Cryst. Growth Des. 2004, 4, 355. doi: 10.1021/cg0341555
24. [24]
  (23) Huang, H. G.; Xi, Y. Y.; Zheng, Z. X.; Yan, J. W.; Zhou, J. Z.; Wu, L. L.; Lin, Z. H. Electrochemistry 2001, 8, 195. [黄怀国, 席燕燕, 郑志新, 颜佳伟, 周剑章, 吴玲玲, 林仲华. 电化学, 2001, 8, 195.]
25. [25]
  (24) Zhang, H. P.; Luo, J.; Huang, H. G.; Wu, L. L.; Lin, Z. H. Chem. J. Chin. Univ. 1999, 20, 624. [张红平, 罗谨, 黄怀国, 吴玲玲, 林仲华. 高等学校化学学报, 1999, 20, 195.]
26. [26]
  (25) Luo, J.; Zhang, H. P.; Huang, H. G.; Wu, L. L.; Lin, Z. H. Mol. Cryst. Liq. Cryst. 1999, 337, 157. doi: 10.1080/10587259908023401
27. [27]
  (26) Huang, H. G.; Zheng, Z. X.; Luo, J.; Zhang, H. P.; Wu, L. L.; Lin, Z. H. Synth. Met. 2001, 123, 321. doi: 10.1016/S0379-6779(01)00298-3
28. [28]
  (27) Routkevitch, D.; Bigioni, T.; Moskovits, M.; Xu, J. M. J. Phys. Chem. 1996, 100, 14037. doi: 10.1021/jp952910m
29. [29]
  (28) Bicer, M.; Aydin, A. O.; Sisman, I. Electrochim. Acta 2010, 55, 3749. doi: 10.1016/j.electacta.2010.02.015
30. [30]
  (29) Baranski, A. S.; Fawcett, W. R. J. Electrochem. Soc. 1984, 131, 2509. doi: 10.1149/1.2115349
31. [31]
  (30) Nuzzo, R. G.; Allara, D. L. J. Am. Chem. Soc. 1983, 105, 4483. doi: 10.1021/ja00351a064
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