Citation: SU An-Qun, WANG Nan-Fang, LIU Su-Qin, WU Tao, PENG Sui. Modification of Carbon Paper Electrode via Hydrothermal Oxidation Applied in the Vanadium Redox Battery[J]. Acta Physico-Chimica Sinica, ;2012, 28(06): 1387-1392. doi: 10.3866/PKU.WHXB201204013 shu

Modification of Carbon Paper Electrode via Hydrothermal Oxidation Applied in the Vanadium Redox Battery

1.
School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R China

Received Date: 27 February 2012
Available Online: 1 April 2012
Fund Project: 国家重点基础研究发展规划项目(973) (2010CB227201) (973) (2010CB227201)国家自然科学基金(51072234)资助 (51072234)

To improve the electrochemical activity of electrodes in the vanadium redox battery, carbon paper electrode was treated with a hydrogen peroxide and sulfuric acid solution, according to the hydrothermal acid oxidation method, in a Teflon-lined stainless steel autoclave over different time periods at 180 °C. The water contact angle test showed that the contact angle of treated carbon paper samples changed from 120.0° to 100.8° by adjusting the treatment time from 6 to 18 h. Furthermore, a treatment time of 12 h resulted in the lowest contact angle observed, indicating that the wetting property of the carbon paper had been enhanced under these treatment conditions. Fourier transformation infrared spectroscopy results showed that oxygen-containing groups, such as the carbonyl and carboxyl groups, had been successfully introduced to the carbon papers. Scanning electron microscopy, cyclic voltammetry, electrochemical impedance spectroscopy, and charge-discharge tests were carried to characterize the surface topography and electrochemical properties of the carbon papers. The treated samples showed high activity in the redox reactions of V(IV)/V(V). A single-cell employing carbon paper was treated for 12 h as an electrode and exhibited an excellent performance. The energy efficiency reached 80% at a current density of 30 mA·cm^-2. The corresponding coulombic and voltage efficiencies were 96% and 84%, respectively.
- Vanadium redox battery,
- Carbon paper,
- Hydrothermal acid oxidation,
- Contact angle,
- Oxygen-containing group,
- Wetting property
1. [1]
  (1) Sum, E.; Rychcik, M.; Skyllas-Kazacos, M. J. Power Sources 1985, 16, 85. doi: 10.1016/0378-7753(85)80082-3
2. [2]
  (2) Sum, E.; Rychcik, M. J. Power Sources 1985, 15, 179. doi: 10.1016/0378-7753(85)80071-9
3. [3]
  (3) Skyllas-Kazacos, M.; Rychcik, M.; Robins, R. G.; Fane, A. G.; Green, M. A. J. Electrochem. Soc. 1986, 133, 1057. doi: 10.1149/1.2108706
4. [4]
  (4) Fabjan, C.; Garche, J.; Harrer, B.; Jorissen, L.; Kolbeck, C.; Philippi, F.; Tomazic,G.; Wagner, F. Electrochim. Acta 2001, 47, 825. doi: 10.1016/S0013-4686(01)00763-0
5. [5]
  (5) Joerissenl, L.; Garche, J.; Fabjan, C.; Tomazic, G. J. Power Sources 2004, 127,98. doi: 10.1016/j.jpowsour.2003.09.066
6. [6]
  (6) Kaneko, H.; Nozaki, K.; Wada, Y.; Aoki, T.; Negishi, A.; Kamimoto, M.Electrochim. Acta 1991, 36, 1191. doi: 10.1016/0013-4686(91)85108-J
7. [7]
  (7) Kamarudin, S. K.; Daud, W. R. W.; Ho, S. L.; Hasran, U. A. J. Power Sources2007, 163, 743. doi: 10.1016/j.jpowsour.2006.09.081
8. [8]
  (8) Sun, B.; Skyllas-Kazacos, M. Electrochim. Acta 1991, 36, 513. doi: 10.1016/0013-4686(91)85135-T
9. [9]
  (9) Rychcik, M.; Skallas-Kazacos, M. J. Power Sources 1987, 19, 45. doi: 10.1016/0378-7753(87)80006-X
10. [10]
  (10) Sun, B.; Skyllas-Kazacos, M. Electrochim. Acta 1992, 37, 1253. doi: 10.1016/0013-4686(92)85064-R
11. [11]
  (11) Sun, B.; Skyllas-Kazacos, M. Electrochim. Acta 1992, 37, 2459. doi: 10.1016/0013-4686(92)87084-D
12. [12]
  (12) Li, X. G.; Huang, K. L.; Liu, S. Q.; Tang, N.; Chen, L. Q. Trans-Actions of Nonferrous Metals Society of China 2007, 17, 195. doi: 10.1016/S1003-6326(07)60071-5
13. [13]
  (13) Wang, W. H.; Wang, X. D. Electrochim. Acta 2007, 52, 6755. doi: 10.1016/j.electacta.2007.04.121
14. [14]
  (14) Yue, L.; Li, W. S.; Sun, F. Q.; Zhao, L. Z.; Xing, L. D. Carbon 2010, 48, 3079. doi: 10.1016/j.carbon.2010.04.044
15. [15]
  (15) Shao, Y. Y.; Wang, Y. Q.; Engelhard, M.; Wang, C. M.; Dai, S.; Liu, J.; Yang, Z.G.; Lin, Y. H. J. Power Sources 2010, 195, 4375. doi: 10.1016/j.jpowsour.2010.01.015
16. [16]
  (16) Wu, T.; Huang, K. L.; Liu, S. Q.; Zhuang, S. X. J.; Fang, D.; Li, S.; Lu, D.; Su, A.Q. Solid State Electrochem. 2011, 16, 579.
17. [17]
  (17) Zhu, J. B.; Xu, Y. L.; Wang, J.; Wang, J. P. Acta Phys. -Chim. Sin. 2012, 28, 373.[朱剑波, 徐友龙, 王杰, 王景平. 物理化学学报, 2012, 28, 373.]
18. [18]
  doi: 10.3866/PKU.WHXB201112021
19. [19]
  (18) Jin, Y.; Chen, H. Y,; Chen, M. H.; Liu, N.; Li, Q. W. Acta Phys. -Chim. Sin.2012, 28, 609. [靳瑜, 陈宏源, 陈名海, 刘宁, 李清文. 物理化学学报, 2012,28, 609.]
20. [20]
  doi: 10.3866/PKU.WHXB201201162
21. [21]
  (19) Yang, D.; Guo, G. Q.; Hu, J. H.; Wang, C. C.; Jiang, D. L. J. Mater. Chem. 2008,18, 350. doi: 10.1039/b713467c
22. [22]
  (20) Kang, Z. H.; Wang, E. B.; Mao, B. D.; Su, Z. M.; Gao, L.; Niu, L.; Shan, H. Y.;Xu, L. Appl. Catal. A 2006, 299, 212. doi: 10.1016/j.apcata.2005.10.038
23. [23]
  (21) Zhang, L.; Yoshio, H.; Taishi, T.; Ni, Q. Q. Appl. Surf. Sci. 2011, 257, 1845. doi: 10.1016/j.apsusc.2010.08.106
24. [24]
  (22) Wu, Z. H.; Pittman, C. U., Jr.; Gardner, S. D. Carbon 1995, 33, 597. doi: 10.1016/0008-6223(95)00145-4
25. [25]
  (23) Pittman, C. U., Jr.; He, G. R.; Wu, B.; Gardner, S. D. Carbon 1997, 35, 317. doi: 10.1016/S0008-6223(97)89608-X
26. [26]
  (24) Osorio, A. G.; Silveira, I. C. L.; Bueno, V. L.; Bergmann, C. P. Appl. Surf. Sci.2008, 255, 2485. doi: 10.1016/j.apsusc.2008.07.144
27. [27]
  (25) Rasheed, A.; Howe, J. Y.; Dadmun, M. D.; Britt, P. F. Carbon 2007, 45, 1072. doi: 10.1016/j.carbon.2006.12.010
28. [28]
  (26) Chen, S. M.; Wu, G. Z.; Chen, D. Y. Nanotechnology 2006, 17, 2368. doi: 10.1088/0957-4484/17/9/048
29. [29]
  (27) Kim, Y. J.; Lee, H. J.; Lee, S. W.; Cho, B. W.; Park, C. R. Carbon 2005, 43, 163. doi: 10.1016/j.carbon.2004.09.001
30. [30]
  (28) Hsieh, C. T.; Teng, H.; Chen, W. Y.; Cheng, Y. S. Carbon 2010, 48, 4219. doi: 10.1016/j.carbon.2010.07.021
31. [31]
  (29) Chen, X. H.; Wang, J. F.; Lin, M.; Zhong, W. B.; Feng, T.; Chen, X. H.; Chen, J.H.; Xue, F. Mater. Sci. Eng. A 2007, 492, 236.
32. [32]
  (30) Cassie, A. B. D.; Baxter, S. Trans. Faraday. Soc. 1944, 40, 546. doi: 10.1039/tf9444000546
33. [33]
  (31) Giovambattista, N.; Debenedetti, P. G.; Rossky, P. J. J. Phys. Chem. B 2007, 111,9581. doi: 10.1021/jp071957s
34. [34]
  (32) Hsieh, C. T.; Teng, H. Carbon 2002, 40, 667. doi: 10.1016/S0008-6223(01)00182-8
35. [35]
  (33) Oriji, G.; Katayama, Y.; Miura, T. Electrochim. Acta 2004, 49, 3091. doi: 10.1016/j.electacta.2004.02.020
1. [1]
  Qin Li , Ziyao Jia , Ye Chen , Mingze Ma , Lin Li , Tao Huang . A Journey into the Enigmatic World of Pickering Emulsion: A Chemical Science Popularization Experiment. University Chemistry, 2024, 39(9): 311-318. doi: 10.3866/PKU.DXHX202306035
2. [2]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Ideological and Political Design of Solid-liquid Contact Angle Measurement Experiment. University Chemistry, 2024, 39(2): 28-33. doi: 10.3866/PKU.DXHX202306065
3. [3]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
4. [4]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
5. [5]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
6. [6]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
7. [7]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
8. [8]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
9. [9]
  Yueguang Chen , Wenqiang Sun . “Carbon” Adventures. University Chemistry, 2024, 39(9): 248-253. doi: 10.3866/PKU.DXHX202308074
10. [10]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
11. [11]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
12. [12]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
13. [13]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
14. [14]
  Qin Tu , Anju Tao , Tongtong Ma , Jinyi Wang . Innovative Experimental Teaching of Escherichia coli Detection Based on Paper Chip. University Chemistry, 2024, 39(6): 271-277. doi: 10.3866/PKU.DXHX202309062
15. [15]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
16. [16]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
17. [17]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
18. [18]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
19. [19]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
20. [20]
  Lei Shu , Zimin Duan , Yushen Kang , Zijian Zhao , Hong Wang , Lihua Zhu , Hui Xiong , Nan Wang . An Exploration of the CO₂-Involved Carbon Cycle World. University Chemistry, 2024, 39(5): 144-153. doi: 10.3866/PKU.DXHX202309084

Get Citation

PDF

XML

Metrics

PDF Downloads(888)
Abstract views(2421)
HTML views(49)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142