Citation: LIU Jian-Wei, ZHOU De-Feng, YANG Mei, LUO Fei, MENG Jian. Structure and Electrical Properties of M or Fe₂O₃-Doped Ce_0.8Nd_0.2O_1.9 Solid Electrolytes[J]. Acta Physico-Chimica Sinica, ;2012, 28(06): 1380-1386. doi: 10.3866/PKU.WHXB201203304 shu

Structure and Electrical Properties of M or Fe₂O₃-Doped Ce_0.8Nd_0.2O_1.9 Solid Electrolytes

LIU Jian-Wei ¹ ,
ZHOU De-Feng ^1, ,
YANG Mei ¹ ,
LUO Fei ¹ ,
MENG Jian ²

1.
1. School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, P. R. China;
2. State Key Laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China

Received Date: 14 December 2011
Available Online: 30 March 2012
Fund Project: 国家自然科学基金(20871023) (20871023)吉林省科技发展计划项目(20101549)资助 (20101549)

A precursor powder of Ce_0.8Nd_0.2O_1.9 (NDC) containing 0.05% (mass fraction) SiO₂ as an impurity (NDCSi) was doped with 0-2.0% (molar fraction) M or FeO_1.5 via the sol-gel method. After pressing at 10 MPa, the samples were sintered at 1300 ° C for 6 h. The structure of the pellets was characterized by X-ray diffraction (XRD), Raman spectroscopy, and field emission scanning electron microscopy (FE-SEM). The electrical conductivity of the pellets was measured using AC impedance spectroscopy. All of the samples exhibited a cubic fluorite structure. Doping with M or Fe₂O₃ lowered the sintering temperature, and increased the density, grain boundaries and total conductivity of NDCSi. The relative density of the samples doped with Fe₂O₃ or M (>93%) was higher than those of NDC or NDCSi (about 86%), suggesting these dopants are effective at promoting densification. NDCSi + 0.5FeO_1.5 and NDCSi + 2.0M samples exhibited the highest conductivities of 0.63 × 10^-2 and 0.29 × 10^-2 S · cm^-1, respectively, which are 5.7 and 2.6 times larger than that of NDCSi (0.11×10^-2 S·cm^-1) at 550 °C. Doping with M or Fe₂O₃ had a larger effect on the grain boundary conductivity of SDCSi than the bulk conductivity. These results indicate that M and Fe₂O₃ are effective sintering aids as well as grain boundary scavengers with different mechanisms.
- Solid electrolyte,
- Neodymium-doped ceria,
- Grain boundary scavenger,
- Electrical conductivity,
- Sintering aid
1. [1]
  (1) Zhang, T. S.; Du, Z. H.; Li, S.; Kong, L. B.; Song, X. C.; Lu, J.; Ma, J. Soild State Ionics 2009, 180, 1311. doi: 10.1016/j.ssi.2009.08.004
2. [2]
  (2) Li, B.; Liu, Y. Y.; Wei, X.; Pan, W. J. Power Sources 2010, 195, 969. doi: 10.1016/j.jpowsour.2009.09.001
3. [3]
  (3) Zhang, T. S.; Ma, J.; Leng, Y. J.; Chan, S. H.; Hing, P.; Kilner, J. A. Solid State Ionics 2004, 168, 187. doi: 10.1016/j.ssi.2004.02.015
4. [4]
  (4) Duan, T.; Yan, X. M.; Liu, X. Y.; Bai, L.; Pei, Zheng, M. Z.; Zhu, C. J.; Wang, D. J.; Su, W. H. J. Power Sources 2010, 195, 6488.
5. [5]
  (5) Molenda, J.; Swierczek, K.; Zajac, W. J. Power Sources 2007, 173, 660.
6. [6]
  (6) Steele, B. C. H. Solid State Ionics 2000, 129, 95. doi: 10.1016/S0167-2738(99)00319-7
7. [7]
  (7) Jennifer, L. M. R.; Anna, I.; Ludwig,; J. G. Acta Mater 2006, 54, 1721. doi: 10.1016/j.actamat.2005.11.032
8. [8]
  (8) Gerhardt, R.; Nowick, A. S.; Mochel, M. E.; Dumler, I. J. Am. Ceram. Soc. 1986, 69, 641. doi: 10.1111/j.1151-2916.1986.tb07464.x
9. [9]
  (9) Guo, X.; Waser, R. Prog. Mater. Sci. 2006, 51, 151. doi: 10.1016/j.pmatsci.2005.07.001
10. [10]
  (10) Wojciech, Z.; Leopoldo, S.; Konrad, S.; Janina, M. J. Power Soures 2009, 194, 2. doi: 10.1016/j.jpowsour.2008.12.020
11. [11]
  (11) Zhang, T. S.; Ma, J.; Kong, L. B.; Hing, P.; Leng, Y. J.; Chan, S.H.; Kilner, J. A. J. Power Sources 2003, 124, 26. doi: 10.1016/S0378-7753(03)00625-6
12. [12]
  (12) Park, H. J.; Choi, G. M. Solid State Ionics 2008, 178, 1746. doi: 10.1016/j.ssi.2007.12.003
13. [13]
  (13) Xu, H. M.; Yan, H. G.; Chen, Z. H. Powder Metallurgy Technology 2008, 26, 443. [徐红梅, 严红革, 陈振华. 粉末冶金技术, 2008, 26, 443.]
14. [14]
  (14) Zhang, T. S.; Ma, J.; Chan, S. H.; Kilner, J. A. Solid State Ionics 2005, 176, 377. doi: 10.1016/j.ssi.2004.07.022
15. [15]
  (15) Xu, D.; Liu, X. M.; Xu, S. F.; Yan, D. T.; Pei, L.; Zhu, C. J.; Wang, D. J.; Su, W. H. Solid State Ionics 2011, 192, 510. doi: 10.1016/j.ssi.2010.03.026
16. [16]
  (16) Zhang, T. S.; Ma, J.; Leng, Y. J.; Chan, S. H.; Hing, P.; Kilner, J. A. Solid State Ionics, 2004, 167, 203. doi: 10.1016/j.ssi.2004.01.006
17. [17]
  (17) Cho, P. S.; Cho, Y. H.; Park, S. Y.; Lee, S. B.; Kim, D. Y.; Park, H. M.; G. A.; J. D.; Lee, J. H. J. Electrochem. Soc. 2009, 3, 339.
18. [18]
  (18) Yan, M.; Mori, T.; Zou, J.; Auchterlonie, G. J.; Drennan, J. J. Eur. Ceram. Soc. 2010, 30, 2505. doi: 10.1016/j.jeurceramsoc.2010.04.036
19. [19]
  (19) Li, B.; Wei, X.; Pan, W. J. Power Sources 2008, 183, 498. doi: 10.1016/j.jpowsour.2008.05.050
20. [20]
  (20) Cho, Y. H.; Cho, P. S.; Auchter, G.; Kim, D. K.; Lee, J. H.; Kim, D. Y.; Park, H. M.; Drennan, J. Acta Mater. 2007, 55, 4807. doi: 10.1016/j.actamat.2007.05.001
21. [21]
  (21) Wang, F. Y.; Wan, B. Z.; Cheng, S. J. Solid State Electrochem. 2005, 9, 168. doi: 10.1007/s10008-004-0575-0
22. [22]
  (22) Zheng, Y. F.; Zhou, M.; Ge, L.; Li, S. J.; Chen, H.; Guo, L. C. J. Alloy. Compd. 2011, 509, 546. doi: 10.1016/j.jallcom.2010.09.103
23. [23]
  (23) Zhang, T. S.; Hing P.; Huang, H. T.; Kilner, J. A. J. Mater. Sci. 2002, 37, 997. doi: 10.1023/A:1014362000128
24. [24]
  (24) McBride, J. R.; Hass, K. C.; Poindexter, B. D.; Weber, W. H.; J. Appl. Phys. 1994, 76, 2435. doi: 10.1063/1.357593
25. [25]
  (25) Dong, Q.; Du, Z. H.; Zhang, T. S.; Lu, J.; Song, X. C.; Ma, J. Int. J. Hydrog. Energy 2009, 34, 7908.
26. [26]
  (26) Ma, Z. F.; Liang, G. C.; Liang, J. S. Acta Phys. -Chim. Sin. 2005, 21, 666. [马志芳, 梁广川, 梁金生. 物理化学学报, 2005, 21, 666.]
1. [1]
  Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021
2. [2]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057
3. [3]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
4. [4]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
5. [5]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
6. [6]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
7. [7]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
8. [8]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
9. [9]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
10. [10]
  Siwei Lv , Tantian Tan , Xinyue Li , Siyan Zhang , Mingyuan Zhang , Minghao Li , Hangshuo Guo , Zhaorong Li , Liangjie Dong , Fengshuo Zhang , Junlong Zhao . Competition of the “King of Transboundary Medicine”. University Chemistry, 2024, 39(9): 102-108. doi: 10.12461/PKU.DXHX202403034
11. [11]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
12. [12]
  Hongling Yuan , Jialin Xie , Jiawei Wang , Jixiang Zhao , Jiayan Liu , Qing Feng , Wei Qi , Min Liu . Cyclic Olefin Copolymer (COC): The Agile Vanguard in the Realm of Materials. University Chemistry, 2024, 39(7): 294-298. doi: 10.12461/PKU.DXHX202311041
13. [13]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
14. [14]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
15. [15]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
16. [16]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
17. [17]
  Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066
18. [18]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
19. [19]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
20. [20]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009

Get Citation

PDF

XML

Metrics

PDF Downloads(853)
Abstract views(2209)
HTML views(12)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Structure and Electrical Properties of M or Fe2O3-Doped Ce0.8Nd0.2O1.9 Solid Electrolytes

Metrics

通讯作者: 陈斌, bchen63@163.com

Structure and Electrical Properties of M or Fe₂O₃-Doped Ce_0.8Nd_0.2O_1.9 Solid Electrolytes