Citation: JIAO Ti-Feng, LIU Ming-Hua. Phase Behaviors and 2D-3D Morphological Transition of Aromatic Schiff Base Derivatives in Organized Molecular Films[J]. Acta Physico-Chimica Sinica, ;2012, 28(06): 1418-1424. doi: 10.3866/PKU.WHXB201203291 shu

Phase Behaviors and 2D-3D Morphological Transition of Aromatic Schiff Base Derivatives in Organized Molecular Films

JIAO Ti-Feng ^1,2, ,
LIU Ming-Hua ^2,

1.
1. Hebei Key Laboratory of Applied Chemistry, School of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004, Hebei Province, P. R. China;
2. CAS Key Laboratory of Colloid and Interface Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received Date: 9 March 2012
Available Online: 29 March 2012
Fund Project: 国家自然科学基金(20903078) (20903078) 中国博士后科学基金(2011M500540) (2011M500540) 河北省留学回国人员科技择优资助经费(2011052) (2011052)河北省高校百名优秀创新人才支持计划(CPRC020)资助 (CPRC020)

A novel aromatic Schiff base ligand has been designed and its interfacial phase behavior as well as its in situ coordination with Cu(II) ions on the surface of pure water was compared with those of the corresponding pre-synthesized Cu(II) complex. Surface pressure-area isotherms, ultraviolet-visible spectroscopy, Fourier transform infrared spectroscopy, and atomic force microscopy were used to characterize deposited monolayer and multilayer films of the complexes. Both the ligand and corresponding complex formed stable monolayer or multilayer films at the air/water interface, which could be subsequently transferred onto solid substrates to construct Langmuir-Blodgett films. A novel phase transition was observed when the ligand was spread on the surface of pure water. During this phase transition, the two-dimensional (2D) flat film changed into three-dimensional (3D) fiber-like nanoarchitectures. However, upon coordination with Cu(II) ions, only flat films were obtained. This phenomenon was thought to be caused by the change of molecular conformation and/or hydrophobicity during supramolecular assembly at the air/water interface. This work provides a simple clue for regulating the nanostructures in organized films.
- Organized molecular film,
- Air/liquid interface,
- Schiff base,
- Phase transition,
- Assembly
1. [1]
  (1) Ghosh, A.; Mahato, P.; Choudhury, S.; Das, A. Thin Solid Films 2011, 519, 8066. doi: 10.1016/j.tsf.2011.02.082
2. [2]
  (2) Giancane, G.; Filippo, E.; Manno, D.; Serra, A.; Valli, L. J. Colloid Interface Sci. 2011, 363, 199. doi: 10.1016/j.jcis.2011.06.054
3. [3]
  (3) Arya, S. K.; Solanki, P. R.; Datta, M.; Malhotra, B. D. Biosens. Bioelectron. 2009, 24, 2810. doi: 10.1016/j.bios.2009.02.008
4. [4]
  (4) Ariga, K.; Lvov, Y. M.; Kawakami, K.; Ji, Q.; Hill, J. P. Adv. Drug Deliv. Rev. 2011, 63, 762. doi: 10.1016/j.addr.2011.03.016
5. [5]
  (5) Mohnani, S.; Bonifazi, D. Coordin. Chem. Rev. 2010, 254, 2342. doi: 10.1016/j.ccr.2010.05.006
6. [6]
  (6) Zhang, H.; Xin, F.; An, W.; Hao, A.; Wang, X.; Zhao, X.; Liu, Z.; Sun, L. Colloids Surf. A: Physicochem. Eng. Aspects 2010, 363, 78. doi: 10.1016/j.colsurfa.2010.04.017
7. [7]
  (7) Yin, S.; Sun, H.; Yan, Y.; Zhang, H.; Li, W.; Wu, L. J. Colloid Interface Sci. 2011, 361, 548. doi: 10.1016/j.jcis.2011.06.006
8. [8]
  (8) Zhavnerko, G.; Marletta, G. Mater. Sci. Eng. B 2010, 169, 43. doi: 10.1016/j.mseb.2009.12.005
9. [9]
  (9) Pavinatto, F. J.; Gameiro Jr., A. F.; Hidal , A. A.; Dinelli, L. R.; Romualdo, L. L.; Batista, A. A.; Barbosa Neto, N. M.; Ferreira, M.; Oliveira Jr., O. N. Appl. Surf. Sci. 2008, 254, 5946. doi: 10.1016/j.apsusc.2008.03.162
10. [10]
  (10) Jin, Y.; Chen, S.; Xin, R.; Zhou, Y. Colloids Surf. B: Biointerf. 2008, 64, 229. doi: 10.1016/j.colsurfb.2008.01.023
11. [11]
  (11) Liu, Y. L.; Wang, W. J.; Gao, X. X.; Xu J. H. Acta Phys. -Chim. Sin. 2011, 27 (8), 1985. [刘云龙, 王文军, 高学喜, 徐建华. 物理化学学报, 2011, 27 (8), 1985.]
12. [12]
  (12) Deng, S. P.; Ouyang, J. H. Acta Phys. -Chim. Sin. 2007, 23 (5), 713. [邓穗平, 欧阳健明. 物理化学学报, 2007, 23 (5), 713.]
13. [13]
  (13) Xu, B.; Wang, Y.; Zhang, Y. F. J. Chem. Eng. Chin. Univ. 2008, 29 (7), 1317. [徐斌, 王英, 张亚非. 高等学校化学学报, 2008, 29 (7), 1317.]
14. [14]
  (14) Gleiche, M.; Chi, L. F.; Fuchs, H. Nature 2000, 403, 173. doi: 10.1038/35003149
15. [15]
  (15) Chen, X.; Hirtz, M.; Fuchs, H.; Chi, L. Langmuir 2007, 23, 2280. doi: 10.1021/la062938x
16. [16]
  (16) Pignataro, B.; Sardone, L.; Marletta, G. Langmuir 2003, 19, 5912. doi: 10.1021/la034557e
17. [17]
  (17) Moraille, P.; Badia, A. Langmuir 2003, 19, 8041. doi: 10.1021/la034727n
18. [18]
  (18) ng, A.; Liu, Y.; Liu, M.; Xi, F. Thin Solid Films 2002, 406, 228. doi: 10.1016/S0040-6090(01)01786-2
19. [19]
  (19) Jiao, T.; Zhou, J.; Liu, M.; Wang, S.; Zhou, J. X.; Zhang, F. J. Dispersion Sci. Technol. 2010, 31, 1120. doi: 10.1080/01932690903224789
20. [20]
  (20) Rousso, L.; Friedman, N.; Sheves, M.; Ottolenghi, M. Biochemistry 1995, 34, 12059. doi: 10.1021/bi00037a049
21. [21]
  (21) Das, K.; Sarkar, N.; Ghosh, A. K.; Majumdar, D.; Nath, D. N.; Bhattacharya, K. J. Phys. Chem. 1994, 98, 9126. doi: 10.1021/j100088a006
22. [22]
  (22) Fores, M.; Duran, M.; Sola, M. J. Phys. Chem. A 1999, 103, 4525. doi: 10.1021/jp984773+
23. [23]
  (23) Acuna, A. U.; Amat Guerri, F.; Costela, A.; Douhal, A.; Figuera, J. M.; Florido, F.; Sastre, R. Chem. Phys. Lett. 1991, 187, 98. doi: 10.1016/0009-2614(91)90491-Q
24. [24]
  (24) Jiao, T.; Zhou, J.; Zhou, J. X.; Gao, L.; Xing, Y.; Li, X. Iran. Polym. J. 2011, 20, 123.
25. [25]
  (25) Sundari, S. S.; Dhathathreyan, A.; Kanthimathi, M.; Nair, B. U. Langmuir 1997, 13, 4923. doi: 10.1021/la970125q
26. [26]
  (26) Vijayalakshmi, R.; Dhathathreyan, A.; Kanthimathi, M.; Subramanian, V.; Nair, B. U.; Ramasami, T. Langmuir 1999, 15, 2898. doi: 10.1021/la9807356
27. [27]
  (27) Nagel, J.; Oertel, U.; Friedel, P.; Komber, H.; Mobius, D. Langmuir 1997, 13, 4693. doi: 10.1021/la9621269
28. [28]
  (28) Liang, Y. Q.; Zhang, Z.; Wu, L.; Tian, Y.; Chen, H. J. Colloid Interface Sci. 1996, 178, 714. doi: 10.1006/jcis.1996.0169
29. [29]
  (29) Liang, Y. Q.; Wu, L.; Tian, Y.; Zhang, Z.; Chen, H. J. Colloid Interface Sci. 1996, 178, 703. doi: 10.1006/jcis.1996.0168
30. [30]
  (30) Yin, M.; Jiao, T.; Liu, M. Chin. Chem. Lett. 2007, 18, 30. doi: 10.1016/j.cclet.2006.11.008
31. [31]
  (31) Jiao, T.; Liu, M. J. Phys. Chem. B 2005, 109, 2532. doi: 10.1021/jp045258g
32. [32]
  (32) Jiao, T.; Liu, M. J. Colloid Interface Sci. 2006, 299, 815. doi: 10.1016/j.jcis.2006.02.037
33. [33]
  (33) Jiao, T.; Liu, M. Langmuir 2006, 22, 5005. doi: 10.1021/la060343w
34. [34]
  (34) Jiao, T.; Zhang, G.; Liu, M. J. Phys. Chem. B 2007, 111, 3090. doi: 10.1021/jp067287s
35. [35]
  (35) Toksoz, S.; Mammadov, R.; Tekinay, A. B.; Guler, M. O. J. Colloid Interface Sci. 2011, 356, 131. doi: 10.1016/j.jcis.2010.12.076
36. [36]
  (36) Al-Saleh, M. H.; Sundararaj, U. Carbon 2009, 47, 2. doi: 10.1016/j.carbon.2008.09.039
37. [37]
  (37) Lu, X. J.; Dou, H.; Yang, S. D.; Hao, L.; Zhang, F.; Zhang, X. G. Acta Phys. -Chim. Sin. 2011, 27 (10), 2333. [卢向军, 窦辉, 杨苏东, 郝亮, 张方, 张校刚. 物理化学学报, 2011, 27 (10), 2333.]
38. [38]
  (38) Li, Y. J.; Cao, T. P.; Wang, C. H.; Shao, C. L. J. Chem. Eng. Chin. Univ. 2011, 32 (11), 2490. [李跃军, 曹铁平, 王长华, 邵长路. 高等学校化学学报, 2011, 32 (11), 2490.]
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