Citation: WANG Yu, DONG Hui, GENG Liang, YU Gang, ZHU Yue-Xiang, XIE You-Chang. Facile Synthesis of Bimodal Mesoporous Carbon with Thin Pore Walls[J]. Acta Physico-Chimica Sinica, ;2012, 28(06): 1525-1532. doi: 10.3866/PKU.WHXB201203271 shu

Facile Synthesis of Bimodal Mesoporous Carbon with Thin Pore Walls

1.
Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 9 November 2011
Available Online: 27 March 2012
Fund Project: 国家自然科学基金(20773004) (20773004)国家重点基础研究发展规划项目(973) (2011CB808702)资助 (973) (2011CB808702)

Mesoporous carbon materials are required for application in various areas. In our previous work, we successfully prepared mesoporous carbon with thin pore walls using inexpensive γ-alumina as a template and sucrose as the carbon source, and proposed a mechanism for the synthetic process. In this work, other carbon source was explored to improve the synthetic process and obtain a better understanding of the synthetic mechanism. Compared with sucrose, phenolic resin generated in situ as the carbon precursor can form a complete and robust carbon layer on the template surface in one polymerization and carbonization procedure, simplifying the synthetic process. In addition, the specific surface areas of the carbon materials were greatly increased when phenolic resin was used as the carbon precursor. According to the proposed synthetic mechanism, the mesopores of the carbon materials had two sources: the removal of template particles, and the original pores of the template. When the size of template pores differed significantly from that of the template particles, the obtained carbon materials possessed a bimodal pore size distribution (PSD) at about 4 and 13 nm. In this work, carbon material with a bimodal PSD in the mesopore range was obtained when thin, rod-like alumina was used as the template. The carbon materials possessed ultra large specific surface area (>1800 m²·g^-1) and pore volume (>4.5 cm³·g^-1), so they were used as electrodes for electric double-layer capacitors. Cyclic voltammograms were nearly rectangular even at a high sweep rate (50 mV·s^-1), and the capacitances were relatively high (about 200 F·g^-1). When the current density was increased from 0.1 A·g^-1 to 1.0 A·g^-1, the decrease in specific capacitance was only 10%.
- Mesoporous carbon,
- Thin pore wall,
- Controllable synthesis,
- Bimodal pore size distribution,
- Phenolic resin,
- Electric double-layer capacitor
1. [1]
  (1) Liang, C. D.; Li, Z. J.; Dai, S. Angewandte Chemie International Edition 2008, 47, 3696. doi: 10.1002/anie.200702046
2. [2]
  (2) Lee, J.; Kim, J.; Hyeon, T. Advanced Materials 2006, 18, 2073. doi: 10.1002/adma.200501576
3. [3]
  (3) Han, S.; Sohn, K.; Hyeon, T. Chemistry of Materials 2000, 12, 3337. doi: 10.1021/cm000106t
4. [4]
  (4) Vinu, A.; Streb, C.; Murugesan, V.; Hartmann, M. Journal of Physical Chemistry B 2003, 107, 8297. doi: 10.1021/jp035246f
5. [5]
  (5) Zhuang, X.; Wan, Y.; Feng, C. M.; Shen, Y.; Zhao, D. Y. Chemistry of Materials 2009, 21, 706. doi: 10.1021/cm8028577
6. [6]
  (6) Joo, S. H.; Choi, S. J.; Oh, I.; Kwak, J.; Liu, Z.; Terasaki, O.; Ryoo, R. Nature 1999, 412, 169.
7. [7]
  (7) Xing, W.; Qiao, S. Z.; Ding, R. G.; Li, F.; Lu, G. Q.; Yan, Z. F.; Cheng, H. M. Carbon 2006, 44, 216. doi: 10.1016/j.carbon.2005.07.029
8. [8]
  (8) Li, L. X.; Song, H. H.; Chen, X. H. Electrochim. Acta 2006, 51, 5715. doi: 10.1016/j.electacta.2006.03.005
9. [9]
  (9) Ji, Q. Q.; Guo, P. Z.; Zhao, X. S. Acta Phys. -Chim. Sin.2010, 26, 1254. [季倩倩, 郭培志, 赵修松. 物理化学学报, 2010, 26, 1254.]
10. [10]
  doi: 10.3866/PKU.WHXB20100330
11. [11]
  (10) Jia, Z. H.; Liang, S. G.; Jiang, Y. B.; Li, H.; Liu, Z. M.; Zhao, T. Carbon 2009, 47, 2194. doi: 10.1016/j.carbon.2009.04.001
12. [12]
  (11) Geng, L.; Wang, Y.; Yu, G.; Zhu, Y. X. Catalysis Communications 2011, 13, 26. doi: 10.1016/j.catcom.2011.06.014
13. [13]
  (12) Hao, G. P.; Li, W. C.; Wang, S.; Zhang, S. F.; Lu, A. H. Carbon 2010, 48, 3330. doi: 10.1016/j.carbon.2010.05.011
14. [14]
  (13) Wang, D. W.; Li, F.; Liu, M.; Lu, G. Q.; Cheng, H. M. Angewandte Chemie International Edition 2008, 47, 373. doi: 10.1002/anie.200702721
15. [15]
  (14) Xu, H.; Gao, Q. M.; Guo, H. L.; Wang, H. L. Microporous and Mesoporous Materials 2010, 133, 106. doi: 10.1016/j.micromeso.2010.04.021
16. [16]
  (15) Tashima, D.; Yamamoto, E.; Kai, N.; Fujikawa, D.; Sakai, G.; Otsubo, M.; Kijima, T. Carbon 2011, 49, 4848. doi: 10.1016/j.carbon.2011.07.005
17. [17]
  (16) He, G.; Ji, X. L.; Nazar, L. Energy & Environmental Science 2011, 4, 2878. doi: 10.1039/c1ee01219c
18. [18]
  (17) Kwon, T. H.; Jung, S.; Kim, H. J.; Park, S.; Kim, S. J.; Huh, S. European Journal of Inorganic Chemistry 2009, 2811.
19. [19]
  (18) Meng, Y.; Gu, D.; Zhang, F. Q.; Shi, Y. F.; Cheng, L.; Feng, D.; Wu, Z. X.; Chen, Z. X.; Wan, Y.; Stein, A.; Zhao, D. Y. Chemistry of Materials 2006, 18, 4447. doi: 10.1021/cm060921u
20. [20]
  (19) Ryoo, R.; Joo, S. H.; Jun, S. Journal of Physical Chemistry B 1999, 103, 7743. doi: 10.1021/jp991673a
21. [21]
  (20) Lee, J.; Yoon, S.; Hyeon, T.; Oh, S. M.; Kim, K. B. Chemical Communications 1999, 2177.
22. [22]
  (21) Jun, S.; Joo, S. H.; Ryoo, R.; Kruk, M.; Jaroniec, M.; Liu, Z.; Ohsuna, T.; Terasaki, O. Journal of the American Chemical Society 2000, 122, 10712. doi: 10.1021/ja002261e
23. [23]
  (22) Lee, J. S.; Joo, S. H.; Ryoo, R. Journal of the American Chemical Society 2002, 124, 1156. doi: 10.1021/ja012333h
24. [24]
  (23) Lu, A. H.; Schmidt, W.; Spliethoff, B.; Schüth, F. Advanced Materials 2003, 15, 1602. doi: 10.1002/adma.200305176
25. [25]
  (24) Pang, J. B.; Hu, Q. Y.; Wu, Z. W.; Hampsey, J. E.; He, J. B.; Lu, Y. F. Microporous and Mesoporous Materials 2004, 74, 73. doi: 10.1016/j.micromeso.2004.06.009
26. [26]
  (25) Wang, Y.; Yu, G.; Cai, B.; Zhu, Y. X.; Xie, Y. C. Acta Phys. -Chim. Sin.2011, 27, 729. [王羽, 魁罡, 蔡斌, 朱月香, 谢有畅. 物理化学学报, 2011, 27, 729.]
27. [27]
  doi: 10.3866/PKU.WHXB20110321
28. [28]
  (26) Wu, D. C.; Fu, R. W. Microporous and Mesoporous Materials 2006, 96, 115. doi: 10.1016/j.micromeso.2006.06.022
29. [29]
  (27) Choma, J.; rka, J.; Jaroniec, M.; Zawislak, A. Topics in Catalysis 2010, 53, 283. doi: 10.1007/s11244-009-9407-x
1. [1]
  Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060
2. [2]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
3. [3]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
4. [4]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
5. [5]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
6. [6]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
7. [7]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
8. [8]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
9. [9]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
10. [10]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
11. [11]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
12. [12]
  Shuhui Li , Xucen Wang , Yingming Pan . Exploring the Role of Electrochemical Technologies in Everyday Life. University Chemistry, 2025, 40(3): 302-307. doi: 10.12461/PKU.DXHX202406059
13. [13]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
14. [14]
  Cen Zhou , Biqiong Hong , Yiting Chen . Application of Electrochemical Techniques in Supramolecular Chemistry. University Chemistry, 2025, 40(3): 308-317. doi: 10.12461/PKU.DXHX202406086
15. [15]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072
16. [16]
  Jingwen Wang , Minghao Wu , Xing Zuo , Yaofeng Yuan , Yahao Wang , Xiaoshun Zhou , Jianfeng Yan . Advances in the Application of Electrochemical Regulation in Investigating the Electron Transport Properties of Single-Molecule Junctions. University Chemistry, 2025, 40(3): 291-301. doi: 10.12461/PKU.DXHX202406023
17. [17]
  Ping Ye , Lingshuang Qin , Mengyao He , Fangfang Wu , Zengye Chen , Mingxing Liang , Libo Deng . 荷叶衍生多孔碳的零电荷电位调节实现废水中电化学捕集镉离子. Acta Physico-Chimica Sinica, 2025, 41(3): 2311032-. doi: 10.3866/PKU.WHXB202311032
18. [18]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
19. [19]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
20. [20]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022

Get Citation

PDF

XML

Metrics

PDF Downloads(822)
Abstract views(2342)
HTML views(62)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142