Citation: HU Wen-Liang, XU Gang, MA Jian-Wei, XIONG Bin, SHI Ji-Fu. Optical and Phase Transition Properties of Ti_xV_1-xO₂ Thin Films[J]. Acta Physico-Chimica Sinica, ;2012, 28(06): 1533-1538. doi: 10.3866/PKU.WHXB201203191 shu

Optical and Phase Transition Properties of Ti_xV_1-xO₂ Thin Films

HU Wen-Liang ^1,2,3 ,
XU Gang ^1,2, ,
MA Jian-Wei ^1,2,4 ,
XIONG Bin ^1,2,3 ,
SHI Ji-Fu ^1,2

1.
1. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, P. R. China;
2. Key Laboratory of Renewable Energy and Gas Hydrate, Chinese Academy of Sciences, Guangzhou 510640, P. R. China;
3. Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
4. Civil Engineering Institute, Northeast Petroleum University, Daqing 163318, Heilongjiang Province, P. R. China

Received Date: 13 December 2011
Available Online: 19 March 2012
Fund Project: 国家自然科学基金(51102235) (51102235) 广东省产学研结合计划(2010B090400109) (2010B090400109)广东省中国科学院全面战略合作计划(2011B090300044)资助项目 (2011B090300044)

Ti_xV_1-xO₂ (0≤x≤1) thin films with different molar ratios of V/Ti were prepared on c-plane sapphire (0001) substrates by radio frequency magnetron sputtering. The microstructure and optical properties of the thin films were determined by X-ray diffraction (XRD), Raman spectroscopy, and UV-visible-near infrared (UV-Vis-NIR) spectroscopy. The width of the optical band gap was calculated and the integrated solar transmittance of the films was characterized. As the content of titanium was increased, infrared regulation and thermal hysteresis were gradually reduced until they disappeared. The results show that the band gap of the thin films broadens as the content of titanium increases, causing the optical absorption edge to exhibit a blue shift. Conversely, the band gap narrows as the proportion of vanadium is increased, which causes a red shift of the optical absorption edge.
- VO₂ thin film,
- TiO₂ thin film,
- Magnetron sputtering,
- Optical property,
- Phase transition property
1. [1]
  (1) Morin, F. J. Phys. Rev. Lett. 1959, 3, 34. doi: 10.1103/PhysRevLett.3.34
2. [2]
  (2) Cavalleri, A.; Tóth, Cs.; Siders, C. W.; Squier, J. A.; Ráksi, F.; Forget, P.; Kieffer, J. C. Phys. Rev. Lett. 2001, 87, 237401. doi: 10.1103/PhysRevLett.87.237401
3. [3]
  (3) Béteille, F.; Livage, J. J. Sol-Gel. Sci. Technol. 1998, 13, 915. doi: 10.1023/A:1008679408509
4. [4]
  (4) He, Y. F.; Xu, G.; Zhu, J.; Cheng, D. M.; Wang, C. P. Micronanoelectronic Technology. 2008, 45, 387. [何云富, 徐刚, 朱俊, 陈德明, 王春平.微纳电子技术, 2008, 45, 387.]
5. [5]
  (5) Xu, G.; Jin, P.; Tazawa, M.; Yoshimura, K. Sol. Energy Mater. Sol. Cells. 2004, 83, 29. doi: 10.1016/j.solmat.2004.02.014
6. [6]
  (6) Christmann, T.; Felde, B.; Niessner, W.; Schalch, D.; Scharmann, A. Thin Solid Films 1996, 287, 134. doi: 10.1016/S0040-6090(96)08770-6
7. [7]
  (7) Du, J.; Gao, Y. F.; Luo, H. G.; Zhang, Z. T.; Kang, L. T.; Chen, Z. Sol. Energy Mater. Sol. Cells 2011, 95, 1604. doi: 10.1016/j.solmat.2011.01.009
8. [8]
  (8) Burkhardt, W.; Christmann, T.; Franke, S.; Kriegseis, W.; Meister, D.; Meyer, B. K.; Niessner, W.; Schach, D.; Scharmann, A. Thin Solid Films 2002, 402, 226. doi: 10.1016/S0040-6090(01)01603-0
9. [9]
  (9) Soltani, M.; Chaker, M.; Haddad, E.; Kruzelecky, R. V.; Mar t, J. Appl. Phys. Lett. 2004, 85, 1958. doi: 10.1063/1.1788883
10. [10]
  (10) Du, J.; Gao, Y. F.; Luo, H. J.; Kang, L. T.; Zhang, Z. T.; Chen, Z.; Cao, C. X. Sol. Energy Mater. Sol. Cells. 2011, 95, 469. doi: 10.1016/j.solmat.2010.08.035
11. [11]
  (11) Kakiuchida, H.; Jin, P.; Tazawa, M. Thin Solid Films 2008, 516, 4563. doi: 10.1016/j.tsf.2007.05.096
12. [12]
  (12) Zhao, G. L.; Han, G. R.; Takahashi, M.; Yoko, T. Thin Solid Films 2002, 410, 14. doi: 10.1016/S0040-6090(02)00252-3
13. [13]
  (13) Fujishima, A.; Zhang, X. T.; Tryk, D. A. Surf. Sci. Rep. 2008, 63, 515. doi: 10.1016/j.surfrep.2008.10.001
14. [14]
  (14) Zhang, X. Y.; Chao, M. J.; Liang, E. J.; Hu, F.; Yuan, F. Journal of Inorganic Materials. 2009, 24, 34. [张晓勇, 晁明举, 梁二军, 胡帆, 袁斌. 无机材料学报, 2009, 24, 34.] doi: 10.3724/SP.J.1077.2009.00034
15. [15]
  (15) Zhang, X. R.; Lin, Y. H.; Zhang, J. F.; He, D. Q.; Wang, D. J. Acta Phys. -Chim. Sin. 2010, 26, 2733. [张晓茹, 林艳红, 张健夫, 何冬青, 王德军. 物理化学学报, 2010, 26, 2733.]
16. [16]
  (16) Lazarovits, B.; Kim, K.; Haule, K.; Kotliar, G. Phys. Rev. B. 2010, 81, 115117. doi: 10.1103/PhysRevB.81.115117
17. [17]
  (17) Béteille, F.; Morineau, R.; Livage, J.; Nagano, M. Mater. Res. Bull. 1997, 32, 1109. doi: 10.1016/S0025-5408(97)00084-6
18. [18]
  (18) Masih, D.; Yoshitake, H.; Izumi, Y. Appl. Catal. A-gen. 2007, 325, 276. doi: 10.1016/j.apcata.2007.02.037
19. [19]
  (19) Lim, J. W.; Yoo, S. J.; Park, S. H.; Yun, S. U.; Sung, Y. E. Sol. Energy Mater. Sol. Cells 2009, 93, 2069. doi: 10.1016/j.solmat.2009.03.008
20. [20]
  (20) Woodley, S. M. Chem. Phys. Lett. 2008, 453, 167. doi: 10.1016/j.cplett.2008.01.018
21. [21]
  (21) Guinneton, F.; Valmalette, J. C.; Gavarri, J. R. Optical Materials 2000, 15, 111. doi: 10.1016/S0925-3467(00)00023-9
22. [22]
  (22) Liang, J. R.; Hu, M.; Wang, X. D.; Li, G. K.; Ji, A.; Yang, F. H.; Liu, J.; Wu, N. J.; Chen, H. D. Acta Phys. -Chim. Sin. 2009, 25, 1523. [梁继然, 胡明, 王晓东, 李贵柯, 季安, 杨富华, 刘剑, 吴南健, 陈弘达. 物理化学学报, 2009, 25, 1523.]
23. [23]
  (23) Gurvitch, M.; Luryi, S.; Polyakov, A.; Shabalov, A.;Dudley, M.; Wang, G.; Ge, S.; Yakovlev, V. J. Appl. Phys. 2007, 102, 033504. doi: 10.1063/1.2764245
24. [24]
  (24) Oh, C.; Yoon, S.; Kim, S.; Han, J.; Chung, H.; Jeong, H. J. J. Pharmaceut. Biomed. 2010, 53, 762. doi: 10.1016/j.jpba.2010.05.008
25. [25]
  (25) Xiao, P.; Zheng, S. B.; You, J. L.; Jiang, G. C.; Chen, H.; Zeng, H. Spectroscopy and Spectral Analysis. 2007, 27, 936. [肖萍, 郑少波, 尤静林, 蒋国昌, 陈辉, 曾昊. 光谱学与光谱分析, 2007, 27, 936.]
26. [26]
  (26) Pan, X. Y.; Ma, X. M. Materials Science and Engineering. 2001, 19, 138. [潘晓燕, 马学鸣. 材料科学与工程, 2001, 19, 138.]
27. [27]
  (27) Sudakar, C.; Kharel, P.; Lawes, G.; Suryanarayanan, R.; Naik, R.; Naik, V. M. J. Phys.: Condens. Matter. 2007, 19, 026212. doi: 10.1088/0953-8984/19/2/026212
28. [28]
  (28) Ma, J. W.; Xu, G.; Miao, L.; Tazawa, M.; Tanemura, S. Jpn. J. Appl. Phys. 2011, 50, 020215. doi: 10.1143/JJAP.50.020215
29. [29]
  (29) Ding, S.; Liu, Y. L.; Siu, G. G. Acta Physica Sinica. 2005, 54, 4416. [丁硕, 刘玉龙, 萧季驹. 物理学报, 2005, 54, 4416.]
30. [30]
  (30) Xu, G.; Jin, P.; Tazawa, M.; Yoshimura, K. Jpn. J. Appl. Phys. 2004, 43, 186. doi: 10.1143/JJAP.43.186
31. [31]
  (31) Kang, L. T.; Gao, Y. F.; Luo, H. J.; Zhang, C.; Du, J.; Zhang, Z. T. ACS Appl. Mater. Interfaces 2011, 3, 135. doi: 10.1021/am1011172
32. [32]
  (32) Tauc, J.; Gri rivici, R.; Vancu, A. Phys. Stat. Sol. 1966, 15, 627. doi: 10.1002/pssb.19660150224
33. [33]
  (33) Tauc, J.; Menth, A. J. Non-Cryst. Solids. 1972, 8-10, 569.
34. [34]
  (34) Tauc, J. Amorphous and Liquid Semiconductors, 1st ed.; Plenum Press: New York, 1974; 171. doi: --- Either first page or author must be supplied.
35. [35]
  (35) Saffarini, G.; Saiter, J. M.; Schmitt, H. Optical Materials 2007, 29, 1143. doi: 10.1016/j.optmat.2006.05.003
1. [1]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
2. [2]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
3. [3]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
4. [4]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
5. [5]
  Qi Wang , Yicong Gao , Feng Lu , Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141
6. [6]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
7. [7]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
8. [8]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
9. [9]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
10. [10]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
11. [11]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
12. [12]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
13. [13]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
14. [14]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
15. [15]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
16. [16]
  Laiying Zhang , Yinghuan Wu , Yazi Yu , Yecheng Xu , Haojie Zhang , Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126
17. [17]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
18. [18]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
19. [19]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
20. [20]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064

Get Citation

PDF

XML

Metrics

PDF Downloads(774)
Abstract views(2061)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Optical and Phase Transition Properties of TixV1-xO2 Thin Films

Metrics

通讯作者: 陈斌, bchen63@163.com

Optical and Phase Transition Properties of Ti_xV_1-xO₂ Thin Films