Citation: XIONG Li-Long, XU You-Long, ZHANG Cheng, TAO Tao. Doping-Coating Surface Modification of Spinel LiMn₂O₄ Cathode Material with Al³⁺ for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2012, 28(05): 1177-1182. doi: 10.3866/PKU.WHXB201203092 shu

Doping-Coating Surface Modification of Spinel LiMn₂O₄ Cathode Material with Al³⁺ for Lithium-Ion Batteries

1.
International Center for Dielectric Research, Electronic Material Research Laboratory of Ministry of Education, Xi'an Jiaotong University, Xi'an 710049, P. R. China

Received Date: 26 December 2011
Available Online: 9 March 2012

A doping-coating surface modification method was used to improve the cycle performance of the lithium-ion battery cathode material spinel LiMn₂O₄. Al was chosen as the doping element and Al(NO₃)₃ as the raw material. We investigated Al³⁺ doping of 7.1%(atomic fraction) at the temperatures of 300, 400, 500, 600, 700, 750, and 800 °C. It was found that at increasing temperatures, the maximum specific capacity of the modified samples first increased and then decreased, with a maximum at 700 °C. The fading rate increased initially with temperature as well, and then decreased, followed by a small rise with temperature. This is because the coated layer gradually reacted with the LiMn₂O₄ granule at elevated temperatures and became a completely solid solution layer by 750 °C. The fading rate reached the minimum at the same time. Subsequently, the solid solution layer diffused into the LiMn₂O₄ granule, weakening the granule protection so that the fading rate slightly increased. Among these samples, the maximum specific capacity (133.6 mAh·g^-1) was for the sample treated at 700 °C for 5 h, and the fading rate was 3.4% after 50 cycles. It is shown that doping-coating surface modification with Al³⁺ may enable the commercial application of spinel LiMn₂O₄ cathode material for lithium-ion batteries.
- Lithium-ion battery,
- Cathode material,
- Spinel LiMn₂O₄,
- Doping-coating surface modification,
- Solid solution
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Doping-Coating Surface Modification of Spinel LiMn₂O₄ Cathode Material with Al³⁺ for Lithium-Ion Batteries