Citation: WANG Wei-Yan, ZHANG Xiao-Zhe, YANG Yun-Quan, YANG Yan-Song, PENG Hui-Zuo, LUO He-An. Preparation of La-Ni-Mo-B Amorphous Catalyst and Its Catalytic Properties for Hydrodeoxygenation of Phenol[J]. Acta Physico-Chimica Sinica, ;2012, 28(05): 1243-1251. doi: 10.3866/PKU.WHXB201203081 shu

Preparation of La-Ni-Mo-B Amorphous Catalyst and Its Catalytic Properties for Hydrodeoxygenation of Phenol

1.
School of Chemical Engineering, Xiangtan University, Xiangtan 411105, Hunan Province, P. R. China

Received Date: 1 January 2012
Available Online: 8 March 2012
Fund Project: 湘潭大学资助基金(2011XZX11) (2011XZX11)湖南省教育厅开放基金(10K062)资助项目 (10K062)

Lanthanum-promoted Ni-Mo-B amorphous catalysts were prepared by chemical reduction of the corresponding metal salts with sodium borohydride aqueous solution. Scanning electron microscopy (SEM), X-ray diffraction (XRD), inductively coupled plasma atomic emission spectrometry (ICP-AES), and X-ray photoelectron spectroscopy (XPS) were used to characterize the resulting materials. Phenol was used as model compound to test the hydrodeoxygenation (HDO) activity of the La-Ni-Mo-B amorphous catalysts. Adding lanthanum could decrease the particle size, increase the content of Ni⁰ and promote the reduction of Mo⁶⁺ to Mo⁴⁺ . But excess lanthanum would cover some of the Ni⁰, and Mo⁴⁺ active sites. The high hydrogenation activity was attributed to the amorphous structure of the catalyst and the high content of Ni⁰ and the high degree of deoxygenation was attributed to the high content of MoO₂. The HDO reation of phenol on the La-Ni-Mo-B amorphous catalyst proceeded with a hydrogenation-dehydration route, thus decreasing the aromatic content of the HDO products. Both the conversion and the total deoxygenation degree were up to 99.0%. The deactivation of the La-Ni-Mo-B amorphous catalysts during the HDO reation of phenol at high temperature was mainly caused by the crystallization of the amorphous structure.
- Amorphous catalyst,
- La-Ni-Mo-B,
- Hydrodeoxygenation,
- Phenol,
- Bio-oil
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