Citation: WU Xiao-Na, ZOU Wen-Sheng, ZHAO Jian-Xi. Highly Stable Foams Generated by the Gemini Surfactant Ethanediyl-α,ω-bis(tetradecyldimethylammonium bromide)[J]. Acta Physico-Chimica Sinica, ;2012, 28(05): 1213-1217. doi: 10.3866/PKU.WHXB201203053 shu

Highly Stable Foams Generated by the Gemini Surfactant Ethanediyl-α,ω-bis(tetradecyldimethylammonium bromide)

1.
Institute of Colloid and Interface Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, P. R. China

Received Date: 20 December 2011
Available Online: 5 March 2012
Fund Project: 国家自然科学基金(20673021, 20873024) (20673021, 20873024)福建省自然科学基金(2010J01038)资助项目 (2010J01038)

This paper reports a highly stable foam system generated by the gemini surfactant ethanediyl- α,ω-bis(tetradecyldimethylammonium bromide) (referred to as 14-2-14). The time measured for the collapse of the foam to half its initial height was used to characterize the foam stability; it was as high as 961 min for this system and significantly longer than that (754 min) for ethanediyl-α,ω-bis(dodecyldimethylammonium bromide) (12-2-12) foams. Thus the gemini surfactant structure of a short spacer together with two long tails enabled it to be a highly efficient foam stabilizer. The dilational rheology of the adsorbed films revealed the relationship between the interfacial elasticity and the foam stability. The high-frequency limit of elasticity of the adsorbed film at a specific surface coverage was again found to indicate foam stability. A larger limit of elasticity indicated a more stable foam.
- Foam stabilizer,
- Gemini surfactant,
- Short spacer,
- Long tail,
- High interfacial-elasticity
1. [1]
  (1) Wu, X. N.; Zhao, J. X.; Li, E. J.; Zou, W. S. Colloid Polym. Sci. 2011, 289, 1025.
2. [2]
  (2) Pei, X. M.; You, Y.; Zhao, J. X.; Deng, Y. S.; Li, E. J.; Li, Z. X. J. Colloid Interface Sci. 2010, 351, 457.
3. [3]
  (3) Bergeron, V. Langmuir 1997, 13, 3474.
4. [4]
  (4) Espert, A.; Klitzing, R. V.; Poulin, P.; Colin, A.; Zana, R.; Langevin, D. Langmuir 1998, 14, 4251.
5. [5]
  (5) Zana, R.; Benrraou, M.; Rueff, R. Langmuir 1991, 7, 1072.
6. [6]
  (6) You, Y.; Wu, X. N.; Zhao, J. X.; Ye, Y. Z.; Zou, W. S. Colloids Surf. A 2011, 384, 164.
7. [7]
  (7) Stubenrauch, C.; Miller, R. J. Phys. Chem. B 2004, 108, 6412.
8. [8]
  (8) Santini, E.; Ravera, F.; Ferrari, M.; Stubenrauch, C.; Makievski, A.; Krägel, J. Colloids Surf. A 2007, 298, 12.
9. [9]
  (9) Wang, L.; Yoon, R. H. Int. J. Miner. Process. 2008, 85, 101.
10. [10]
  (10) Georgieva, D.; Cagna, A.; Langevin, D. Soft Matter 2009, 5, 2063.
11. [11]
  (11) Acharya, D. P.; Gutiérrez, J. M.; Aramaki, K.; Aratani, K.; Kunieda, H. J. Colloid Interface Sci. 2005, 291, 236.
12. [12]
  (12) Espert, A.; Klitzing, R. V.; Poulin, P.; Colin, A.; Zana, R.; Langevin, D. Langmuir 1998, 14, 4251.
13. [13]
  (13) Sonin, A, A.; Bonfillon, A.; Langevin, D. J. Colloid Interface Sci. 1994, 162, 323.
14. [14]
  (14) Li, Y. M.; Xu, G. Y.; Xin, X.; Gao, X. R.; Wu, D. Carbohydrate Polym. 2008, 72, 211.
15. [15]
  (15) Lucassen, J.; van den Tempel, M. Chem. Eng. Sci. 1972, 27, 1283.
16. [16]
  (16) Lucassen, J.; van den Tempel, M. J. Colloid Interface Sci. 1972, 41, 491.
17. [17]
  (17) Rosen, M. J. Surfactants and Interfacial Phenomena; Wiley: New York, 1988.
1. [1]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
2. [2]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
3. [3]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
4. [4]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
5. [5]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
6. [6]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
7. [7]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
8. [8]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003
9. [9]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
10. [10]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032
11. [11]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
12. [12]
  Yanhui Sun , Junmin Nan , Guozheng Ma , Xiaoxi Zuo , Guoliang Li , Xiaoming Lin . Exploration and Teaching Practice of Ideological and Political Elements in Interface Physical Chemistry: Taking “Additional Pressure on Curved Surfaces” as an Teaching Example. University Chemistry, 2024, 39(11): 20-27. doi: 10.3866/PKU.DXHX202402023
13. [13]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
14. [14]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
15. [15]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
16. [16]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
17. [17]
  Xiaoyan Wang , Chao Wang , Dongmei Dai , Yanling Geng , Hongtao Gao . Design of Ideological and Political Education for the Experiment on Calcium Content Determination in Calcium Supplements. University Chemistry, 2024, 39(2): 162-167. doi: 10.3866/PKU.DXHX202307074
18. [18]
  Xiuyun Wang , Jiashuo Cheng , Yiming Wang , Haoyu Wu , Yan Su , Yuzhuo Gao , Xiaoyu Liu , Mingyu Zhao , Chunyan Wang , Miao Cui , Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067
19. [19]
  Tongyu Zheng , Teng Li , Xiaoyu Han , Yupei Chai , Kexin Zhao , Quan Liu , Xiaohui Ji . A DIY pH Detection Agent Using Persimmon Extract for Acid-Base Discoloration Popularization Experiment. University Chemistry, 2024, 39(5): 27-36. doi: 10.3866/PKU.DXHX202309107
20. [20]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046

Get Citation

PDF

XML

Metrics

PDF Downloads(714)
Abstract views(2167)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142