Citation: LI Lan, HU Geng-Shen, LU Ji-Qing, LUO Meng-Fei. Review of Oxygen Vacancies in CeO₂-doped Solid Solutions as Characterized by Raman Spectroscopy[J]. Acta Physico-Chimica Sinica, ;2012, 28(05): 1012-1020. doi: 10.3866/PKU.WHXB201203052 shu

Review of Oxygen Vacancies in CeO₂-doped Solid Solutions as Characterized by Raman Spectroscopy

1.
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, Zhejiang Province, P. R. China

Received Date: 18 November 2011
Available Online: 5 March 2012
Fund Project: 国家自然科学基金(20703039, 21173195)资助项目 (20703039, 21173195)

This review summarizes the current status of the evolution and observation of oxygen vacancies in CeO₂-doped solid solutions as characterized by Raman spectroscopy. Three Raman peaks at 465, 560, and 600 cm^-1 are ascribed to the F_2g symmetrical stretching vibration mode of CeO₂ in a fluorite structure, oxygen vacancies, and a MO₈-type complex, respectively. The presence of oxygen vacancies was related to the ionic valence states of the dopant, while the MO₈-type complex was associated with the ionic radii of the dopant. The oxygen vacancy concentration correlated with the sample absorbance and the surface enrichment of oxygen vacancies. The in situ Raman spectroscopic investigations show that the atmospheric composition and temperature had a large influence on the absorbance of the samples, which in turn alters the detection depth of the Raman laser and the observed oxygen vacancy concentration.
- Raman spectroscopy,
- Oxygen vacancy,
- CeO₂-based solid solution,
- Absorbance
1. [1]
  (1) Reddy, B. M.; Bharali, P.; Saikia, P.; Ataulah, K.; Loridant, S.; Muhler, M.; Grünert,W. J. Phys. Chem. C 2007, 111, 1878.
2. [2]
  (2) Wang, X. Q.; Rodriguez, J. A.; Hanson, J. C.; Gamarra, D.; Martínez-Arias, A.; Fernández-García, M. J. Phys. Chem. B 2006, 110, 428.
3. [3]
  (3) Park, S.; Vohs, J. M.; rte, R. J. Nature 2000, 404, 265.
4. [4]
  (4) rte, R. J.; Vohs, J. M.; Mclntosch, S. Solid State Ionics 2004, 175, 1.
5. [5]
  (5) Mori, T.; Drennan, J. J. Electroceram. 2006, 17, 749.
6. [6]
  (6) Liu, L.; Tang, C. Q. J. Power Sources (China) 2001, 25, 428.
7. [7]
  (7) Monte, R. D.; Kaspar, J. Top. Catal. 2004, 28, 47.
8. [8]
  (8) Trovarelli, A. Catal. Rev. Sci. Eng. 1996, 38, 439.
9. [9]
  (9) Jin, X. L.; Meng, M. Chinese Chemical Industry and Engineering 2007, 27, 345. [金向亮, 孟明. 化学工业与工程, 2007, 27, 345.]
10. [10]
  (10) Song, Z. X.; Liu,W.; Nishiguchi. H.; Takami, A.; Nagaoka, K.; Takita, Y. Appl. Catal. A: Gen. 2007, 329, 86.
11. [11]
  (11) McBride, J. R.; Hass, K. C.; Poindexter, B. D. ;Weber,W. H. J. Appl. Phys. 1994, 76, 2435.
12. [12]
  (12) He, H.; Dai, H. X.; Au, C. T. Catal. Today 2004, 90, 245.
13. [13]
  (13) Xiao, G. L.; Li, S.; Li, H.; Chen, L. Q. Microporous and Mesoporous Mater. 2009, 120, 426.
14. [14]
  (14) Hennings, U.; Reimert, R. Appl. Catal. A 2007, 325, 41.
15. [15]
  (15) Zhou, G.; rte, R. J. J. Phys. Chem. B 2008, 112, 9869.
16. [16]
  (16) Daturi, M.; Finocchio, E.; Binet, C.; Lavalley, J. C.; Fally, F.; Perrichon, V.; Vidal, H.; Hickey, N.; Kaspar, J. J. Phys. Chem. B 2000, 104, 9186.
17. [17]
  (17) Kozlov, A. I.; Kim, D. H.; Yezerets, A.; Andersen, P.; Kung, H. H.; Kung, M.C. J. Catal. 2002, 209, 417.
18. [18]
  (18) Thangadurai, V.; Kopp, P. J. Power Sources 2007, 168, 178.
19. [19]
  (19) Etsell, T. H.; Flengas, S. N. Chem. Rev. 1970, 70, 339.
20. [20]
  (20) Li, S. P.; Lu, J. Q.; Fang, P.; Luo, M. F. J. Power Sources 2009, 193, 93.
21. [21]
  (21) Gayen, A.; Priolkar, K. R.; Sarode, P. R.; Jayaram, V.; Hegde, M. S.; Subbanna, G. N.; Emura S. Chem. Mater. 2004, 16, 2317.
22. [22]
  (22) Ganduglia-Pirovano, M. V.; Hofmann, A.; Sauer, J. Surf. Sci. Rep. 2007, 62, 219.
23. [23]
  (23) Popovi?, Z. V.; Dohcevi?-Mitrovi?, Z.; Konstantinovi?, M. J.; S?epanovi?, M. J. Raman Spectrosc. 2007, 38, 750.
24. [24]
  (24) Thomas, J. M.; Thomas,W. J. Principles and Practice of Heterogeneous Catalysis; New York:Wiley-VCH, 1997; pp 257-275.
25. [25]
  (25) Knozinger, H.; Mestl, G.. Top. Catal. 1999, 8, 45.
26. [26]
  (26) Banares, M. A.;Wachs, I. E. J. Raman. Spectrosc. 2002, 33, 359.
27. [27]
  (27) Wachs, I. E. Top. Catal. 1999, 8, 57.
28. [28]
  (28) Li, C.; Li, M. J. J. Mol. Catal.(China) 2003, 17, 213. [李灿, 李美俊. 分子催化, 2003, 17, 213.]
29. [29]
  (29) Xiong, G.; Feng, Z.; Li, J.; Yang, Q. H.; Ying, P. L.; Xin, Q.; Li, C. J. Phys. Chem. B 2000, 104, 3581.
30. [30]
  (30) Xiong, G.; Yu, Y.; Feng, Z. C.; Xin, Q.; Xiao, F. S.; Li, C. Microporous Mesoporous Mater. 2001, 42, 317.
31. [31]
  (31) Wang, L.; Hall,W. K. J. Catal. 1983, 82, 177.
32. [32]
  (32) Schrader, G. L.; Cheng, C. P. J. Catal. 1983, 80, 369.
33. [33]
  (33) Vuurman, M. A.;Wachs, I. E. J. Phys. Chem. 1992, 96, 5008.
34. [34]
  (34) Weckhuysen, B. M.;Wachs, I . E. J. Phys. Chem. B 1997, 101, 2793.
35. [35]
  (35) Weckhuysen, B. M.;Wachs, I. E. J. Phys. Chem. 1996, 100, 14437.
36. [36]
  (36) Li, M. J.; Feng, Z. C.; Zhang, J.; Ying, P. L.; Xin, Q.; Li, C. Chin. J. Catal. 2003, 24, 861. [李美俊, 冯兆池, 张静, 应品良, 辛勤, 李灿. 催化学报, 2003, 24, 861.]
37. [37]
  (37) Li, M. J.; Feng, Z. C.; Xiong, G.; Ying, P. l.; Xin, Q.; Li, C. J. Phys. Chem. B 2001, 105, 8107.
38. [38]
  (38) Weng,W. Z.;Wan, H. L.; Li, M. J.; Cao, Z. X. Angew. Chem. Int. Edit. 2004, 43, 975.
39. [39]
  (39) Fan, F. T. ; Feng, Z. C. ; Li, G. N.; Sun, K. J.; Ying, P. L.; Li, C. Chem. Eur. J. 2008, 14, 5125.
40. [40]
  (40) Zhang, J.; Xu, Q.; Feng, Z. C.; Li, M. J.; Li, C. Angew. Chem. Int. Edit. 2008, 47, 1766.
41. [41]
  (41) Pu, Z. Y.; Lu, J. Q.; Luo, M. F.; Xie, Y. L. J. Phys. Chem. C 2007, 111, 18695.
42. [42]
  (42) Guo, M.; Lu, J. Q.; Bi, Q. Y.; Luo, M. F. Chem.Phys.Chem. 2010, 11, 1693.
43. [43]
  (43) Kobayashi, T.;Wang, S.; Dokiya, M.; Tagawa, H.; Hashimotom, T. Solid State Ionics 1999, 126, 349.
44. [44]
  (44) Shuk, P.; Greenblatt, M. Solid State Ionics 1999, 116, 217.
45. [45]
  (45) Luo, M. F.; Lu, G. L.; Zheng, X. M.; Zhong, Y. J.;Wu, T. H. J. Mater. Sci. Lett. 2000, 19, 1351.
46. [46]
  (46) Keramidas, V. G.; White,W. B. J. Chem. Phys. 1973, 59, 1561.
47. [47]
  (47) Nakajima, A.; Yoshihara, A.; Ishigame, M. Phys. Review B, 1994, 50, 13297.
48. [48]
  (48) Taniguchi, T.;Watanabe, T.; Sugiyama, N.; Subramani, A. K.; Wagata, H.; Matsushita, N.; Yoshimura, M. J. Phys. Chem. C 2009, 113, 19789.
49. [49]
  (49) Li, L.; Chen, F.; Lu, J. Q.; Luo, M. F.; J. Phys. Chem. A 2011, 115, 7972.
50. [50]
  (50) Wu, Z. L.; Li, M. J.; Howe, J.; Meyer, H. M. III; Overbury, S. H. Langmuir 2010, 26, 16595.
51. [51]
  (51) Lee, Y.; He, G.; Akey, A. J; Si, R.; Flytzani-Stephanopoulos, M.; Herman, I. P. J. Am. Chem. Soc. 2011, 133, 12952.
52. [52]
  (52) Luo, M. F.; Yan, Z. L.; Jin, L. Y.; He, M. J. Phys. Chem. B 2006, 110, 13068.
53. [53]
  (53) Ou, D. R.; Mori, T.; Ye, F.; Kobayashi, T. Appl. Phys. Lett. 2006, 89, 171911-1.
54. [54]
  (54) Li, L.; Guo, M.; Pu, Z. Y.; Lu, J. Q.; Luo, M. F. Chin. J. Inorg. Chem. 2011, 27, 840. [李岚, 郭明, 普志英, 鲁继青, 罗孟飞. 无机化学学报, 2011, 27, 840.]
55. [55]
  (55) Guo, M.; Lu, J. Q.;Wu, Y. N.;Wang, Y. J.; Luo, M. F.; Langmuir 2011, 27, 3872.
56. [56]
  (56) Ye, F.; Mori, T.; Ou, D. R.; Cormack, A. N. Solid State Ionics 2009, 180, 1127.
57. [57]
  (57) Guzman, J.; Carrettin, S.; Fierro- nzalez, J. C.; Hao, Y.; Gates, B. C.; Corma, A. Angew. Chem. Int. Edit. 2005, 44, 4778.
58. [58]
  (58) Shapovalov, V.; Metiu, H. J. Catal. 2007, 245, 205.
59. [59]
  (59) Shapovalov, V.; Carrettin, S.; Corma, A. J. Am. Chem. Soc. 2005, 127, 3286.
60. [60]
  (60) Yan, Z. L.; Lin, X.; Luo, J. H.; Xie, G. Q.; Luo, M. F. Chin. J. Inorg. Mater. 2005, 20, 653. [闫宗兰, 林霞, 罗建海, 谢冠群, 罗孟飞. 无机材料学报, 2005, 20, 653.]
61. [61]
  (61) Pu, Z. Y.; Liu, X. S.; Jia, A. P.; Xie, Y. L.; Lu, J. Q.; Luo, M. F. J. Phys. Chem. C 2008, 112, 15045.
62. [62]
  (62) Li, H. F.; Zhang, N.; Chen, P.; Luo, M. F.; Lu, J. Q. Appl. Catal. B 2011, 110, 279.
63. [63]
  (63) Meng, L.; Jia, A. P.; Lu, J. Q.; Luo, L. F.; Huang,W. X.; Luo, M. F. J. Phys. Chem. C 2011, 115, 19789.
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沈阳化工大学材料科学与工程学院沈阳 110142

Review of Oxygen Vacancies in CeO2-doped Solid Solutions as Characterized by Raman Spectroscopy

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通讯作者: 陈斌, bchen63@163.com

Review of Oxygen Vacancies in CeO₂-doped Solid Solutions as Characterized by Raman Spectroscopy