Citation: ZHOU Wei, HUANG Qi-Yu, WANG Xiao-Chen, QI Fang-Yi, JIAO Fang, ZHENG Yi-Zhou. Fabrication and Characterization of Quasi-Solid-State Electrolyte Films Based on Polyvinyl Butyral[J]. Acta Physico-Chimica Sinica, ;2012, 28(05): 1134-1138. doi: 10.3866/PKU.WHXB201203051 shu

Fabrication and Characterization of Quasi-Solid-State Electrolyte Films Based on Polyvinyl Butyral

1.
1. School of Microelectronics, Shanghai Jiao Tong University, Shanghai 200240, P. R. China;
2. School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Received Date: 5 December 2011
Available Online: 5 March 2012
Fund Project: 中国科学院新型薄膜太阳能电池重点实验室开放课题(KF200903)资助项目 (KF200903)

The preparation and properties of quasi-solid-state electrolyte films based on polyvinyl butyral were studied. The films were prepared by adding a pore forming agent and auxiliary agents to polyvinyl butyral. Factors affecting the preparation of the films were investigated. The results showed that the films prepared by adding 6.000 g calcium carbonate, 0.310 g calcium chloride, and 0.150 g glucose to 0.200 g polyvinyl butyral performed best. The impact of different pore ratios on device efficiency was investigated as well. The efficiency of dye-sensitized solar cells (DSSCs) using the quasi-solid-state electrolyte film reached 4.720% (open-circuit voltage V_oc=0.7194 V, short-circuit current density J_sc=10.014 mA·cm^-2, fill factor FF=0.6559), which was 88% of that for the corresponding liquid electrolyte solar cells. The film is easy to use for packaging and its preparation method is simple and non-toxic.
- Dye-sensitized solar cell,
- Quasi-solid state electrolyte,
- Electrolyte film,
- Polyvinyl butyral,
- Porous membrane
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