Citation: HU Jia-Yuan, CAO Shun-An, XIE Jian-Li. Effect of Rust Layer on the Corrosion Behavior of Carbon Steel in Reverse Osmosis Product Water[J]. Acta Physico-Chimica Sinica, ;2012, 28(05): 1153-1162. doi: 10.3866/PKU.WHXB201203022 shu

Effect of Rust Layer on the Corrosion Behavior of Carbon Steel in Reverse Osmosis Product Water

1.
1. College of Power and Mechanical Engineering, Wuhan University, Wuhan 430072, P. R. China;
2. Suzhou Nuclear Power Research Institute, Suzhou 215004, Jiangsu Province, P. R. China

Received Date: 15 January 2012
Available Online: 2 March 2012
Fund Project: 中央高校基本科研业务费专项(20102080101000090)资助项目 (20102080101000090)

The morphologies and electrochemical characteristics of rust layers generated in seawater and reverse osmosis (RO) product water were investigated by scanning electron microscopy (SEM), infrared spectroscopy (IR), X-ray diffraction (XRD) and electrochemical tests. Experimental results revealed obvious differences in the components, structures and functions of rust layers in two types of solutions, so that the corrosion rates of carbon steel were markedly different. The reduction potential of γ-FeOOH is higher than the corrosion potential of carbon steel in RO product water, such that γ-FeOOH is easily reduced to Fe₃O₄ and two layers emerge in the rust structures. The outer layer (γ-FeOOH layer) is too thin to inhibit oxygen diffusion, and tends to accelerate the cathodic process via reduction of γ-FeOOH. Because Fe2 + and electrons can pass through the Fe₃O₄ layer, oxygen can be directly reduced on the surface of the inner layer (Fe₃O₄ layer). Therefore, the inner rust layer (Fe₃O₄ layer) can provide a large cathode area on which to promote oxygen reduction. As a result, the corrosion process of carbon steel in RO product water can be accelerated greatly. The corrosion rate of carbon steel is determined by the limiting diffusion rate of oxygen from solution to the inner rust layer. Anti-corrosion measures should inhibit the reduction reaction of γ-FeOOH.
- Rust layer,
- Seawater,
- RO product water,
- Electrochemical behavior,
- Corrosion mechanism,
- Anti-corrosion
1. [1]
  (1) Maran u, V. S.; Savvides, K. Desalination 2001, 138, 251.
2. [2]
  (2) Li, J.; Liu, G. C.; Wang, W.; Zhang, Q.; Yi, G. H. Guangzhou Chemical Industry 2009, 37 (4), 95. [李敬, 刘贵昌, 王玮, 章强, 易桂虎. 广州化工, 2009, 37 (4), 95.]
3. [3]
  (3) Malik, A. U.; Andijani, I.; Mobin, M.; Al-Fozan, S.; Al-Muaili, F.; Al-Hajiri, M. Desalin. Water Treat. 2010, 20, 22.
4. [4]
  (4) Malik, A. U.; Andijani, I. N.; Mobin, M.; Ahmad, S. Desalination 2006, 196, 149.
5. [5]
  (5) Delion, N.; Mauguin, G.; Corsin, P. Desalination 2004, 165, 323.
6. [6]
  (6) Withers, A. Desalination 2005, 179, 11.
7. [7]
  (7) Hu, J. Y.; Cao, S. A., Han, J. W., Hao, X. W. Research on Corrosion Factors and Corrosion Prevention Measure of Carbon Steel in Produce Water of Reverse Osmosis in Power Plant. Proceedings of 2011 Asia-Pacific Power and Energy Engineering Conference, Wuhan, Mar 25-28, 2011; IEEE Computer Society, Piscataway, 2011.
8. [8]
  (8) Blute, N. K.; McGuire, M. J.; West, N.; Voutchkov, N.; Maclaggan, P.; Reich, K. J. Am.Water Works Assoc. 2008, 100, 117.
9. [9]
  (9) Greenlee, L. F.; Lawler, D. F.; Freeman, B. D.; Marrot, B.; Moulin, P. Water Research 2009, 43, 2317.
10. [10]
  (10) Melchers, R. E.; Jeffrey, R. Corros. Sci. 2005, 47, 1678.
11. [11]
  (11) Melchers, R. E. Corros. Sci. 2003, 45, 923.
12. [12]
  (12) Samide, A. P.; Bibicu, I. Surf. Interface Anal. 2008, 40, 944.
13. [13]
  (13) Zhou, Y.; Zheng, Y. Y.; Wang, Y. H.; Wang, J. Acta Metall. Sin. 2010, 46, 123. [邹妍, 郑莹莹, 王燕华, 王佳. 金属学报, 2010, 46, 123.]
14. [14]
  (14) Zhou, Y.; Wang, J.; Zheng, Y. Y. Corros. Sci. 2011, 53, 208.
15. [15]
  (15) Kamimura, T.; Hara, S.; Miyuki, H.; Yamashita, M.; Uchida, H. Corros. Sci. 2006, 48, 2799.
16. [16]
  (16) Li, Y. T.; Hou, B. R. Chin. J. Oceanol. Limnol. 1998, 16, 231.
17. [17]
  (17) Liu, B. Y.; Liu, Z.; Han, G. C.; Li, Y. H. Thin Solid Films 2011, 519, 7836.
18. [18]
  (18) Paul, S. J. Mater. Eng. Perform. 2011, 20, 325.
19. [19]
  (19) Guermazi, N.; Ibrahmi, A.; Hmidi, H.; Elleuch, K.; Ayedi, H. F. Mater. Corros. 2010, 61, 43.
20. [20]
  (20) Zhou, Y.; Wang, J.; Zheng, Y. Y. Acta Phys. –Chim. Sin. 2010, 26, 2361. [邹妍, 王佳, 郑莹莹. 物理化学学报, 2010, 26, 2361.]
21. [21]
  (21) Dillmann, Ph.; Mazaudier, F.; Hoerlé, S. Corros. Sci. 2004, 46, 1401.
22. [22]
  (22) Yamashita, M.; Miyuki, H.; Matsuda, Y.; Nagano, H.; Misawa, T. Corros. Sci. 1994, 36, 283.
23. [23]
  (23) García, K. E.; Morales, A. L.; Barrero, C. A.; Greneche, J. M. Corros. Sci. 2006, 48, 2813.
24. [24]
  (24) Yamashita, M.; Miyuki, H.; Nagano, H. Sumitomo Search 1995, 57, 12.
25. [25]
  (25) Cao, C. N. Principles of Electrochemistry of Corrosion, 3nd ed.; Chemical Industry Press: Beijing, 2008; pp 187-192. [曹楚南. 腐蚀电化学原理(第三版). 北京:化学工业出版社, 2008: 187-192.]
26. [26]
  (26) Bai, Z. Q.; Chen, C. F.; Lu, M. X.; Li, J. B. Appl. Surf. Sci. 2006, 252, 7578.
27. [27]
  (27) Bousselmi, L.; Fiaud, C.; Tribollet, B.; Triki, E. Electrochim. Acta 1999, 44, 4357.
28. [28]
  (28) Bousselmi, L.; Fiaud, C.; Tribollet, B.; Triki, E. Corros. Sci. 1997, 39, 1711.
29. [29]
  (29) Qiao, G. F.; Ou, J. P. Electrochim. Acta 2007, 52, 8008.
30. [30]
  (30) Zeng, C. L.; Wang, W.; Wu, W. T. Acta Metall. Sin. 1999, 35, 751. [曾潮流, 王文, 吴维芠. 金属学报, 1999, 35, 751.]
31. [31]
  (31) Cao, C. N.; Zhang, J. Q. An Introduction to Electrochemical Impedance Spectroscopy; Science Press: Beijing, 2002; pp 86-88. [曹楚南, 张鉴清. 电化学阻抗谱导论. 北京:科学出版社, 2002: 86-88]
32. [32]
  (32) Xiao, J.; Lu, J. F.; Chen, J.; Li, Y. G. J. Chem. Eng. of Chinese Univ. 2001, 15, 6. [肖吉, 陆九芳, 陈健, 李以圭. 高校化学工程学报, 2001, 15, 6.]
33. [33]
  (33) Ma, Y. T.; Li, Y.; Wang, F. H. Mater. Chem. Phys. 2008, 112, 844.
34. [34]
  (34) Hoerlé, S.; Mazaudier, F.; Dillmann, Ph.; Santarini, G. Corros. Sci. 2004, 46, 1431.
35. [35]
  (35) Evans, U. R. Nature 1965, 206, 980.
36. [36]
  (36) Stratmann, M.; Bohnenkamp, K.; Engell, H. J. Corros. Sci. 1983, 23, 969.
37. [37]
  (37) Lair, V.; Antony, H.; Legrand, L.; Chaussé, A. Corros. Sci. 2006, 48, 2050.
38. [38]
  (38) Nishikata, A.; Ichiara, Y.; Hayashi, Y.; Tsuru, T. J. Electrochem. Soc. 1997, 144, 1244.
39. [39]
  (39) Stratmann, M.; Hoffmann, K. Corros. Sci. 1989, 29, 1329.
40. [40]
  (40) Sun, M.; Xiao, K.; Dong, C. F.; Li, X. G. Acta Metall. Sin. 2011, 47, 442. [孙敏, 肖葵, 董超芳. 金属学报, 2011, 47, 442.]
41. [41]
  (41) Syed, S. Mater. Corros. 2010, 61, 238.
1. [1]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002
2. [2]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
3. [3]
  Wenda WANG , Jinku MA , Yuzhu WEI , Shuaishuai MA . Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 809-822. doi: 10.11862/CJIC.20230353
4. [4]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
5. [5]
  Jiarong Feng , Yejie Duan , Chu Chu , Dezhen Xie , Qiu'e Cao , Peng Liu . Preparation and Application of a Streptomycin Molecularly Imprinted Electrochemical Sensor: A Suggested Comprehensive Analytical Chemical Experiment. University Chemistry, 2024, 39(8): 295-305. doi: 10.3866/PKU.DXHX202401016
6. [6]
  Ronghao Zhao , Yifan Liang , Mengyao Shi , Rongxiu Zhu , Dongju Zhang . Investigation into the Mechanism and Migratory Aptitude of Typical Pinacol Rearrangement Reactions: A Research-Oriented Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 305-313. doi: 10.3866/PKU.DXHX202309101
7. [7]
  Xinxin JING , Weiduo WANG , Hesu MO , Peng TAN , Zhigang CHEN , Zhengying WU , Linbing SUN . Research progress on photothermal materials and their application in solar desalination. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1033-1064. doi: 10.11862/CJIC.20230371
8. [8]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
9. [9]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
10. [10]
  Yingying Chen , Di Xu , Congmin Wang . Exploration and Practice of the “Four-Level, Three-Linkage” General Chemistry Course System. University Chemistry, 2024, 39(8): 119-125. doi: 10.3866/PKU.DXHX202401057
11. [11]
  Xiao-Qi Xu , Yapei Wang . Practice of Cultivating Multi-Disciplinary Talents with Comprehensive Skills through Demand-Driven, Individualized Education, and Humanities and Science Integration. University Chemistry, 2024, 39(6): 90-97. doi: 10.3866/PKU.DXHX202311049
12. [12]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
13. [13]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
14. [14]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
15. [15]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072
16. [16]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
17. [17]
  Yongmei Chen , Lidan Zhang , Shunlai Li , Chunting Zhang , Meng Cui , Qinghong Xu , Lan Jin , Chunchuang Li , Zhi Lv . Development of a National First-Class Course of “University Chemistry Experiment” Based on MOOCs. University Chemistry, 2024, 39(7): 8-12. doi: 10.3866/PKU.DXHX202404017
18. [18]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
19. [19]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
20. [20]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447

Get Citation

PDF

XML

Metrics

PDF Downloads(689)
Abstract views(2211)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142