Citation: TIAN Hong, ZHANG -Lei, XU Yao, WU Dong, WU Zhong-Hua, LÜ Hai-Bing, YUAN Xiao-Dong. Comparision of Silica Anti-Reflective Films Obtained via a Sol-Gel Process in the Presence of PEG or PVP[J]. Acta Physico-Chimica Sinica, ;2012, 28(05): 1197-1205. doi: 10.3866/PKU.WHXB201202231 shu

Comparision of Silica Anti-Reflective Films Obtained via a Sol-Gel Process in the Presence of PEG or PVP

TIAN Hong ¹ ,
ZHANG -Lei ² ,
XU Yao ^1, ,
WU Dong ¹ ,
WU Zhong-Hua ³ ,
LÜ Hai-Bing ⁴ ,
YUAN Xiao-Dong ⁴

1.
1. CAS Key Laboratory for Carbon, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, P. R. China;
2. College of Science, Henan Polytechnic University, Jiaozuo 454003, Henan Province, P. R. China;
3. Laboratory of Synchrotron Radiation, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, P. R. China;
4. Laer Fusion Research Center,Chinese Academy of Engineering Physics, Mianyang 621900, Sichuan Province, P. R. China

Received Date: 25 October 2011
Available Online: 23 February 2012
Fund Project: 国家自然科学基金(10835008)资助项目 (10835008)

The different effects of poly(ethylene glycol) (PEG) and poly(vinylpyrrolidone) (PVP) on the structure and laser-induced damage threshold of sol-gel silica anti-reflective films were investigated. The results of dynamic light-scattering, transmission electron microscopy (TEM), and small-angle X-ray scattering (SAXS) showed that PEG could prompt silica particles to form uniform clusters, whereas in the PVP-modified sol, the growth of silica particles was restricted. This was a result of the strong hydrogen bonds between Si―OH groups and PVP molecules Multi-fractal spectrum (MFS) analysis suggested that PEG improved the uniformity of the silica film but PVP reduced it, therefore the laser-damage resistance of the PEG-modified silica film was enhanced, but that of the PVP-modified silica film was weakened. ²⁹Si magic-angle spinning nuclear magnetic responance (MAS NMR) showed that PEG improved the condensation of Si ―O tetrahedron, but PVP did not. This led to differences between the laser-damage resistances of PEG-modified silica films and PVP-modified silica films.
- Laser-induced damage,
- Anti-reflection,
- Optical film,
- Surface fractal
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