Citation: ZHAO Jian-Xi, YANG Duo-Ping. Highly Viscoelastic Worm-Like Micelle Solution of Sodium Hexadecyl Sulfate Induced by Bolaform Counterions[J]. Acta Physico-Chimica Sinica, ;2012, 28(05): 1218-1222. doi: 10.3866/PKU.WHXB201202211 shu

Highly Viscoelastic Worm-Like Micelle Solution of Sodium Hexadecyl Sulfate Induced by Bolaform Counterions

1.
Institute of Colloid and Interface Chemistry, Department of Applied Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, P. R. China

Received Date: 16 November 2011
Available Online: 21 February 2012
Fund Project: 国家自然科学基金(20673021, 20873024) (20673021, 20873024)福建省自然科学基金(2010J01038)资助项目 (2010J01038)

The rheological behaviors of mixed aqueous solutions of sodium hexadecyl sulfate (SHS) and a bolaform salt, either N,N'-ethanediyl-α,ω-bis(ethyldimethylammonium bromide) (Bola2Et) or N,N'- propanediyl-α,ω-bis(trimethylammonium bromide) (Bola4), were investigated by steady-state and frequency-sweep measurements. The results showed that long worm-like micelles were formed in both systems at 45 °C, and the solutions exhibited high viscoelasticities, especially the SHS/Bola2Et system in which the solution had very high elasticity. The zero-shear viscosity of SHS/Bola2Et was as high as 2520 Pa·s, and the system was gel-like. These results were attributed to the formation of 2:1 complexes by electrostatic attraction. Since the spacers of both Bola counterions were shorter than the distance between quaternary ammonium ions under electrostatic equilibrium, the generated complex in shape favored formation of worm-like micelles. In comparison, it was difficult to induce SHS to form worm-like micelles by the addition of tetramethylammonium counterions, and the solution exhibited low viscosity.
- Anionic surfactant,
- Bola-counterion,
- Worm-like micelle,
- High viscoelasticity
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