Citation: ZHAO Jian-Xi, YANG Duo-Ping. Highly Viscoelastic Worm-Like Micelle Solution of Sodium Hexadecyl Sulfate Induced by Bolaform Counterions[J]. Acta Physico-Chimica Sinica, ;2012, 28(05): 1218-1222. doi: 10.3866/PKU.WHXB201202211 shu

Highly Viscoelastic Worm-Like Micelle Solution of Sodium Hexadecyl Sulfate Induced by Bolaform Counterions

1.
Institute of Colloid and Interface Chemistry, Department of Applied Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, P. R. China

Received Date: 16 November 2011
Available Online: 21 February 2012
Fund Project: 国家自然科学基金(20673021, 20873024) (20673021, 20873024)福建省自然科学基金(2010J01038)资助项目 (2010J01038)

The rheological behaviors of mixed aqueous solutions of sodium hexadecyl sulfate (SHS) and a bolaform salt, either N,N'-ethanediyl-α,ω-bis(ethyldimethylammonium bromide) (Bola2Et) or N,N'- propanediyl-α,ω-bis(trimethylammonium bromide) (Bola4), were investigated by steady-state and frequency-sweep measurements. The results showed that long worm-like micelles were formed in both systems at 45 °C, and the solutions exhibited high viscoelasticities, especially the SHS/Bola2Et system in which the solution had very high elasticity. The zero-shear viscosity of SHS/Bola2Et was as high as 2520 Pa·s, and the system was gel-like. These results were attributed to the formation of 2:1 complexes by electrostatic attraction. Since the spacers of both Bola counterions were shorter than the distance between quaternary ammonium ions under electrostatic equilibrium, the generated complex in shape favored formation of worm-like micelles. In comparison, it was difficult to induce SHS to form worm-like micelles by the addition of tetramethylammonium counterions, and the solution exhibited low viscosity.
- Anionic surfactant,
- Bola-counterion,
- Worm-like micelle,
- High viscoelasticity
1. [1]
  (1) Dreiss, C. A. Soft Matter 2007, 3, 956 and references therein.
2. [2]
  (2) Ezrahi, S.; Tuval, E.; Aserin, A. Adv. Colloid Interface Sci. 2006, 128-130, 77 and references therein.
3. [3]
  (3) Trickett, K.; Eastoe, J. Adv. Colloid Interface Sci. 2008, 144, 66 and references therein.
4. [4]
  (4) Shikata, T.; Hirata, H. Langmuir 1987, 3, 1081.
5. [5]
  (5) Shikata, T.; Hirata, H.; Kotaka, T. Langmuir 1988, 4, 354.
6. [6]
  (6) Makhloufi, R.; Hirsch, E.; Candau, S. J.; Binana-Limbele,W.; Zana, R. J. Phys. Chem. 1989, 93, 8095.
7. [7]
  (7) Ali, A. A.; Makhloufi, R. Phys. Rev. E 1997, 56, 4474.
8. [8]
  (8) Ali, A. A.; Makhloufi, R. Colloid Polym. Sci. 1999, 277, 270.
9. [9]
  (9) Clausen, T. M.; Vinson, P. K.; Minter, J. R.; Davis, H. T.; Talmon, Y.; Miller,W. G. J. Phys. Chem. 1992, 96, 474.
10. [10]
  (10) Aswal, V. K.; yal, P. S.; Thiyagarajan, P. J. Phys. Chem. B 1998, 102, 2469.
11. [11]
  (11) Soltero, J. F. A.; Puig, J. E.; Manero, O. Langmuir 1996, 12, 2654.
12. [12]
  (12) Maitland, G. C. Curr. Opin. Colloid Interface Sci. 2000, 5, 301.
13. [13]
  (13) (a) Magid, L. J.; Li, Z.; Butler, P. D. Langmuir 2000, 16, 10028. (b) Arleth, L.; Bergström, M.; Pedersen, J. S. Langmuir 2002, 18, 5343.
14. [14]
  (14) (a) Mu, J. H.; Li, G. Z. Colloid Polym. Sci. 2001, 279, 872. (b) Mu, J. H.; Li, G. Z.;Wang, Z.W. Rheol. Acta 2002, 41, 493. (c) Mu, J. H.; Li, G. Z.; Jia, X. L.;Wang, H. X.; Zhang, G. Y. J. Phys. Chem. B 2002, 106, 11685. (d) Mu, J. H.; Li, G. Z. Chem. Phys. Lett. 2001, 345, 100.
15. [15]
  (15) Kalur, G. C.; Raghavan, S. R. J. Phys. Chem. B 2005, 109, 8599.
16. [16]
  (16) Menger, F. M.; Littau, C. A. J. Am. Chem. Soc. 1993, 113, 1451.
17. [17]
  (17) Kern, F.; Lequeux, F.; Zana, R.; Candau, S. J. Langmuir 1994, 10, 1714.
18. [18]
  (18) Danino, D.; Talmon, Y.; Zana, R. Langmuir 1995, 11, 1448.
19. [19]
  (19) Oda, R.; Huc, I.; Homo, J. C.; Heinrich, B.; Schmutz, M.; Candau, S. Langmuir 1999, 15, 2384.
20. [20]
  (20) Moroi, Y.; Matuura, R.; Kuwamura, T.; Inokuma, S. J. Colloid Interface Sci. 1986, 113, 225.
21. [21]
  (21) Moroi, Y.; Murata, Y.; Fukuda, Y.; Kido, Y.; Seto,W.; Tanaka, M. J. Phys. Chem. 1992, 96, 8610.
22. [22]
  (22) Moroi, Y.; Matuura, R.; Tanaka, M.; Murata, Y.; Aikawa, Y.; Furutani, E.; Kuwamura, T.; Takahashi, H.; Inokuma, S. J. Phys. Chem. 1990, 94, 842.
23. [23]
  (23) Yang, D. P.; Zhao, J. X. Colloids Surf. A submitted.
24. [24]
  (24) Nlshikldo, N.; Kobayashl, H.; Tanaka, M. J. Phys. Chem. 1982, 86, 3170.
25. [25]
  (25) Shrestha, R. G.; Shrestha, L. K.; Aramaki, K. J. Colloid Interface Sci. 2007, 311, 276.
26. [26]
  (26) Pei, X. M.; Zhao, J. X.; Ye, Y. Z.; You, Y.;Wei, X. L. Soft Matter 2011, 7, 2953.
27. [27]
  (27) Pei, X. M.; Zhao, J. X.;Wei, X. L. J. Colloid Interface Sci. 2011, 356, 176.
28. [28]
  (28) Raghavan, S. R.; Kaler, E.W. Langmuir 2001, 17, 300.
29. [29]
  (29) Israelachvili, J. Intermolecular & Surface Forces Second Edition; Academic Press: San Die , 1992; pp 370-382.
30. [30]
  (30) Alami, E.; Beinert, G.; Marie, P.; Zana, R. Langmuir 1993, 9, 1465.
31. [31]
  (31) Wettig, S. D.; Verrall, R. E. J. Colloid Interface Sci. 2001, 235, 310.
32. [32]
  (32) Tanford, C. J. Phys. Chem. 1972, 76, 3020.
33. [33]
  (33) Granek, R.; Cates, M. E. J. Chem. Phys. 1992, 96, 4758.
34. [34]
  (34) Cates, M. E. Macromolecules 1987, 20, 2289.
35. [35]
  (35) Khatory, A.; Lequeux, F.; Kern, F.; Candau, S. J. Langumir 1993, 9, 1456.
36. [36]
  (36) Oda, R.; Narayanan, J.; Hassan, P. A.; Manohar, C.; Salkar, R. A.; Kern, F.; Candau, S. J. Langmuir 1998, 14, 4364.
37. [37]
  (37) Granek, R.; Cates, M. E. J. Chem. Phys. 1992, 96, 4758.
38. [38]
  (38) Acharya, D. P.; Kunieda, H.; Shiba, Y.; Aratani, K. J. Phys. Chem. B 2004, 108, 1790.
1. [1]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
2. [2]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
3. [3]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
4. [4]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
5. [5]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003
6. [6]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
7. [7]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
8. [8]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
9. [9]
  Guoze Yan , Bin Zuo , Shaoqing Liu , Tao Wang , Ruoyu Wang , Jinyang Bao , Zhongzhou Zhao , Feifei Chu , Zhengtong Li , Yusuke Yamauchi , Saad Melhi , Xingtao Xu . Opportunities and Challenges of Capacitive Deionization for Uranium Extraction from Seawater. Acta Physico-Chimica Sinica, 2025, 41(4): 100032-. doi: 10.3866/PKU.WHXB202404006
10. [10]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
11. [11]
  Xiaochen Zhang , Fei Yu , Jie Ma . 多角度数理模拟在电容去离子中的前沿应用. Acta Physico-Chimica Sinica, 2024, 40(11): 2311026-. doi: 10.3866/PKU.WHXB202311026
12. [12]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
13. [13]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
14. [14]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
15. [15]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
16. [16]
  Dongqi Cai , Fuping Tian , Zerui Zhao , Yanjuan Zhang , Yue Dai , Feifei Huang , Yu Wang . Exploration of Factors Influencing the Determination of Ion Migration Number by Hittorf Method. University Chemistry, 2024, 39(4): 94-99. doi: 10.3866/PKU.DXHX202310031
17. [17]
  Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021
18. [18]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
19. [19]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
20. [20]
  Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa_0.5Sr_0.5Fe_1.6Ni_0.4O_5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397

Get Citation

PDF

XML

Metrics

PDF Downloads(804)
Abstract views(2186)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142