Citation: YANG Zhi-Bin, DING Wei-Zhong. Reaction Pathway for Reforming Coke Oven Gas over NiO/M Catalyst in an Oxygen Permeation Membrane Reactor[J]. Acta Physico-Chimica Sinica, ;2012, 28(04): 935-941. doi: 10.3866/PKU.WHXB201202133 shu

Reaction Pathway for Reforming Coke Oven Gas over NiO/M Catalyst in an Oxygen Permeation Membrane Reactor

YANG Zhi-Bin ^1, ,
DING Wei-Zhong ²

1.
1. School of Metallurgy and Materials Engineering, Zhangjiagang Campus, Jiangsu University of Science and Technology, Zhangjiagang 215600, Jiangsu Province, P. R. China;
2. Shanghai Key Laboratory of Modern Metallurgy and Material Processing, Shanghai University, Shanghai 200072, P. R. China

Received Date: 22 October 2011
Available Online: 13 February 2012
Fund Project: 国家高技术研究发展计划(863)(2006AA11A189) (863)(2006AA11A189) 江苏科技大学人才引进(35271103) (35271103)

The reaction pathway for reforming coke oven gas (COG) in an oxygen permeation membrane was analyzed. Through the reforming experiments of H₂+N₂, CH₄+N₂, CO+N₂, H₂+CH₄+N₂ mixtures, with or without a catalyst and the catalyst bed, the reaction scheme is proposed: H₂ in COG is absorbed and dissociates on Ni particle on catalyst, the H* of dissociation migrates to high active site (“triphase boundary”) and reacts with diffused oxygen or lattice oxygen on film surface to form H₂O. The CH₄ also could be dissociated on active metal surface to form CH₃^* and H^*. The H₂O formed reacts with the C species to form H₂ and CO. At last the residual H₂O reacts with the residual CH₄ on the catalyst bed to form H₂ and CO.
- Oxygen permeation membrane reactor,
- Coke oven gas,
- Reforming,
- Reaction pathway
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