Citation: WANG Zhao, WU Feng, SU Yue-Feng, BAO Li-Ying, CHEN Lai, LI Ning, CHEN Shi. Preparation and Characterization of xLi₂MnO₃·(1-x)Li[Ni_1/3Mn_1/3Co_1/3]O₂ Cathode Materials for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2012, 28(04): 823-830. doi: 10.3866/PKU.WHXB201202102 shu

Preparation and Characterization of xLi₂MnO₃·(1-x)Li[Ni_1/3Mn_1/3Co_1/3]O₂ Cathode Materials for Lithium-Ion Batteries

1.
National Development Center of Hi-Tech Green Materials, School of Chemical Engineering & Environment, Beijing Institute of Technology, Beijing 100081, P. R. China

Received Date: 17 November 2011
Available Online: 10 February 2012
Fund Project: 国家重点基础研究发展规划(973) (2009CB220100)，国家自然科学基金(51102018) (973) (2009CB220100)，国家自然科学基金(51102018)国家高技术研究发展计划(863) (SQ2010AA1123116001)资助项目 (863) (SQ2010AA1123116001)

The lithium rich cathode materials xLi₂MnO₃·(1-x)Li[Ni_1/3Mn_1/3Co_1/3]O₂ (x=0.4, 0.5, 0.6) were successfully synthesized via sol-gel method with calcination in air. The transition metal acetate, lithium acetate, and citric acid were used as raw materials. The as-prepared materials were characterized by X-ray diffraction (XRD), scaning electron microscopy (SEM), and electrochemical tests. The material 0.5Li₂MnO₃·0.5LiNi_1/3Mn_1/3Co_1/3]O₂, which was obtained after calcination at 900 °C for 12 h, exhibited fine microstructures and od electrochemical performance. When cycled at 2.0-4.8 V with a current density of 20 mA·g^-1 at room temperature, 0.5Li₂MnO₃·0.5LiNi_1/3Mn_1/3Co_1/3]O₂ delivered a initial discharge specific capacity of 260.0 mAh·g^-1, and maintained a capacity of 244.7 mAh·g^-1 after 40 cycles (capacity retention 94.12%).
- Lithium-ion battery,
- Sol-gel,
- Solid solution,
- Cathode material,
- Electrochemical performance
1. [1]
  (1) Ohzuku, T.; Ueda, A. J. Electrochem. Soc. 1994, 141, 2972.
2. [2]
  (2) Wu, Y. P.; Zhang, H. P.;Wu, F.; Zhang, P.; Guan, S. Y. Green Power Material; Chemical Industry Press: Beijing, 2008; pp 23-30. [吴宇平, 张汉平, 吴锋, 张鹏, 关士友. 绿色电源材料. 北京: 化学工业出版社, 2008: 23-30.]
3. [3]
  (3) Lu, J. B.; Tang, Z. L.; Le, B.; Zhang, Z. T.; Shen,W. C. Chem. J. Chin. Univ. 2005, 26, 2093. [卢俊彪, 唐子龙, 乐斌, 张中太, 沈万慈. 高等学校化学学报, 2005, 26, 2093.]
4. [4]
  (4) He, H.; Cheng, X.; Zhang, Y. J. Funct. Mater. 2004, 35, 667. [贺慧, 程璇, 张颖. 功能材料, 2004, 35, 667.]
5. [5]
  (5) Gummow, R. J.; Kock, A.; Thackery, M. M. Solid State Ionics 1994, 69, 59.
6. [6]
  (6) Chang, Z. R.; Chen, Z. J.;Wu, F.; Tang, H.W.; Zhu, Z. H. Acta Chim. Sin. 2008, 66, 890. [常照荣, 陈中军, 吴锋, 汤宏伟, 朱志红. 化学学报, 2008, 66, 890.]
7. [7]
  (7) Thackeray, M. M.; Kang, S. H.; Johnson, C. S. J. Mater. Chem. 2007, 17, 3112.
8. [8]
  (8) Johnson, C. S.; Li, N. C.; Lefief, C.; Thackeray, M. M. Electrochem. Commun. 2007, 9, 787.
9. [9]
  (9) Wu, Y.; Manthiram, A. Electrochem. Solid-State Lett. 2006, 9, A221.
10. [10]
  (10) Wu, Y.; Manthiram, A. Solid State Ionics 2009, 180, 50.
11. [11]
  (11) Gao, J.; Kim, J.; Manthiram, A. Electrochemistry Communications 2009, 11, 84.
12. [12]
  (12) Kim, J. H.; Park, C.W.; Sun, Y. K. Solid State Ionics 2003, 164, 43.
13. [13]
  (13) Wang, Q. Y.; Liu, J.; Murugan, A. V.; Manthiram, A. J. Mater. Chem. 2009, 19, 4965.
14. [14]
  (14) Liu, J.; Reeja-Jayan, B.; Manthiram, A. J. Phys. Chem. C 2010, 114, 9528.
15. [15]
  (15) Lee, Y. J.; Kim, M. G.; Cho, J. Nano Lett. 2008, 8, 957.
16. [16]
  (16) Kim, M. G.; Jo, M.; Hong, Y. S.; Cho, J. Chem. Commun. 2009, 218.
17. [17]
  (17) Lu, Z. H.; Dahn, J. R. J. Electrochem. Soc. 2002, 149, A815.
18. [18]
  (18) Wei, Y.;Wang, L. J.; Yan, A. J.; Sha, O.; Tang, Z. Y.; Ma, L. Acta Phys. -Chim Sin. 2011, 27, 2587. [魏怡, 王利娟, 闫继, 沙鸥, 唐致远, 马莉. 物理化学学报, 2011, 27, 2587.]
19. [19]
  (19) Ohzuku, T.; Ueda, A.; Nagayama, M. J. Electrochem. Soc. 1993, 140, 1862.
20. [20]
  (20) Myung, S. T.; Kumagai, N.; Komaba, S.; Chungb, H. T. Solid State Ionics 2001, 139, 47.
21. [21]
  (21) Jiao, L. F.; Zhang, M.; Yuan, H. T.; Zhao, M.; Guo, J.;Wang, W.; Zhou, X. D.;Wang,Y. M. Journal of Power Sources 2007, 167, 178.
22. [22]
  (22) Kim, Y.; Kim, H. S.; Martin, S.W. Electrochim. Acta 2006, 52, 1316.
23. [23]
  (23) Kang, K.; Meng, Y. S.; Breger, J.; Grey, C. P.; Ceder, G. Science 2006, 311, 977.
24. [24]
  (24) Armstrong, A. R.; Holzapfel, M.; Novak, P.; Johnson, C. S.; Kang, A. H.; Thackeray, M. M.; Bruce, P. G. J. Am. Chem. Soc. 2006, 128, 8694.
25. [25]
  (25) Miao, J. H.; Chai, Z. Q.; Sun, L. Chinese Battery Industry 2000, 5, 175. [缪建红, 柴志强, 孙丽.电池工业, 2000, 5, 175.]
26. [26]
  (26) Yu, L. Y.; Qiu,W. H.; Lian, F.; Liu,W.; Kang, X. L.; Huang, J. Y. Materials Letters 2008, 62, 3010.
27. [27]
  (27) Julien, C. M.; Massot, M. Mater. Sci. Eng. B 2003, 100, 69.
28. [28]
  (28) Lu, Z. H.; Beaulieu, L. Y.; Donaberger, R. A.; Thomas, C. L.; Dahn, J. R. J. Electrochem. Soc. 2002, 149, A778.
29. [29]
  (29) Dahn, J. R.; Sacken, U.; Michal, C. A. Solid State Ionics 1990, 44, 87.
1. [1]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
2. [2]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
3. [3]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
4. [4]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
5. [5]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
6. [6]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
7. [7]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
8. [8]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
9. [9]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
10. [10]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
11. [11]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
12. [12]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
13. [13]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
14. [14]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
15. [15]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
16. [16]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
17. [17]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
18. [18]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
19. [19]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
20. [20]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444

Get Citation

PDF

XML

Metrics

PDF Downloads(1477)
Abstract views(2739)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Characterization of xLi2MnO3·(1-x)Li[Ni1/3Mn1/3Co1/3]O2 Cathode Materials for Lithium-Ion Batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Characterization of xLi₂MnO₃·(1-x)Li[Ni_1/3Mn_1/3Co_1/3]O₂ Cathode Materials for Lithium-Ion Batteries