Citation: WANG Zhao, WU Feng, SU Yue-Feng, BAO Li-Ying, CHEN Lai, LI Ning, CHEN Shi. Preparation and Characterization of xLi₂MnO₃·(1-x)Li[Ni_1/3Mn_1/3Co_1/3]O₂ Cathode Materials for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2012, 28(04): 823-830. doi: 10.3866/PKU.WHXB201202102 shu

Preparation and Characterization of xLi₂MnO₃·(1-x)Li[Ni_1/3Mn_1/3Co_1/3]O₂ Cathode Materials for Lithium-Ion Batteries

1.
National Development Center of Hi-Tech Green Materials, School of Chemical Engineering & Environment, Beijing Institute of Technology, Beijing 100081, P. R. China

Received Date: 17 November 2011
Available Online: 10 February 2012
Fund Project: 国家重点基础研究发展规划(973) (2009CB220100)，国家自然科学基金(51102018) (973) (2009CB220100)，国家自然科学基金(51102018)国家高技术研究发展计划(863) (SQ2010AA1123116001)资助项目 (863) (SQ2010AA1123116001)

The lithium rich cathode materials xLi₂MnO₃·(1-x)Li[Ni_1/3Mn_1/3Co_1/3]O₂ (x=0.4, 0.5, 0.6) were successfully synthesized via sol-gel method with calcination in air. The transition metal acetate, lithium acetate, and citric acid were used as raw materials. The as-prepared materials were characterized by X-ray diffraction (XRD), scaning electron microscopy (SEM), and electrochemical tests. The material 0.5Li₂MnO₃·0.5LiNi_1/3Mn_1/3Co_1/3]O₂, which was obtained after calcination at 900 °C for 12 h, exhibited fine microstructures and od electrochemical performance. When cycled at 2.0-4.8 V with a current density of 20 mA·g^-1 at room temperature, 0.5Li₂MnO₃·0.5LiNi_1/3Mn_1/3Co_1/3]O₂ delivered a initial discharge specific capacity of 260.0 mAh·g^-1, and maintained a capacity of 244.7 mAh·g^-1 after 40 cycles (capacity retention 94.12%).
- Lithium-ion battery,
- Sol-gel,
- Solid solution,
- Cathode material,
- Electrochemical performance
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Preparation and Characterization of xLi₂MnO₃·(1-x)Li[Ni_1/3Mn_1/3Co_1/3]O₂ Cathode Materials for Lithium-Ion Batteries