Citation: YANG Wei-Hua, YANG Wu-Tao, LIN Xiao-Yan. Preparation and Characterization of a Novel Bi-Doped PbO₂ Electrode[J]. Acta Physico-Chimica Sinica, ;2012, 28(04): 831-836. doi: 10.3866/PKU.WHXB201202101 shu

Preparation and Characterization of a Novel Bi-Doped PbO₂ Electrode

1.
College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, Fujian Province, P. R. China

Received Date: 3 January 2012
Available Online: 10 February 2012
Fund Project: 国家自然科学基金(21103055) (21103055)华侨大学基本科研业务专项基金(JB-ZR1139)资助项目 (JB-ZR1139)

A novel high-performance PbO₂ electrode modified with Bi³⁺ (Bi-PbO₂) was prepared by electrodeposition. The microstructure and electrochemical properties of the modified electrode were investigated using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS), fluorospectrophotometry (FP), Mott-Schottky analysis, electrochemical impedance spectroscopy (EIS), and linear-sweep voltammetry (LSV). The results of SEM, EDS, XPS, XRD, and UV-Vis DRS show that insertion of Bi³⁺ , which is in the form of Bi₂O₃, into the PbO₂ film can reduce its particle size, change its crystal cell parameters, and narrow its bandgap (E_g). FP analysis reveals that the electrocatalytic activity of the Bi-PbO₂ electrode in the degradation of organic materials is higher than that of the PbO₂ electrode because more hydroxyl radicals can be generated on its surface. Electrochemical performance tests show that the modified electrode has a more negative flat-band potential (E_fb), larger active surface area, lower charge-transfer resistance, and higher oxygen-evolution potential; these characteristics promote the electrocatalytic activity of the Bi-PbO₂ electrode in the decomposition of organic materials.
- Bismuth,
- Lead dioxide,
- Bandgap,
- Flatband potential,
- Electro-catalytic activity
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Preparation and Characterization of a Novel Bi-Doped PbO₂ Electrode