Citation: YANG Wei-Hua, YANG Wu-Tao, LIN Xiao-Yan. Preparation and Characterization of a Novel Bi-Doped PbO₂ Electrode[J]. Acta Physico-Chimica Sinica, ;2012, 28(04): 831-836. doi: 10.3866/PKU.WHXB201202101 shu

Preparation and Characterization of a Novel Bi-Doped PbO₂ Electrode

1.
College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, Fujian Province, P. R. China

Received Date: 3 January 2012
Available Online: 10 February 2012
Fund Project: 国家自然科学基金(21103055) (21103055)华侨大学基本科研业务专项基金(JB-ZR1139)资助项目 (JB-ZR1139)

A novel high-performance PbO₂ electrode modified with Bi³⁺ (Bi-PbO₂) was prepared by electrodeposition. The microstructure and electrochemical properties of the modified electrode were investigated using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS), fluorospectrophotometry (FP), Mott-Schottky analysis, electrochemical impedance spectroscopy (EIS), and linear-sweep voltammetry (LSV). The results of SEM, EDS, XPS, XRD, and UV-Vis DRS show that insertion of Bi³⁺ , which is in the form of Bi₂O₃, into the PbO₂ film can reduce its particle size, change its crystal cell parameters, and narrow its bandgap (E_g). FP analysis reveals that the electrocatalytic activity of the Bi-PbO₂ electrode in the degradation of organic materials is higher than that of the PbO₂ electrode because more hydroxyl radicals can be generated on its surface. Electrochemical performance tests show that the modified electrode has a more negative flat-band potential (E_fb), larger active surface area, lower charge-transfer resistance, and higher oxygen-evolution potential; these characteristics promote the electrocatalytic activity of the Bi-PbO₂ electrode in the decomposition of organic materials.
- Bismuth,
- Lead dioxide,
- Bandgap,
- Flatband potential,
- Electro-catalytic activity
1. [1]
  (1) Martínez-Huitle, C. A.; Ferro, S. Chem. Soc. Rev. 2006, 35, 1324.
2. [2]
  (2) Awad, H. S.; Galwa, N. A. Chemosphere 2005, 61, 1327.
3. [3]
  (3) Panizza, M.; Cerisola, G. Electrochim. Acta 2003, 48, 3491.
4. [4]
  (4) Kokoh, K. B.; Hahn, F.; Belgsir, E. M.; Lamy, C.; Andrade, A. R.; Olivi, P.; Motheo, A. J.; Tremiliosi-Filho, G. Electrochim. Acta 2004, 49, 2077.
5. [5]
  (5) Andradea, L. S.; Rocha-Filhoa, R. C.; Bocchia, N.; Biaggioa, S. R.; Iniestab, J.; García-Garciab, V.; Montielb, V. J. Hazard Mater. 2008, 153, 252.
6. [6]
  (6) Kong, J.; Shi, S.; Kong, L.; Zhu, X.; Ni, J. Electrochim. Acta 2007, 53, 2048.
7. [7]
  (7) Song, Y.;Wei, G.; Xiong, R. Electrochim. Acta 2007, 52, 7022.
8. [8]
  (8) Ai, S.; Gao, M.; Zhang,W.;Wang, Q.; Xie, Y.; Jin, L. Talanta 2004, 62, 445.
9. [9]
  (9) Velichenko, A. B.; Amadelli, R.; Baranova, E. A. J. Electroanal. Chem. 2002, 527, 56.
10. [10]
  (10) Li, G.; Qu, J.; Zhang, X.; Ge, J. Water Res. 2006, 40, 213.
11. [11]
  (11) Tong, S.; Ma, C.; Feng, H. Electrochim. Acta 2008, 53, 3002.
12. [12]
  (12) Liu, Y.; Liu, H. Electrochim. Acta 2008, 53, 5077.
13. [13]
  (13) Anglada, A.; Urtiaga, A.; Ortiz, I. Environ. Sci. Technol. 2009, 43, 2035.
14. [14]
  (14) Lindsey, M. E.; Tarr, M. A. Chemosphere 2000, 41, 409.
15. [15]
  (15) Lindsey, M. E.; Tarr, M. A. Environ. Sci. Technol. 2000, 34, 444.
16. [16]
  (16) Baumanis, C.; Bahnemann, D.W. J. Phys. Chem. C 2008, 112, 19097.
17. [17]
  (17) Cong, Y.;Wu, Z. J. Phys. Chem. C 2007, 111, 3442.
18. [18]
  (18) Yua, N.; Gao, L.; Zhao, S.;Wang, Z. Electrochim. Acta 2009, 54, 3835.
19. [19]
  (19) Liu, H.; Liu, Y.; Zhang, C.; Shen, R. J. Appl. Electrochem. 2008, 38, 101.
20. [20]
  (20) Radecka, M.; Rekas, M.; Trenczek-Zajac, A.; Zakrzewska, K.; J. Power Sources 2008, 181, 46.
21. [21]
  (21) El-Bahy, Z. M.; Ismail, A. A.; Mohamed, R. M. J. Hazard. Mater. 2009, 166, 138.
22. [22]
  (22) Li, H.;Wang, D.; Fan, H.;Wang, P.; Jiang, T.; Xie, T. J. Colloid Interface Sci. 2011, 354, 175.
23. [23]
  (23) Banerjee, S.; Banerjee, S. Int. J. Eng. Sci. 2011, 3, 2134.
24. [24]
  (24) Ciríaco, L.; Anjo, C.; Correia, J.; Pacheco, M. J.; Lopes, A. Electrochim. Acta 2009, 54, 1464.
25. [25]
  (25) Kong, D.; Lu,W.; Feng, Y.; Bi, S. Prog. Chem. 2009, 21, 1107.
26. [26]
  (26) Harrington, S. P.; Devine, T. M. J. Electrochem. Soc. 2008, 155, 381.
27. [27]
  (27) Cheng, F.; Su, Y.; Liang, J.; Tao, Z. Chem. Mater. 2010, 22, 898.
28. [28]
  (28) Song, S.; Zhang, H.; Ma, X.; Shao, Z.; Baker, R. T.; Yi, B. Int . J. Hydrog. Energy 2008, 33, 4955.
29. [29]
  (29) Donne, S.W.; Kennedy, J. H. J. Appl. Electrochem. 2004, 34, 159.
30. [30]
  (30) Lao, G. H.; Shao, H. B.; Fan, Y. Q.;Wang, J. M.; Zhang, J. Q.; Cao, C. N. Acta Phys. -Chim. Sin. 2011, 27, 627. [劳国洪, 邵海波, 樊玉欠, 王建明, 张鉴清, 曹楚南. 物理化学学报, 2011, 27, 627.]
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Preparation and Characterization of a Novel Bi-Doped PbO₂ Electrode