Citation: ZHAO Lei, XU Xiang-Sheng, ZHANG Kai-Chao, YAN Xin-Huan. Selective Hydrogenation of Cinnamaldehyde with Efficient Assembled Pt-Fe/C Catalysts[J]. Acta Physico-Chimica Sinica, ;2012, 28(04): 923-927. doi: 10.3866/PKU.WHXB201202081 shu

Selective Hydrogenation of Cinnamaldehyde with Efficient Assembled Pt-Fe/C Catalysts

1.
State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, P. R. China

Received Date: 21 October 2011
Available Online: 8 February 2012

Platinum nanoparticles (d=2.0 nm) were obtained by decomposition of Pt₂(dba)₃ (dba: dibenzalacetone) and captured by active carbon modified with Fe to prepare a Pt-Fe/C catalyst. Transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and energy dispersive X-ray spectrometry (EDS) were used to characterize the size, distribution, electronic state of the Pt and Fe nanoparticles, and surface elements of the catalysts. The catalysts selectively hydrogenated cinnamaldehyde (CAL) to cinnamyl alcohol (COL), and the activity was more than one time that of a Pt/C catalyst prepared by the impregnation method. The 1% (w, mass fraction)Pt-1.5% (w)Fe/C catalyst exhibited the highest activity and selectivity at 60 °C, 2.5 h, and 4.0 MPa H₂. The conversion for CAL was 99.2%, and the selectivity of CAL to COL was 85.0%.
- Pt,
- Fe,
- Active carbon,
- Cinnamaldehyde,
- Cinnamyl alcohol,
- Selective hydrogenation
1. [1]
  (1) Arvela, P. M.; Hajek, J.; Salmi, T.; Murzin, D. Y. Appl. Catal. A: Gen. 2005, 292, 1.
2. [2]
  (2) Gallezot, P.; Richard, D. Catal. Rev. 1998, 40, 81.
3. [3]
  (3) Chen, X. F.; Li, H. X.; Dai,W. L. Appl. Catal. A: Gen. 2003, 253, 359.
4. [4]
  (4) Li, H. X.; Chen, X. F.;Wang, M. H. Appl. Catal. A: Gen. 2002, 225, 117.
5. [5]
  (5) Wang, H.; Shu, Y. Y.; Zheng, M. Y. Catal. Lett. 2008, 124, 219.
6. [6]
  (6) Galletti, A. M. R.; Antonetti, C.; Venezia, A. M.; Giambastiani, G. Appl. Catal. A: Gen. 2010, 386, 124.
7. [7]
  (7) Qiu, J. S.; Zhang, H. Z.;Wang, X. N. Catal. Lett. 2006, 88, 269.
8. [8]
  (8) Li, Y.; Li, Z. G.; Zhou, R. X. J. Mol. Catal. A 2008, 279, 140.
9. [9]
  (9) Mahata, N.; ncalves, F.; Pereira, M. F. R.; Figueiredo, J. L. Appl. Catal. A: Gen. 2008, 339, 159.
10. [10]
  (10) Hajek, J.; Murzin, D. Y. Chem. Res. 2004, 43, 2030.
11. [11]
  (11) Hajek, J.;Warna, J.; Murzin, D. Y. Chem. Res. 2004, 43, 2039.
12. [12]
  (12) Carrillo, J. H.; Aramendia, M. A.; Marinas, A.; Marinas, J. M.; Urbano, F. J. Appl. Catal. A: Gen. 2010, 385, 190.
13. [13]
  (13) Hsu, C. Y.; Chiu, T. C.; Shih, M. H.; Tsai,W. J.; Chen,W. Y.; Lin, C. H. J. Phys. Chem. 2010, 114, 4502.
14. [14]
  (14) Chatterjee, M.; Ikushima, Y.; Yokoyama, T.; Suzuki, T. Microporous Mesoporous Mat. 2009, 117, 201.
15. [15]
  (15) Plomp, A. J.; Vuori, H.; Krause, A. O. I.; Jong, K. P.; Bitter, J. H. Appl. Catal. A: Gen. 2008, 351, 9.
16. [16]
  (16) Li, Y.; Ge, C. H.; Zhao, J.; Zhou, R. X. Catal. Lett. 2008, 126, 280.
17. [17]
  (17) Ma, H. X.;Wang, L. C.; Chen, L. Y.; Dong, C.; Yu,W. C.; Huang, T.; Qian, Y. T. Catal. Commun. 2007, 8, 452.
18. [18]
  (18) Han, X. X.; Zhou, R. X.; Yue, B. H.; Zheng, X. M. Catal. Lett. 2006, 109, 3.
19. [19]
  (19) Mao, J. Z.; Yan, X. H.; Gu, H. Z.; Jiang, L. C. Chin. J. Catal. 2009, 30, 182. [毛建忠, 严新焕, 顾辉子, 江玲超. 催化学报, 2009, 30, 182.]
20. [20]
  (20) Englisch, M.; Ranade, V. S.; Lercher, J. A. Mol. Catal. A: Chem. 1997, 121, 69.
21. [21]
  (21) Amornpattana,W. K.;Winterbottom, J. M. Catal. Today 2001, 66, 277.
1. [1]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
2. [2]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
3. [3]
  Qingying Gao , Tao Luo , Jianyuan Su , Chaofan Yu , Jiazhu Li , Bingfei Yan , Wenzuo Li , Zhen Zhang , Yi Liu . Refinement and Expansion of the Classic Cinnamic Acid Synthesis Experiment. University Chemistry, 2024, 39(5): 243-250. doi: 10.3866/PKU.DXHX202311074
4. [4]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
5. [5]
  Yunhao Zhang , Yinuo Wang , Siran Wang , Dazhen Xu . Progress in Selective Construction of Functional Aromatics from Nitrogenous Cycloalkanes. University Chemistry, 2024, 39(11): 136-145. doi: 10.3866/PKU.DXHX202401083
6. [6]
  Yukun Chang , Haoqin Huang , Baolei Wang . Preparation of Trans-Cinnamic Acid via “One-Pot” Protocol of Aldol Condensation-Hydrolysis Reaction: Recommending an Improved Organic Synthesis Experiment. University Chemistry, 2024, 39(4): 322-328. doi: 10.3866/PKU.DXHX202309095
7. [7]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
8. [8]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
9. [9]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
10. [10]
  Yuan Zheng , Quan Lan , Zhenggen Zha , Lingling Li , Jun Jiang , Pingping Zhu . Teaching Reform of Organic Synthesis Experiments by Introducing Reverse Thinking and Design Concepts: Taking the Synthesis of Cinnamic Acid Based on Retrosynthetic Analysis as an Example. University Chemistry, 2024, 39(6): 207-213. doi: 10.3866/PKU.DXHX202310065
11. [11]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
12. [12]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
13. [13]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
14. [14]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
15. [15]
  Xiuyun Wang , Jiashuo Cheng , Yiming Wang , Haoyu Wu , Yan Su , Yuzhuo Gao , Xiaoyu Liu , Mingyu Zhao , Chunyan Wang , Miao Cui , Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067
16. [16]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
17. [17]
  Tong Zhou , Liyi Xie , Chuyu Liu , Xiyan Zheng , Bao Li . Between Sobriety and Intoxication: The Fascinating Journey of Sauce-Flavored Latte. University Chemistry, 2024, 39(9): 55-58. doi: 10.12461/PKU.DXHX202312048
18. [18]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
19. [19]
  Jinfeng Chu , Yicheng Wang , Ji Qi , Yulin Liu , Yan Li , Lan Jin , Lei He , Yufei Song . Comprehensive Chemical Experiment Design: Convenient Preparation and Characterization of an Oxygen-Bridged Trinuclear Iron(III) Complex. University Chemistry, 2024, 39(7): 299-306. doi: 10.3866/PKU.DXHX202310105
20. [20]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077

Get Citation

PDF

XML

Metrics

PDF Downloads(865)
Abstract views(2535)
HTML views(13)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142