Citation: ZHAO Lei, XU Xiang-Sheng, ZHANG Kai-Chao, YAN Xin-Huan. Selective Hydrogenation of Cinnamaldehyde with Efficient Assembled Pt-Fe/C Catalysts[J]. Acta Physico-Chimica Sinica, ;2012, 28(04): 923-927. doi: 10.3866/PKU.WHXB201202081 shu

Selective Hydrogenation of Cinnamaldehyde with Efficient Assembled Pt-Fe/C Catalysts

1.
State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, P. R. China

Received Date: 21 October 2011
Available Online: 8 February 2012

Platinum nanoparticles (d=2.0 nm) were obtained by decomposition of Pt₂(dba)₃ (dba: dibenzalacetone) and captured by active carbon modified with Fe to prepare a Pt-Fe/C catalyst. Transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and energy dispersive X-ray spectrometry (EDS) were used to characterize the size, distribution, electronic state of the Pt and Fe nanoparticles, and surface elements of the catalysts. The catalysts selectively hydrogenated cinnamaldehyde (CAL) to cinnamyl alcohol (COL), and the activity was more than one time that of a Pt/C catalyst prepared by the impregnation method. The 1% (w, mass fraction)Pt-1.5% (w)Fe/C catalyst exhibited the highest activity and selectivity at 60 °C, 2.5 h, and 4.0 MPa H₂. The conversion for CAL was 99.2%, and the selectivity of CAL to COL was 85.0%.
- Pt,
- Fe,
- Active carbon,
- Cinnamaldehyde,
- Cinnamyl alcohol,
- Selective hydrogenation
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沈阳化工大学材料科学与工程学院沈阳 110142