Citation: CHE Qian, ZHANG Fang, ZHANG Xiao-Gang, LU Xiang-Jun, DING Bing, ZHU Jia-Jia. Preparation of Ordered Mesoporous Carbon/NiCo₂O₄ Electrode and Its Electrochemical Capacitive Behavior[J]. Acta Physico-Chimica Sinica, ;2012, 28(04): 837-842. doi: 10.3866/PKU.WHXB201202074 shu

Preparation of Ordered Mesoporous Carbon/NiCo₂O₄ Electrode and Its Electrochemical Capacitive Behavior

1.
College of Material Science & Engneering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China

Received Date: 31 October 2011
Available Online: 7 February 2012
Fund Project: 国家自然科学基金(20873064) (20873064) 江苏省自然科学基金(BK2011030) (BK2011030)高等学校博士学科点专项科研基金(20060287026)资助项目 (20060287026)

OMC/NiCo₂O₄ composite was prepared by co-precipitation with ordered mesoporous carbon (OMC) as a support. The crystalline structure and morphology of the composite were investigated by X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, and transmission electron microscopy (TEM). TEM images showed that NiCo₂O₄ was uniformly coated on the OMC. Cyclic voltammetry and galvanostatic charge-discharge were used to investigate the electrochemical performance of the OMC/ NiCo₂O₄ composite. The specific capacitances of the OMC/NiCo₂O₄ composite with a mass fraction of 40% NiCo₂O₄ were 577.0 F·g^-1 at a current density of 1 A·g^-1 and 470.8 F·g^-1 at 8 A·g^-1. The specific capacitance remains at 508.4 F·g^-1 after 2000 cycles at a current density of 2 A·g^-1, with a capacitance retention of 92.7%.
- Supercapacitor,
- Ordered mesoporous carbon,
- NiCo₂O₄,
- Co-precipitation method
1. [1]
  (1) Conway, B. E. J. Electrochem. Soc. 1991, 138, 1539.
2. [2]
  (2) Miller, J. R. Electrochim. Acta 2006, 52, 1703.
3. [3]
  (3) Liu, C.; Li, F.; Ma, L. P.; Cheng, H. M. Adv. Mater. 2010, 22, E28.
4. [4]
  (4) Zhang, F.; Yuan, C. Z.; Zhang, X. G.; Zhang, L. J.; Xu, K. Acta Phys. - Chim. Sin. 2010, 26 (12), 3175. [张方, 原长洲, 张校刚, 章罗江, 徐科. 物理化学学报, 2010, 26 (12), 3175.]
5. [5]
  (5) Yuan, C. Z.; Gao, B.; Shen, L. F.; Yang, S. D. ; Hao, L. ; Lu, X. J.; Zhang, F.; Zhang, L. J.; Zhang, X. G. Nanoscale 2011, 3, 529.
6. [6]
  (6) Hwang, S.W.; Hyun, S. H. J. Non-Cryst. Solids 2004, 347, 238.
7. [7]
  (7) Kim, N. D.; Kim,W.; Joo, J. B.; Oh, S.; Kim, P.; Kim, Y.; Yi, J. J. Power Sources 2008, 180, 671.
8. [8]
  (8) Li,W.; Chen, D.; Li, Z.; Shi, Y.;Wan, Y.; Huang, J.; Yang, J.; Zhao, D.; Jiang, Z. Electrochem. Commun. 2007, 9, 569.
9. [9]
  (9) Hu, C. C.; Chang, K. H.; Lin, M. C.;Wu, Y. T. Nano Lett. 2006, 6, 2690.
10. [10]
  (10) Sugimoto,W.; Iwata, H.; Yokoshima, K.; Murakami, Y.; Takasu, Y. J. Phys. Chem. B 2005, 109, 7330.
11. [11]
  (11) Wu, Z. S.; Ren,W. C.;Wang, D.W.; Li, F.; Liu, B. L.; Cheng, H. M. ACS Nano 2010, 4, 5835.
12. [12]
  (12) Xia, X. H.; Tu, J. P.; Mai, Y. J.;Wang, X. L.; Gu, C. D.; Zhao, X. B. J. Mater. Chem. 2011, 21, 9319.
13. [13]
  (13) Cao, C. Y.; Guo.W.; Cui, Z. M.; Song,W. G.; Cai,W. J. Mater. Chem. 2011, 21, 3204.
14. [14]
  (14) Hu, C. C.; Chen,W. C.; Chang, K. H. J. Electrochem. Soc. 2004, 151, A281.
15. [15]
  (15) Yu, L. Q.; Chen, S. L.; Chang, S.; Li, Y. H.; Gao, Y. Y.;Wang, G. L.; Cao, D. X. Acta Phys .-Chim. Sin. 2011, 27 (3), 615. [于丽秋, 陈书礼, 常莎, 李云虎, 高胤义, 王贵领, 曹殿学. 物理化学学报.2011, 27 (3), 615.]
16. [16]
  (16) Wei, T. Y.;Chen, C. H.; Chien, H. C.; Lu, S. Y.; Hu, C. C. Adv. Mater. 2010, 22, 347.
17. [17]
  (17) Gupta V.; Gupta S.; Miura N. J. Power Sources 2010, 195, 3757.
18. [18]
  (18) Yin,W. Y.; Chen, X.; Cao, M. H.; Hu, C.W.;Wei, B. Q. J. Phys. Chem. C. 2009, 113, 15897.
19. [19]
  (19) Lu, B. P.; Bai, J.; Bo, X. J.; Zhu, L. D.; Guo, L. P. Electrochim. Acta 2010, 55, 8724.
20. [20]
  (20) Cui, B.; Lin, H.; Li, J. B.; Li, X.; Yang, J.; Tao, J. Adv. Funct. Mater. 2008, 18, 1441.
21. [21]
  (21) Singh, R. N.; Koenig, J. F.; Poillerat, G.; Chartier, P. J. Electrochem. Soc. 1990, 137, 1408.
22. [22]
  (22) Chi, B.; Lin, H.; Li, J.;Wang, N.; Yang, J. Int. J. Hydrog. Energy 2006, 31, 1210.
23. [23]
  (23) Aboutalebi, S. H.; Chidembo, A. T.; Chidembo, Salari, M.; Konstantinov, K.;Wexler, D.; Liu, H. K.; Dou, S. X. Energy Environ. Sci. 2011, 4, 1855.
24. [24]
  (24) Meher, S. K.; Justin, P.; Rao, G. R. ACS Appl. Mater. Interfaces 2011, 3, 2063.
25. [25]
  (25) Wang, Y. G.; Li, H. Q.; Xia, Y. Y. Adv. Mater. 2006, 18, 2619.
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Ordered Mesoporous Carbon/NiCo2O4 Electrode and Its Electrochemical Capacitive Behavior

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Preparation of Ordered Mesoporous Carbon/NiCo₂O₄ Electrode and Its Electrochemical Capacitive Behavior