Citation: ZHAO Hui-Min, LIN Dan, YANG Gang, CHUN Yuan, XU Qin-Hua. Adsorption Capacity of Carbon Dioxide on Amine Modified Mesoporous Materials with Larger Pore Sizes[J]. Acta Physico-Chimica Sinica, ;2012, 28(04): 985-992. doi: 10.3866/PKU.WHXB201202071 shu

Adsorption Capacity of Carbon Dioxide on Amine Modified Mesoporous Materials with Larger Pore Sizes

1.
Key Laboratory of Mesoscopic Chemistry of the Ministry of Education, School of Chemistry & Chemical Engineering, Nanjing University, Nanjing 210093, P. R. China

Received Date: 1 September 2011
Available Online: 7 February 2012
Fund Project: 国家高技术研究发展计划项目(863) (2008AA06Z327) (863) (2008AA06Z327) 中央高校基础研究基金(1116020503) (1116020503)南京大学开放测试基金(0205001330)资助 (0205001330)

Mesoporous silica SBA-15-like materials with large pores were synthesized using tri-block copolymer P123 as a structure-directing agent, tetramethoxysilane as the silicon source, and different organic solvents as swelling agents. The resulting materials were characterized by powder X-ray diffraction (XRD), N₂ adsorption-desorption, scanning electron microscopy (SEM), and Fourier transform infrared (FTIR) spectroscopy. The results showed that the introduction of swelling agents effectively enlarged the pore diameter and pore volume of the SBA-15 materials, and pore swelling with isooctane was larger than that with CCl4. When modified with tetraethylenepentamine (TEPA), all of these composite materials exhibited excellent adsorption capacities for CO₂. The adsorption capacity of CO₂ was independent of the pore structure, if the template was removed before modification with TEPA. By contrast, the adsorption capacity increased with the pore diameter when the as-synthesized mesoporous material was modified with TEPA. The effects of temperature and pressure on the CO₂ adsorption capacity were investigated using adsorption isotherms and CO₂ temperature-programmed desorption (TPD). With CO₂ adsorption at higher temperature, the composite materials showed different adsorption capacities with pressure variation. As a result, the adsorption and separation of CO₂ on these TEPA modified mesoporous materials in ambient air flow can be realized via pressure swing adsorption.
- Swelling agent,
- Mesoporous materials,
- CO₂,
- Pressure swing adsorption,
- Template,
- Tetraethylenepentamine
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沈阳化工大学材料科学与工程学院沈阳 110142