Citation: DOU Xi-Hua, ZHAO Wei-Ren, SONG En-Hai, MIN Hua-Chu. Optical Properties and Energy Transfer of Sr_1-x-yMgP₂O₇:xCe³⁺,yTb³⁺ Phosphor under Ultraviolet Excitation[J]. Acta Physico-Chimica Sinica, ;2012, 28(03): 699-705. doi: 10.3866/PKU.WHXB201201121 shu

Optical Properties and Energy Transfer of Sr_1-x-yMgP₂O₇:xCe³⁺,yTb³⁺ Phosphor under Ultraviolet Excitation

1.
1. School of Physics & Optoelectronic Engineering, Guangdong University of Technology, Guangzhou 510006, P. R. China;
2. Dongguan Xinguangyuan Electronics Co. Ltd., Dongguan 523500, Guangdong Province, P. R. China

Received Date: 8 September 2011
Available Online: 12 January 2012
Fund Project: 广东省教育部产学研结合项目(2010B090400021)资助 (2010B090400021)

Sr_1-x-yMgP₂O₇:xCe³⁺,yTb³⁺ phosphors were successfully synthesized by a solid-state reaction method. The crystal structure, optical properties, luminescence decay, energy transfer, and thermal stability properties were investigated. The results showed that the emission peaks of the co-doped Ce³⁺ and Tb³⁺ ions in the SrMgP₂O₇ host were located at 398 and 545 nm, respectively. The peaks were attributed to 5d-4f and ⁵D₄→⁷F₅ transitions, respectively. An efficient energy transfer from the Ce³⁺ to Tb³⁺ ions by means of dipole-dipole interactions was observed and the critical distance of the energy transfer was 0.614 nm. The thermal activation energies of 0.122 and 0.111 eV for SrMgP₂O₇:Ce³⁺ and SrMgP₂O₇:Tb³⁺, respectively, were obtained from the temperature dependent (313-453 K) luminescence intensities. The Tb³⁺ ion was found to be superior to Ce³⁺ ion in the thermal stability of light-emitting diodes.
- Optical property,
- Luminescence decay,
- Energy transfer,
- Thermal stability
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Optical Properties and Energy Transfer of Sr1-x-yMgP2O7:xCe3+,yTb3+ Phosphor under Ultraviolet Excitation

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Optical Properties and Energy Transfer of Sr_1-x-yMgP₂O₇:xCe³⁺,yTb³⁺ Phosphor under Ultraviolet Excitation