Citation: CHEN Zhan. Molecular Structures of Buried Polymer Interfaces and Biological Interfaces Detected by Sum Frequency Generation Vibrational Spectroscopy[J]. Acta Physico-Chimica Sinica, ;2012, 28(03): 504-521. doi: 10.3866/PKU.WHXB201201091 shu

Molecular Structures of Buried Polymer Interfaces and Biological Interfaces Detected by Sum Frequency Generation Vibrational Spectroscopy

CHEN Zhan

1.
Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, MI 48109, USA

Received Date: 14 November 2011
Available Online: 9 January 2012

Molecular structures at interfaces determine interfacial properties. In order to optimize the interfacial structures to achieve improved properties of advanced materials, it is important to characterize molecular structures of interfaces in situ in real time. Recently, a nonlinear optical spectroscopic technique, sum frequency generation (SFG) vibrational spectroscopy, has been developed into a powerful and unique tool to elucidate molecular structures of buried interfaces, including liquid/liquid, solid/liquid, and solid/solid interfaces. In this review, applications of SFG to study molecular structures of complex interfaces such as polymer interfaces and biological interfaces have been discussed. Particularly, molecular surface structural changes of various polymers in water, molecular interactions between polymers and silane model adhesion promoters at interfaces, and structures of buried polymer/polymer as well as polymer/metal interfaces have been presented. In addition, interfacial structures of peptides with varied secondary structures and several representative proteins have been introduced. Interfaces play important roles in many disciplines ranging from chemistry, biology, physics, materials science and engineering, to nanotechnology. The development of a unique technique which can probe molecular structures of complex interfaces in situ greatly impacts the research in these disciplines as well as many interdisciplinary studies.
- Polymer surface and interface,
- Biological interface,
- Peptide,
- Protein,
- Adhesion,
- Secondary structure,
- Alpha-helix,
- Beta-sheet
1. [1]
  (1) Woodruff, D.; Delchar, T. Modern Techniques of Surface Science; Cambridge Univ. Press: Cambridge, 1986.
2. [2]
  (2) Somorjai, G. A. Introduction to Surface Chemistry and Catalysis;Wiley: New York, 1994.
3. [3]
  (3) Shen, Y. R. The Principles of Nonlinear Optics;Wiley: New York, 1984.
4. [4]
  (4) Chen, Z.; Shen, Y. R.; Somorjai, G. A. Ann. Rev. Phys. Chem. 2002, 53, 437.
5. [5]
  (5) Chen, C. Y.; Liu,W. T.; Pagliusi, P.; Shen, Y. R. Macromolecules 2009, 42, 2122.
6. [6]
  (6) Rao, Y.; Comstock, M.; Eisenthal, K. B. J. Phys. Chem. B 2006, 110, 1727.
7. [7]
  (7) Moore, F. G.; Richmond, G. L. Accounts Chem. Res. 2008, 41, 739.
8. [8]
  (8) Chen, Z.; Gracias, D. H.; Somorjai, G. A. Appl. Phys. B 1999, 68, 549.
9. [9]
  (9) Gracias, D. H.; Chen, Z.; Shen, Y. R.; Somorjai, G. A. Accounts Chem. Res. 1999, 320, 930.
10. [10]
  (10) Shultz, M. J.; Schnitzer, C.; Simonelli, D.; Baldelli, S. Int. Rev. Phys. Chem. 2000, 19, 123.
11. [11]
  (11) palakrishnan, D.; Liu, D. F.; Allen, H. C.; Kuo, M.; Shultz, M. J. Chem. Rev. 2006, 106, 1155.
12. [12]
  (12) Kim, J.; Cremer, P. S. J. Am. Chem. Soc. 2000, 122, 12371.
13. [13]
  (13) Briggman, K. A.; Stephenson, J. C.;Wallace,W. E.; Richter, L. J. J. Phys. Chem. B 2001, 105, 2785.
14. [14]
  (14) Gautam, K. S.; Schwab, A. D.; Dhinojwala, A.; Zhang, D.; Dougai, S. M.; Yeganeh, M. S. Phys. Rev. Lett. 2000, 85, 3854.
15. [15]
  (15) Baldelli, S. J. Phys. Chem. B 2003, 107, 6148.
16. [16]
  (16) Xu, M.; Spinney, R.; Allen, H. C. J. Phys. Chem. B 2009, 113, 4102.
17. [17]
  (17) Liu, J.; Conboy, J. C. J. Am. Chem. Soc. 2004, 126, 8894.
18. [18]
  (18) Ye, H. K.; Gu, Z. Y.; Gracias, D. H. Langmuir 2006, 22, 1863.
19. [19]
  (19) Jayathilake, H. D.; Zhu, M. H.; Rosenblatt, C.; Bordenyuk, A. N.;Weeraman, C.; Benderskii, A. V. J. Chem. Phys. 2006, 125, 064706.
20. [20]
  (20) Stokes, G. Y.; Buchbinder, A. M.; Gibbs-Davis, J. M.; Scheidt, K. M.; Geiger, F. M. J. Phys. Chem. A 2008, 112, 11688.
21. [21]
  (21) Esenturk, O.;Walker, R. A. Chem. Phys. 2006, 125, 174701.
22. [22]
  (22) Perry, A.; Neipert, C.; Space, B.; Moore, P. B. Chem. Rev. 2006, 106, 1234.
23. [23]
  (23) Li, Q. F.; Hua, R.; Cheah, I. J.; Chou, K. C. J. Phys. Chem. B 2008, 112, 694.
24. [24]
  (24) Li, Q. F.; Hua, R.; Chou, K. C. J. Phys. Chem. B 2008, 112, 2315.
25. [25]
  (25) McGall, S. J.; Davies, P. B.; Neivandt, D. J. J. Phys. Chem. A 2005, 109, 8745.
26. [26]
  (26) Chen, P.; Kung, K. Y.; Shen, Y. R.; Somorjai, G. A. Surf. Sci. 2001, 494, 289.
27. [27]
  (27) Chen, Z. Poly. Inter. 2006, 56, 577.
28. [28]
  (28) Chen, X.; Chen, Z. Biochim. Biophys. Acta 2006, 1758, 1257.
29. [29]
  (29) Ye, S.; Nguyen, K.; Le Clair, S. V.; Chen, Z. J. Struct. Biol. 2009, 168, 61.
30. [30]
  (30) Le Clair, S. V.; Nguyen, K.; Chen, Z. J. Adhesion 2009, 85, 484.
31. [31]
  (31) Chen, Z. Prog. Polym. Sci 2010, 35, 1376.
32. [32]
  (32) Wang, J.;Woodcock, S. E.; Buck, S. M.; Chen, C.; Chen, Z. J. Am. Chem. Soc. 2001, 123, 9470.
33. [33]
  (33) Wang, J.; Chen, C.; Buck, S. M.; Chen, Z. J. Phys. Chem. B 2001, 105, 12118.
34. [34]
  (34) Ratner, B. D.; Castner, D. G. Surface Modification of Polymeric Biomaterials; Plenum Press: New York, 1996.
35. [35]
  (35) Krishnan, S.;Weinman, C. J.; Ober, C. K. J. Mater. Chem. 2008, 18, 3405.
36. [36]
  (36) Yebra, D. M.; Kiil, S.; Dam-Johansen, K. Prog. Org. Coat. 2004, 50, 75.
37. [37]
  (37) Yoda, R. J. Biomater. Sci. -Polym. Ed. 1998, 9, 561.
38. [38]
  (38) Chambers, L. D.; Stokes, K. R.;Walsh, F. C.;Wood, R. J. K. Surf. Coat. Technol. 2006, 201, 3642.
39. [39]
  (39) Hron, P. Polym. Inter. 2003, 52, 1531.
40. [40]
  (40) Ruckenstein, E.; urisankar, S. V. J. Colloid Interface Sci. 1986, 109, 557.
41. [41]
  (41) Yasuda, H.; Charlson, E. J.; Charlson, E. M.; Yasuda, T.; Miyama, M.; Okuno, T. Langmuir 1991, 7, 2394.
42. [42]
  (42) Yasuda, T.; Okuno, T.; Yasuda, H. Langmuir 1994, 10, 2435.
43. [43]
  (43) Hogt, A. H.; Gre nis, D. E.; Andrade, J. D.; Kim, S.W.; Dankert, J.; Feijen, J. J. Colloid Interface Sci. 1985, 106, 289.
44. [44]
  (44) Lewis, K. B.; Ratner, B. D. J. Colloid Interface Sci. 1993, 159, 77.
45. [45]
  (45) Zhang, D.;Ward, R. S.; Shen, Y. R.; Somorjai, G. A. J. Phys. Chem. B 1997, 101, 9060.
46. [46]
  (46) Wang, J.; Paszti, Z.; Even, M. A.; Chen, Z. J. Am. Chem. Soc. 2002, 124, 7016.
47. [47]
  (47) Chen, C. Y.; Clarke, M. L.;Wang, J.; Chen, Z. Phys. Chem. Chem. Phys. 2005, 7, 2357.
48. [48]
  (48) Clarke, M. L.; Chen, C.;Wang, J.; Chen, Z. Langmuir 2006, 22, 8800.
49. [49]
  (49) Lu, X.; Clarke, M. L.; Li, D.;Wang, X.; Xue, G.; Chen, Z. J. Phys. Chem. C 2011, 115, 13759.
50. [50]
  (50) Woodcock, S. E.; Chen, C.; Chen, Z. Langmuir 2004, 20, 1928.
51. [51]
  (51) Kristalyn, C. B.; Lu, X.;Weinman, C. J.; Ober, C. K.; Kramer, E. J.; Chen, Z. Langmuir 2010, 26, 11337.
52. [52]
  (52) Chen, C.;Wang, J.; Chen, Z. Langmuir 2004, 20, 10186.
53. [53]
  (53) Ye, S.; Majumdar, P.; Chisholm, B.; Stafslien, S.; Chen, Z. Langmuir 2010, 26, 16455.
54. [54]
  (54) Chen, S. F.; Li, L. Y.; Zhao, C.; Zheng, J. Polymer 2010, 51, 5283.
55. [55]
  (55) Jiang, S.; Cao, Z. Q. Adv. Mater. 2010, 22, 920.
56. [56]
  (56) Zhang, Z.; Finlay, J. A.;Wang, L. F.; Gao, Y.; Callow, J. A.; Callow, M. E.; Jiang, S. Langmuir 2009, 25, 13516.
57. [57]
  (57) Shi, Q.; Ye, S.; Spanninga, S. A.; Su, Y.; Jiang, Z.; Chen, Z. Soft Matter 2009, 5, 3487.
58. [58]
  (58) Chen, C.; Loch, C. L.;Wang, J.; Chen, Z. J. Phys. Chem. B 2003, 107, 10440.
59. [59]
  (59) Chen, C.;Wang, J.; Loch, C. L.; Ahn, D.; Chen, Z. J. Am. Chem. Soc. 2004, 126, 1174.
60. [60]
  (60) Loch, C. L.; Ahn, D.; Vázquez, A. V.; Chen, Z. J. Colloid Interface Sci. 2007, 308, 170.
61. [61]
  (61) Loch, C. L.; Ahn, D.;Wang, J.; Chen, C.; Chen, Z. Langmuir 2004, 20, 5467.
62. [62]
  (62) Loch, C. L.; Ahn, D.; Chen, C.; Chen, Z. J. Adhesion 2005, 81, 319.
63. [63]
  (63) Loch, C. L.; Ahn, D.; Chen, Z. J. Phys. Chem. B 2006, 110, 914.
64. [64]
  (64) Vázquez, A. V.; Shephard, N. E.; Steinecker, C. L.; Ahn, D.; Spanninga, S.; Chen, Z. J. Colloid Interface Sci. 2009, 331, 408.
65. [65]
  (65) Mine, K.; Nishio, M.; Sumimura, S. US Patent 4,033,924, 1977-07-05.
66. [66]
  (66) Schulz, J. B. US Patent 4,087,585, 1978-05-02.
67. [67]
  (67) Chen, C.;Wang, J.; Even, M. A.; Chen, Z. Macromolecules 2002, 35, 8093.
68. [68]
  (68) Lu, X.; Shephard, N.; Han, J.; Xue, G.; Chen, Z. Macromolecules 2008, 41, 8770.
69. [69]
  (69) Lu, X.; Li, D.; Kristalyn, C. B.; Han, J.; Shephard, N.; Rhodes, S.; Xue, G.; Chen, Z. Macromolecules 2009, 42, 9052.
70. [70]
  (70) Harp, G. P.; Rangwalla, H.; Li, G.; Yeganeh, M. S.; Dhinojwala, A. Macromolecules 2006, 39, 7464.
71. [71]
  (71) Li, G.; Dhinojwala, A.; Yeganeh, M. S. J. Phys. Chem. B 2009, 113, 2739.
72. [72]
  (72) Yurdumakan, B.; Nanjundiah, K.; Dhinojwala, A. J. Phys. Chem. C 2007, 111, 960.
73. [73]
  (73) Wilson, P. T.; Briggman, K. A.;Wallace,W. E.; Stephenson, J. C.; Richter, L. J. Appl. Phys. Lett. 2002, 80, 3084.
74. [74]
  (74) Kweskin, S. J.; Komvopoulos, K.; Somorjai, G. A. Langmuir 2005, 21, 3647.
75. [75]
  (75) Morita, S.; Ye, S.; Li, G.; Osawa, M. Vib. Spectr. 2004, 35, 15.
76. [76]
  (76) Ye, S.; Morita, S.; Li, G.; Noda, H.; Tanaka, M.; Uosaki, K.; Osawa, M. Macromolecules 2003, 36, 5694.
77. [77]
  (77) Kweskin, S. J.; Komvopoulos, K.; Somorjai, G. A. Appl. Phys. Lett. 2006, 88, 134105.
78. [78]
  (78) Chen, Z.;Ward, R.; Tian, Y.; Malizia, F.; Gracias, D. H.; Shen, Y. R.; Somorjai, G. A. J. Biomed. Mater. Res. 2002, 62, 254.
79. [79]
  (79) Mermut, O.; Phillips, D. C.; York, R. L.; McCrea, K. R.;Ward, R. S.; Somorjai, G. A. J. Am. Chem. Soc. 2006, 128, 3598.
80. [80]
  (80) Phillips, D. C.; York, R. L.; Mermut, O.; McCrea, K. R.;Ward, R. S.; Somorjai, G. A. J. Phys. Chem. C 2007, 111, 255.
81. [81]
  (81) York, R. L.; Browne,W. K.; Geissler, P. L.; Somorjai, G. A. Isr. J. Chem. 2007, 47, 51.
82. [82]
  (82) Weidner, T.; Apte, J. S.; Gamble, L. J.; Castner, D. G. Langmuir 2010, 26, 3433.
83. [83]
  (83) Weidner, T.; Breen, N. F.; Li, K.; Drohny, G. P.; Castner, D. G. Proc. Natl. Acad. Sci. U. S. A. 2010, 107, 13288.
84. [84]
  (84) Fu, L.; Ma, G.; Yan, E. C. J. Am. Chem. Soc. 2010, 132, 5405.
85. [85]
  (85) Jung, S.,Y.; Lim, S. M.; Albertorio, F.; Kim, G.; Gurau, M. C.; Yang, R. D.; Holden, M. A.; Cremer, P. S. J. Am. Chem. Soc. 2003, 125, 12782.
86. [86]
  (86) Chen, X.; Sagle, L. B.; Cremer, P. S. J. Am. Chem. Soc. 2007, 129, 15104.
87. [87]
  (87) Hall, S. A.; Jena, K. C.; Trudeau, T. G.; Hore, D. K. J. Phys. Chem. C 2011, 115, 11216.
88. [88]
  (88) Wang, J.; Buck, S. M.; Chen, Z. Analyst 2003, 128, 773.
89. [89]
  (89) Wang, J.; Buck, S. M.; Even, M. A.; Chen, Z. J. Am. Chem. Soc. 2002, 124, 13302.
90. [90]
  (90) Wang, J.; Buck, S. M.; Chen, Z. J. Phys. Chem. B 2002, 106, 11666.
91. [91]
  (91) Wang, J.; Clarke, M. L.; Zhang, Y.; Chen, X. Langmuir 2003, 19, 7862.
92. [92]
  (92) Wang, J.; Clarke, M. L.; Chen, X.; Even, M. A.; Johnson,W. C.; Chen, Z. Surf. Sci. 2005, 587, 1.
93. [93]
  (93) Chen, X.; Clarke, M. L.;Wang, J.; Chen, Z. Intern. J. Mod. Phys. B 2005, 19, 691.
94. [94]
  (94) Nguyen, K. T.; Le Clair, S. V.; Ye, S.; Chen, Z. J. Phys. Chem. B 2009, 113, 12169.
95. [95]
  (95) Nguyen, K. T.; King, J. T.; Chen, Z. J. Phys. Chem. B 2010, 114, 8291.
96. [96]
  (96) Wang, J.; Lee, S. H.; Chen, Z. J. Phys. Chem. B 2008, 112, 2281.
97. [97]
  (97) Lee, S.;Wang, J.; Krimm, S.; Chen, Z. J. Phys. Chem. A 2006, 110, 7035.
98. [98]
  (98) Chen, X.;Wang, J.; Boughton, A. P.; Kristalyn, C. B.; Chen, Z. J . Am. Chem. Soc. 2007, 129, 1420.
99. [99]
  (99) Wang, J.; Chen, X.; Clarke, M. L.; Chen, Z. Proc. Natl. Acad. Sci. U. S. A. 2005, 102, 4978.
100. [100]
  (100) Krimm, S.; Bandekar, J. Adv. Protein Chem. 1986, 38, 181.
101. [101]
  (101) Barth, A.; Zscherp, C. Q. Rev. Biophys. 2002, 35, 369.
102. [102]
  (102) Tamm, L. K.; Tatulian, S. A. Q. Rev. Biophys. 1997, 30,365.
103. [103]
  (103) Wang, J.; Even, M. A.; Chen, X.; Schmaier, A. H.;Waite, J. H.; Chen, Z. J. Am. Chem. Soc. 2003, 125, 9914
104. [104]
  (104) Chen, X.;Wang, J.; Sniadecki, J. J.; Even, M. A.; Chen, Z. Langmuir 2005, 21, 2662
105. [105]
  (105) Lad, M. D.; Birembaut, F.; Clifton, L. A.; Frazier, R. A.; Webster, J. R. P.; Green, R. J. Biophys. J. 2007, 92, 3575.
106. [106]
  (106) Ludtke, S.; He, K.; Heller,W.; Harroun, T.; Yang, L.; Huang, H. Biochemistry 1996, 35, 13723.
107. [107]
  (107) Chen, F. Y.; Lee, M. T.; Huang, H.W. Biophys. J. 2003, 84, 3751.
108. [108]
  (108) Ludtke, S.; He, K.; Huang, H. Biochemistry 1995, 35, 16764.
109. [109]
  (109) Imura, Y.; Choda, N.; Matsuzaki, K. Biophys. J. 2008, 95, 5757.
110. [110]
  (110) Boughton, A. P.; Andricioaei, I.; Chen, Z. Langmuir 2010, 26, 16031.
111. [111]
  (111) Mecke, A.; Lee, D. K.; Ramamoorthy, A.; Orr, B. G.; BanaszakHoll, M. M. Biophys. J. 2005, 89, 4043.
112. [112]
  (112) Gre ry, S. M.; Pokorny, A.; Almeida, P. F. F. Biophys. J. 2009, 96, 116.
113. [113]
  (113) Nguyen, K. T.; Le Clair, S. V.; Ye, S.; Chen, Z. J. Phys. Chem. B 2009, 113, 12358.
114. [114]
  (114) Murzyn, K.; Pasenkiewicz-Gierula, M. J. Mol. Model. 2003, 9, 217.
115. [115]
  (115) Yang, P.; Ramamoorthy, A.; Chen, Z. Langmuir 2011, 27, 7760.
116. [116]
  (116) Hallock, K. J.; Lee, D.; Ramamoorthy, A. Biophys. J. 2003, 84, 3052.
117. [117]
  (117) Dempsey, C. E. Biochim. Biophys. Acta 1990, 1031, 143.
118. [118]
  (118) Wang, J.; Paszti, Z.; Clarke, M. L.; Chen, X.; Chen, Z. J. Phys. Chem. B 2007, 111, 6088.
119. [119]
  (119) Nguyen, K.; Soong,T.; Im, S.;Waskell, L.; Ramamoorthy, A.; Chen, Z. J. Am. Chem. Soc., 2010, 132, 15112.
120. [120]
  (120) Renthal, R. Cell Mol. Life Sci. 2010, 67, 1077.
121. [121]
  (121) Colombo, S. F.; Longhi, R.; Borgese, N. J. Cell Sci. 2009, 122, 2383.
122. [122]
  (122) Dürr, U. H. N.; Ramamoorthy, A.;Waskell, L. Biochim. Biophys. Acta 2007, 1768, 3235.
123. [123]
  (123) Neves, S. R.; Ram, P. T.; Iyengar, R. Science 2002, 296, 1636.
124. [124]
  (124) Cabrera-Vera, T. M.; Vanhauwe, J.; Thomas, T. O.; Medkova, M.; Preininger, A.; Mazzoni, M. R.; Hamm, H. E. Endocr. Rev. 2003, 24, 765.
125. [125]
  (125) Chen, X.; Boughton, A. P.; Tesmer, J. J. G.; Chen, Z. J. Am. Chem. Soc. 2007, 129, 12658.
126. [126]
  (126) Boughton, A. P.; Yang, P.; Tesmer, V. M.; Ding, B.; Tesmer, J. J. G.; Chen, Z. Proc. Natl. Acad. Sci . U. S. A. 2011, 108, E667.
127. [127]
  (127) Clarke, M. L.;Wang, J.; Chen, Z. J. Phys. Chem. B 2005, 109, 22027.
128. [128]
  (128) Wang, J.; Chen, X.; Clarke, M. L.; Chen, Z. J. Phys. Chem. B 2006, 110, 5017.
129. [129]
  (129) Ye, S.; Nguyen, K. T.; Boughton, A. P.; Mello, C. M.; Chen, Z. Langmuir 2010, 26, 6471.
130. [130]
  (130) Han, X.; Soblosky, L.; Slutsky, M.; Mello, C. M.; Chen, Z. Langmuir 2011, 27, 7042.
131. [131]
  (131) Chen, X.;Wang, J.; Paszti, Z.;Wang, F.; Schrauben, J. N.; Tarabara, V. V.; Schmaier, A. H.; Chen, Z. Anal. Bioanal. Chem. 2007, 388, 65.
132. [132]
  (132) Ye, S.; Nguyen, K. T.; Chen, Z. J. Phys. Chem. B 2010, 114, 3334.
133. [133]
  (133) Wang, J.; Clarke, M. L.; Chen, Z. Anal. Chem. 2004, 76, 2159.
134. [134]
  (134) Guyotsionnest, P.; Hunt J. H.; Shen, Y. R. Phys. Rev. Lett. 1987, 59, 1597.
135. [135]
  (135) Hunt, J. H.; Guyot-Sionnest, P.; Shen, Y. R. Chem. Phys. Lett. 1987, 133, 189.
136. [136]
  (136) Zhang, C.;Wang, J.; Khmaladze, A.; Liu, Y.; Ding, B.; Jasensky, J.; Chen, Z. Opt. Lett. 2011, 36, 2272.
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沈阳化工大学材料科学与工程学院沈阳 110142