Citation: CHEN Zhan. Molecular Structures of Buried Polymer Interfaces and Biological Interfaces Detected by Sum Frequency Generation Vibrational Spectroscopy[J]. Acta Physico-Chimica Sinica, ;2012, 28(03): 504-521. doi: 10.3866/PKU.WHXB201201091 shu

Molecular Structures of Buried Polymer Interfaces and Biological Interfaces Detected by Sum Frequency Generation Vibrational Spectroscopy

CHEN Zhan

1.
Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, MI 48109, USA

Received Date: 14 November 2011
Available Online: 9 January 2012

Molecular structures at interfaces determine interfacial properties. In order to optimize the interfacial structures to achieve improved properties of advanced materials, it is important to characterize molecular structures of interfaces in situ in real time. Recently, a nonlinear optical spectroscopic technique, sum frequency generation (SFG) vibrational spectroscopy, has been developed into a powerful and unique tool to elucidate molecular structures of buried interfaces, including liquid/liquid, solid/liquid, and solid/solid interfaces. In this review, applications of SFG to study molecular structures of complex interfaces such as polymer interfaces and biological interfaces have been discussed. Particularly, molecular surface structural changes of various polymers in water, molecular interactions between polymers and silane model adhesion promoters at interfaces, and structures of buried polymer/polymer as well as polymer/metal interfaces have been presented. In addition, interfacial structures of peptides with varied secondary structures and several representative proteins have been introduced. Interfaces play important roles in many disciplines ranging from chemistry, biology, physics, materials science and engineering, to nanotechnology. The development of a unique technique which can probe molecular structures of complex interfaces in situ greatly impacts the research in these disciplines as well as many interdisciplinary studies.
- Polymer surface and interface,
- Biological interface,
- Peptide,
- Protein,
- Adhesion,
- Secondary structure,
- Alpha-helix,
- Beta-sheet
1. [1]
  (1) Woodruff, D.; Delchar, T. Modern Techniques of Surface Science; Cambridge Univ. Press: Cambridge, 1986.
2. [2]
  (2) Somorjai, G. A. Introduction to Surface Chemistry and Catalysis;Wiley: New York, 1994.
3. [3]
  (3) Shen, Y. R. The Principles of Nonlinear Optics;Wiley: New York, 1984.
4. [4]
  (4) Chen, Z.; Shen, Y. R.; Somorjai, G. A. Ann. Rev. Phys. Chem. 2002, 53, 437.
5. [5]
  (5) Chen, C. Y.; Liu,W. T.; Pagliusi, P.; Shen, Y. R. Macromolecules 2009, 42, 2122.
6. [6]
  (6) Rao, Y.; Comstock, M.; Eisenthal, K. B. J. Phys. Chem. B 2006, 110, 1727.
7. [7]
  (7) Moore, F. G.; Richmond, G. L. Accounts Chem. Res. 2008, 41, 739.
8. [8]
  (8) Chen, Z.; Gracias, D. H.; Somorjai, G. A. Appl. Phys. B 1999, 68, 549.
9. [9]
  (9) Gracias, D. H.; Chen, Z.; Shen, Y. R.; Somorjai, G. A. Accounts Chem. Res. 1999, 320, 930.
10. [10]
  (10) Shultz, M. J.; Schnitzer, C.; Simonelli, D.; Baldelli, S. Int. Rev. Phys. Chem. 2000, 19, 123.
11. [11]
  (11) palakrishnan, D.; Liu, D. F.; Allen, H. C.; Kuo, M.; Shultz, M. J. Chem. Rev. 2006, 106, 1155.
12. [12]
  (12) Kim, J.; Cremer, P. S. J. Am. Chem. Soc. 2000, 122, 12371.
13. [13]
  (13) Briggman, K. A.; Stephenson, J. C.;Wallace,W. E.; Richter, L. J. J. Phys. Chem. B 2001, 105, 2785.
14. [14]
  (14) Gautam, K. S.; Schwab, A. D.; Dhinojwala, A.; Zhang, D.; Dougai, S. M.; Yeganeh, M. S. Phys. Rev. Lett. 2000, 85, 3854.
15. [15]
  (15) Baldelli, S. J. Phys. Chem. B 2003, 107, 6148.
16. [16]
  (16) Xu, M.; Spinney, R.; Allen, H. C. J. Phys. Chem. B 2009, 113, 4102.
17. [17]
  (17) Liu, J.; Conboy, J. C. J. Am. Chem. Soc. 2004, 126, 8894.
18. [18]
  (18) Ye, H. K.; Gu, Z. Y.; Gracias, D. H. Langmuir 2006, 22, 1863.
19. [19]
  (19) Jayathilake, H. D.; Zhu, M. H.; Rosenblatt, C.; Bordenyuk, A. N.;Weeraman, C.; Benderskii, A. V. J. Chem. Phys. 2006, 125, 064706.
20. [20]
  (20) Stokes, G. Y.; Buchbinder, A. M.; Gibbs-Davis, J. M.; Scheidt, K. M.; Geiger, F. M. J. Phys. Chem. A 2008, 112, 11688.
21. [21]
  (21) Esenturk, O.;Walker, R. A. Chem. Phys. 2006, 125, 174701.
22. [22]
  (22) Perry, A.; Neipert, C.; Space, B.; Moore, P. B. Chem. Rev. 2006, 106, 1234.
23. [23]
  (23) Li, Q. F.; Hua, R.; Cheah, I. J.; Chou, K. C. J. Phys. Chem. B 2008, 112, 694.
24. [24]
  (24) Li, Q. F.; Hua, R.; Chou, K. C. J. Phys. Chem. B 2008, 112, 2315.
25. [25]
  (25) McGall, S. J.; Davies, P. B.; Neivandt, D. J. J. Phys. Chem. A 2005, 109, 8745.
26. [26]
  (26) Chen, P.; Kung, K. Y.; Shen, Y. R.; Somorjai, G. A. Surf. Sci. 2001, 494, 289.
27. [27]
  (27) Chen, Z. Poly. Inter. 2006, 56, 577.
28. [28]
  (28) Chen, X.; Chen, Z. Biochim. Biophys. Acta 2006, 1758, 1257.
29. [29]
  (29) Ye, S.; Nguyen, K.; Le Clair, S. V.; Chen, Z. J. Struct. Biol. 2009, 168, 61.
30. [30]
  (30) Le Clair, S. V.; Nguyen, K.; Chen, Z. J. Adhesion 2009, 85, 484.
31. [31]
  (31) Chen, Z. Prog. Polym. Sci 2010, 35, 1376.
32. [32]
  (32) Wang, J.;Woodcock, S. E.; Buck, S. M.; Chen, C.; Chen, Z. J. Am. Chem. Soc. 2001, 123, 9470.
33. [33]
  (33) Wang, J.; Chen, C.; Buck, S. M.; Chen, Z. J. Phys. Chem. B 2001, 105, 12118.
34. [34]
  (34) Ratner, B. D.; Castner, D. G. Surface Modification of Polymeric Biomaterials; Plenum Press: New York, 1996.
35. [35]
  (35) Krishnan, S.;Weinman, C. J.; Ober, C. K. J. Mater. Chem. 2008, 18, 3405.
36. [36]
  (36) Yebra, D. M.; Kiil, S.; Dam-Johansen, K. Prog. Org. Coat. 2004, 50, 75.
37. [37]
  (37) Yoda, R. J. Biomater. Sci. -Polym. Ed. 1998, 9, 561.
38. [38]
  (38) Chambers, L. D.; Stokes, K. R.;Walsh, F. C.;Wood, R. J. K. Surf. Coat. Technol. 2006, 201, 3642.
39. [39]
  (39) Hron, P. Polym. Inter. 2003, 52, 1531.
40. [40]
  (40) Ruckenstein, E.; urisankar, S. V. J. Colloid Interface Sci. 1986, 109, 557.
41. [41]
  (41) Yasuda, H.; Charlson, E. J.; Charlson, E. M.; Yasuda, T.; Miyama, M.; Okuno, T. Langmuir 1991, 7, 2394.
42. [42]
  (42) Yasuda, T.; Okuno, T.; Yasuda, H. Langmuir 1994, 10, 2435.
43. [43]
  (43) Hogt, A. H.; Gre nis, D. E.; Andrade, J. D.; Kim, S.W.; Dankert, J.; Feijen, J. J. Colloid Interface Sci. 1985, 106, 289.
44. [44]
  (44) Lewis, K. B.; Ratner, B. D. J. Colloid Interface Sci. 1993, 159, 77.
45. [45]
  (45) Zhang, D.;Ward, R. S.; Shen, Y. R.; Somorjai, G. A. J. Phys. Chem. B 1997, 101, 9060.
46. [46]
  (46) Wang, J.; Paszti, Z.; Even, M. A.; Chen, Z. J. Am. Chem. Soc. 2002, 124, 7016.
47. [47]
  (47) Chen, C. Y.; Clarke, M. L.;Wang, J.; Chen, Z. Phys. Chem. Chem. Phys. 2005, 7, 2357.
48. [48]
  (48) Clarke, M. L.; Chen, C.;Wang, J.; Chen, Z. Langmuir 2006, 22, 8800.
49. [49]
  (49) Lu, X.; Clarke, M. L.; Li, D.;Wang, X.; Xue, G.; Chen, Z. J. Phys. Chem. C 2011, 115, 13759.
50. [50]
  (50) Woodcock, S. E.; Chen, C.; Chen, Z. Langmuir 2004, 20, 1928.
51. [51]
  (51) Kristalyn, C. B.; Lu, X.;Weinman, C. J.; Ober, C. K.; Kramer, E. J.; Chen, Z. Langmuir 2010, 26, 11337.
52. [52]
  (52) Chen, C.;Wang, J.; Chen, Z. Langmuir 2004, 20, 10186.
53. [53]
  (53) Ye, S.; Majumdar, P.; Chisholm, B.; Stafslien, S.; Chen, Z. Langmuir 2010, 26, 16455.
54. [54]
  (54) Chen, S. F.; Li, L. Y.; Zhao, C.; Zheng, J. Polymer 2010, 51, 5283.
55. [55]
  (55) Jiang, S.; Cao, Z. Q. Adv. Mater. 2010, 22, 920.
56. [56]
  (56) Zhang, Z.; Finlay, J. A.;Wang, L. F.; Gao, Y.; Callow, J. A.; Callow, M. E.; Jiang, S. Langmuir 2009, 25, 13516.
57. [57]
  (57) Shi, Q.; Ye, S.; Spanninga, S. A.; Su, Y.; Jiang, Z.; Chen, Z. Soft Matter 2009, 5, 3487.
58. [58]
  (58) Chen, C.; Loch, C. L.;Wang, J.; Chen, Z. J. Phys. Chem. B 2003, 107, 10440.
59. [59]
  (59) Chen, C.;Wang, J.; Loch, C. L.; Ahn, D.; Chen, Z. J. Am. Chem. Soc. 2004, 126, 1174.
60. [60]
  (60) Loch, C. L.; Ahn, D.; Vázquez, A. V.; Chen, Z. J. Colloid Interface Sci. 2007, 308, 170.
61. [61]
  (61) Loch, C. L.; Ahn, D.;Wang, J.; Chen, C.; Chen, Z. Langmuir 2004, 20, 5467.
62. [62]
  (62) Loch, C. L.; Ahn, D.; Chen, C.; Chen, Z. J. Adhesion 2005, 81, 319.
63. [63]
  (63) Loch, C. L.; Ahn, D.; Chen, Z. J. Phys. Chem. B 2006, 110, 914.
64. [64]
  (64) Vázquez, A. V.; Shephard, N. E.; Steinecker, C. L.; Ahn, D.; Spanninga, S.; Chen, Z. J. Colloid Interface Sci. 2009, 331, 408.
65. [65]
  (65) Mine, K.; Nishio, M.; Sumimura, S. US Patent 4,033,924, 1977-07-05.
66. [66]
  (66) Schulz, J. B. US Patent 4,087,585, 1978-05-02.
67. [67]
  (67) Chen, C.;Wang, J.; Even, M. A.; Chen, Z. Macromolecules 2002, 35, 8093.
68. [68]
  (68) Lu, X.; Shephard, N.; Han, J.; Xue, G.; Chen, Z. Macromolecules 2008, 41, 8770.
69. [69]
  (69) Lu, X.; Li, D.; Kristalyn, C. B.; Han, J.; Shephard, N.; Rhodes, S.; Xue, G.; Chen, Z. Macromolecules 2009, 42, 9052.
70. [70]
  (70) Harp, G. P.; Rangwalla, H.; Li, G.; Yeganeh, M. S.; Dhinojwala, A. Macromolecules 2006, 39, 7464.
71. [71]
  (71) Li, G.; Dhinojwala, A.; Yeganeh, M. S. J. Phys. Chem. B 2009, 113, 2739.
72. [72]
  (72) Yurdumakan, B.; Nanjundiah, K.; Dhinojwala, A. J. Phys. Chem. C 2007, 111, 960.
73. [73]
  (73) Wilson, P. T.; Briggman, K. A.;Wallace,W. E.; Stephenson, J. C.; Richter, L. J. Appl. Phys. Lett. 2002, 80, 3084.
74. [74]
  (74) Kweskin, S. J.; Komvopoulos, K.; Somorjai, G. A. Langmuir 2005, 21, 3647.
75. [75]
  (75) Morita, S.; Ye, S.; Li, G.; Osawa, M. Vib. Spectr. 2004, 35, 15.
76. [76]
  (76) Ye, S.; Morita, S.; Li, G.; Noda, H.; Tanaka, M.; Uosaki, K.; Osawa, M. Macromolecules 2003, 36, 5694.
77. [77]
  (77) Kweskin, S. J.; Komvopoulos, K.; Somorjai, G. A. Appl. Phys. Lett. 2006, 88, 134105.
78. [78]
  (78) Chen, Z.;Ward, R.; Tian, Y.; Malizia, F.; Gracias, D. H.; Shen, Y. R.; Somorjai, G. A. J. Biomed. Mater. Res. 2002, 62, 254.
79. [79]
  (79) Mermut, O.; Phillips, D. C.; York, R. L.; McCrea, K. R.;Ward, R. S.; Somorjai, G. A. J. Am. Chem. Soc. 2006, 128, 3598.
80. [80]
  (80) Phillips, D. C.; York, R. L.; Mermut, O.; McCrea, K. R.;Ward, R. S.; Somorjai, G. A. J. Phys. Chem. C 2007, 111, 255.
81. [81]
  (81) York, R. L.; Browne,W. K.; Geissler, P. L.; Somorjai, G. A. Isr. J. Chem. 2007, 47, 51.
82. [82]
  (82) Weidner, T.; Apte, J. S.; Gamble, L. J.; Castner, D. G. Langmuir 2010, 26, 3433.
83. [83]
  (83) Weidner, T.; Breen, N. F.; Li, K.; Drohny, G. P.; Castner, D. G. Proc. Natl. Acad. Sci. U. S. A. 2010, 107, 13288.
84. [84]
  (84) Fu, L.; Ma, G.; Yan, E. C. J. Am. Chem. Soc. 2010, 132, 5405.
85. [85]
  (85) Jung, S.,Y.; Lim, S. M.; Albertorio, F.; Kim, G.; Gurau, M. C.; Yang, R. D.; Holden, M. A.; Cremer, P. S. J. Am. Chem. Soc. 2003, 125, 12782.
86. [86]
  (86) Chen, X.; Sagle, L. B.; Cremer, P. S. J. Am. Chem. Soc. 2007, 129, 15104.
87. [87]
  (87) Hall, S. A.; Jena, K. C.; Trudeau, T. G.; Hore, D. K. J. Phys. Chem. C 2011, 115, 11216.
88. [88]
  (88) Wang, J.; Buck, S. M.; Chen, Z. Analyst 2003, 128, 773.
89. [89]
  (89) Wang, J.; Buck, S. M.; Even, M. A.; Chen, Z. J. Am. Chem. Soc. 2002, 124, 13302.
90. [90]
  (90) Wang, J.; Buck, S. M.; Chen, Z. J. Phys. Chem. B 2002, 106, 11666.
91. [91]
  (91) Wang, J.; Clarke, M. L.; Zhang, Y.; Chen, X. Langmuir 2003, 19, 7862.
92. [92]
  (92) Wang, J.; Clarke, M. L.; Chen, X.; Even, M. A.; Johnson,W. C.; Chen, Z. Surf. Sci. 2005, 587, 1.
93. [93]
  (93) Chen, X.; Clarke, M. L.;Wang, J.; Chen, Z. Intern. J. Mod. Phys. B 2005, 19, 691.
94. [94]
  (94) Nguyen, K. T.; Le Clair, S. V.; Ye, S.; Chen, Z. J. Phys. Chem. B 2009, 113, 12169.
95. [95]
  (95) Nguyen, K. T.; King, J. T.; Chen, Z. J. Phys. Chem. B 2010, 114, 8291.
96. [96]
  (96) Wang, J.; Lee, S. H.; Chen, Z. J. Phys. Chem. B 2008, 112, 2281.
97. [97]
  (97) Lee, S.;Wang, J.; Krimm, S.; Chen, Z. J. Phys. Chem. A 2006, 110, 7035.
98. [98]
  (98) Chen, X.;Wang, J.; Boughton, A. P.; Kristalyn, C. B.; Chen, Z. J . Am. Chem. Soc. 2007, 129, 1420.
99. [99]
  (99) Wang, J.; Chen, X.; Clarke, M. L.; Chen, Z. Proc. Natl. Acad. Sci. U. S. A. 2005, 102, 4978.
100. [100]
  (100) Krimm, S.; Bandekar, J. Adv. Protein Chem. 1986, 38, 181.
101. [101]
  (101) Barth, A.; Zscherp, C. Q. Rev. Biophys. 2002, 35, 369.
102. [102]
  (102) Tamm, L. K.; Tatulian, S. A. Q. Rev. Biophys. 1997, 30,365.
103. [103]
  (103) Wang, J.; Even, M. A.; Chen, X.; Schmaier, A. H.;Waite, J. H.; Chen, Z. J. Am. Chem. Soc. 2003, 125, 9914
104. [104]
  (104) Chen, X.;Wang, J.; Sniadecki, J. J.; Even, M. A.; Chen, Z. Langmuir 2005, 21, 2662
105. [105]
  (105) Lad, M. D.; Birembaut, F.; Clifton, L. A.; Frazier, R. A.; Webster, J. R. P.; Green, R. J. Biophys. J. 2007, 92, 3575.
106. [106]
  (106) Ludtke, S.; He, K.; Heller,W.; Harroun, T.; Yang, L.; Huang, H. Biochemistry 1996, 35, 13723.
107. [107]
  (107) Chen, F. Y.; Lee, M. T.; Huang, H.W. Biophys. J. 2003, 84, 3751.
108. [108]
  (108) Ludtke, S.; He, K.; Huang, H. Biochemistry 1995, 35, 16764.
109. [109]
  (109) Imura, Y.; Choda, N.; Matsuzaki, K. Biophys. J. 2008, 95, 5757.
110. [110]
  (110) Boughton, A. P.; Andricioaei, I.; Chen, Z. Langmuir 2010, 26, 16031.
111. [111]
  (111) Mecke, A.; Lee, D. K.; Ramamoorthy, A.; Orr, B. G.; BanaszakHoll, M. M. Biophys. J. 2005, 89, 4043.
112. [112]
  (112) Gre ry, S. M.; Pokorny, A.; Almeida, P. F. F. Biophys. J. 2009, 96, 116.
113. [113]
  (113) Nguyen, K. T.; Le Clair, S. V.; Ye, S.; Chen, Z. J. Phys. Chem. B 2009, 113, 12358.
114. [114]
  (114) Murzyn, K.; Pasenkiewicz-Gierula, M. J. Mol. Model. 2003, 9, 217.
115. [115]
  (115) Yang, P.; Ramamoorthy, A.; Chen, Z. Langmuir 2011, 27, 7760.
116. [116]
  (116) Hallock, K. J.; Lee, D.; Ramamoorthy, A. Biophys. J. 2003, 84, 3052.
117. [117]
  (117) Dempsey, C. E. Biochim. Biophys. Acta 1990, 1031, 143.
118. [118]
  (118) Wang, J.; Paszti, Z.; Clarke, M. L.; Chen, X.; Chen, Z. J. Phys. Chem. B 2007, 111, 6088.
119. [119]
  (119) Nguyen, K.; Soong,T.; Im, S.;Waskell, L.; Ramamoorthy, A.; Chen, Z. J. Am. Chem. Soc., 2010, 132, 15112.
120. [120]
  (120) Renthal, R. Cell Mol. Life Sci. 2010, 67, 1077.
121. [121]
  (121) Colombo, S. F.; Longhi, R.; Borgese, N. J. Cell Sci. 2009, 122, 2383.
122. [122]
  (122) Dürr, U. H. N.; Ramamoorthy, A.;Waskell, L. Biochim. Biophys. Acta 2007, 1768, 3235.
123. [123]
  (123) Neves, S. R.; Ram, P. T.; Iyengar, R. Science 2002, 296, 1636.
124. [124]
  (124) Cabrera-Vera, T. M.; Vanhauwe, J.; Thomas, T. O.; Medkova, M.; Preininger, A.; Mazzoni, M. R.; Hamm, H. E. Endocr. Rev. 2003, 24, 765.
125. [125]
  (125) Chen, X.; Boughton, A. P.; Tesmer, J. J. G.; Chen, Z. J. Am. Chem. Soc. 2007, 129, 12658.
126. [126]
  (126) Boughton, A. P.; Yang, P.; Tesmer, V. M.; Ding, B.; Tesmer, J. J. G.; Chen, Z. Proc. Natl. Acad. Sci . U. S. A. 2011, 108, E667.
127. [127]
  (127) Clarke, M. L.;Wang, J.; Chen, Z. J. Phys. Chem. B 2005, 109, 22027.
128. [128]
  (128) Wang, J.; Chen, X.; Clarke, M. L.; Chen, Z. J. Phys. Chem. B 2006, 110, 5017.
129. [129]
  (129) Ye, S.; Nguyen, K. T.; Boughton, A. P.; Mello, C. M.; Chen, Z. Langmuir 2010, 26, 6471.
130. [130]
  (130) Han, X.; Soblosky, L.; Slutsky, M.; Mello, C. M.; Chen, Z. Langmuir 2011, 27, 7042.
131. [131]
  (131) Chen, X.;Wang, J.; Paszti, Z.;Wang, F.; Schrauben, J. N.; Tarabara, V. V.; Schmaier, A. H.; Chen, Z. Anal. Bioanal. Chem. 2007, 388, 65.
132. [132]
  (132) Ye, S.; Nguyen, K. T.; Chen, Z. J. Phys. Chem. B 2010, 114, 3334.
133. [133]
  (133) Wang, J.; Clarke, M. L.; Chen, Z. Anal. Chem. 2004, 76, 2159.
134. [134]
  (134) Guyotsionnest, P.; Hunt J. H.; Shen, Y. R. Phys. Rev. Lett. 1987, 59, 1597.
135. [135]
  (135) Hunt, J. H.; Guyot-Sionnest, P.; Shen, Y. R. Chem. Phys. Lett. 1987, 133, 189.
136. [136]
  (136) Zhang, C.;Wang, J.; Khmaladze, A.; Liu, Y.; Ding, B.; Jasensky, J.; Chen, Z. Opt. Lett. 2011, 36, 2272.
1. [1]
  Xinyi Hong , Tailing Xue , Zhou Xu , Enrong Xie , Mingkai Wu , Qingqing Wang , Lina Wu . Non-Site-Specific Fluorescent Labeling of Proteins as a Chemical Biology Experiment. University Chemistry, 2024, 39(4): 351-360. doi: 10.3866/PKU.DXHX202310010
2. [2]
  Qi Wang , Yicong Gao , Feng Lu , Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141
3. [3]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
4. [4]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
5. [5]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
6. [6]
  Laiying Zhang , Yinghuan Wu , Yazi Yu , Yecheng Xu , Haojie Zhang , Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126
7. [7]
  Yanhui Sun , Junmin Nan , Guozheng Ma , Xiaoxi Zuo , Guoliang Li , Xiaoming Lin . Exploration and Teaching Practice of Ideological and Political Elements in Interface Physical Chemistry: Taking “Additional Pressure on Curved Surfaces” as an Teaching Example. University Chemistry, 2024, 39(11): 20-27. doi: 10.3866/PKU.DXHX202402023
8. [8]
  Wenbing Hu , Jin Zhu . Flipped Classroom Approach in Teaching Professional English Reading and Writing to Polymer Graduates. University Chemistry, 2024, 39(6): 128-131. doi: 10.3866/PKU.DXHX202310015
9. [9]
  Kai Yang , Gehua Bi , Yong Zhang , Delin Jin , Ziwei Xu , Qian Wang , Lingbao Xing . Comprehensive Polymer Chemistry Experiment Design: Preparation and Characterization of Rigid Polyurethane Foam Materials. University Chemistry, 2024, 39(4): 206-212. doi: 10.3866/PKU.DXHX202308045
10. [10]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
11. [11]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Ideological and Political Design of Solid-liquid Contact Angle Measurement Experiment. University Chemistry, 2024, 39(2): 28-33. doi: 10.3866/PKU.DXHX202306065
12. [12]
  Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021
13. [13]
  Lijun Huo , Mingcun Wang , Tianyi Zhao , Mingjie Liu . Exploration of Undergraduate and Graduate Integrated Teaching in Polymer Chemistry with Aerospace Characteristics. University Chemistry, 2024, 39(6): 103-111. doi: 10.3866/PKU.DXHX202312059
14. [14]
  Feng Zheng , Ruxun Yuan , Xiaogang Wang . “Research-Oriented” Comprehensive Experimental Design in Polymer Chemistry: the Case of Polyimide Aerogels. University Chemistry, 2024, 39(10): 210-218. doi: 10.12461/PKU.DXHX202404027
15. [15]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
16. [16]
  Pingping Zhu , Yongjun Xie , Yuanping Yi , Yu Huang , Qiang Zhou , Shiyan Xiao , Haiyang Yang , Pingsheng He . Excavation and Extraction of Ideological and Political Elements for the Virtual Simulation Experiments at Molecular Level: Taking the Project “the Simulation and Computation of Conformation, Morphology and Dimensions of Polymer Chains” as an Example. University Chemistry, 2024, 39(2): 83-88. doi: 10.3866/PKU.DXHX202309063
17. [17]
  Xuan Zhou , Yi Fan , Zhuoqi Jiang , Zhipeng Li , Guowen Yuan , Laiying Zhang , Xu Hou . Liquid Gating Mechanism and Basic Properties Characterization: a New Experimental Design for Interface and Surface Properties in the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 113-120. doi: 10.12461/PKU.DXHX202407111
18. [18]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
19. [19]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
20. [20]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357

Get Citation

PDF

XML

Metrics

PDF Downloads(986)
Abstract views(2709)
HTML views(55)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142