Citation: ZHOU Ai-Jun, CUI Heng-Guan, LI Jing-Ze, ZHAO Xin-Bing. Structure and Morphology of Induction-Melted Higher Manganese Silicide[J]. Acta Physico-Chimica Sinica, ;2011, 27(12): 2915-2919. doi: 10.3866/PKU.WHXB20112915 shu

Structure and Morphology of Induction-Melted Higher Manganese Silicide

1.
1. State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China,Chengdu 610054, P. R. China;
2. State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027, P. R. China

Received Date: 1 July 2011
Available Online: 23 September 2011
Fund Project: 国家自然科学基金(51102039) (51102039) 中央高校基本科研业务费(ZYGX2010J033) (ZYGX2010J033)中国博士后科学基金(20100481375, 201104640)资助项目 (20100481375, 201104640)

Field emission scanning microscopy (FESEM) and energy-dispersive X-ray spectroscopy (EDXS) were used to study the morphology and composition of secondary phase precipitations in induction-melted higher manganese silicide (HMS). Striations of the secondary phase were observed in individual HMS crystals with an average interval of 5-30 μm and a thickness of ~30 nm. The chemical composition of the striations was examined and found to be MnSi, which was observed as an amorphous phase by high resolution transmission electron microscopy (HRTEM). The crystal structure of HMS was determined by selective area electron diffraction (SAED) and the results indicated a single Mn₄Si₇ phase in the as-prepared material and no other incommensurate HMS phases were found. After ball milling and hot pressing many defects and stress fields were observed in the HMS by transmission electron microscope (TEM), which differentiated substantially from the morphology of the as-melted HMS.
- Higher manganese silicide,
- MnSi precipitation,
- Amorphous,
- Crystal structure,
- defect
1. [1]
  (1) Luo,W.H.; Li, H.; Yan, Y.G.; Lin, Z.B.; Tang, X.F.; Zhang, Q.J.; Uher, C. Intermetallics 2011, 19, 404.
2. [2]
  (2) Zhou, A. J.; Zhu, T. J.; Zhao, X. B.; Yang, S. H.; Dasgupta, T.; Stiewe, C.; Hassdorf, R.; Mueller, E. J. Electron. Mater. 2010, 39, 2002.
3. [3]
  (3) Kaga, H.; Kinemuchi, Y.;Watari, K.; Tanaka, S.; Makiya, A.; Kato, Z.; Uematsu, K. J. Mater. Res. 2007, 22, 2917.
4. [4]
  (4) Fedorov, M. I.; Zaitsev, V. K. Thermoelectric Porperties of Transition Metal Silicides. In Thermoelectrics Handbook; Rowe, D. M. Ed.; CRC Press: New York, 2005; p 31.
5. [5]
  (5) Zaitsev, V. K.; Ordin, S. V.; Rakhimov, K. A.; Engalychev, A. E. Sov. Phys. Solid State 1981, 23, 353.
6. [6]
  (6) Nowotny, H. Crystal Chemistry of Transition Element Defect Silicides and Related Compounds. In The Chemistry of Extended Defects in Non-Metallic Solids; Eyring, L. R.; O'Keefe, M. Eds.; North-Holland: Amsterdam, 1970; pp 223-237.
7. [7]
  (7) Kapinski, O. G.; Evseev, B. A. Izvestiya AN SSSR (Neorganicheskie Materialy) 1969, 5, 525.
8. [8]
  (8) Schwomma, O.; Presinger, A.; Nowotny, H.;Wittman, A. Monatsh. Chem. 1964, 95, 1527.
9. [9]
  (9) Knott, H.W.; Mueller, M. H.; Heaton, L. Acta Cryst. 1967, 23, 549.
10. [10]
  (10) Zwilling, G.; Nowotny, H. Monatsh.Chem. 1971, 102, 672.
11. [11]
  (11) Kawasumi, I.; Sakata, M.; Nishida, I.; Masumoto, K. J. Cryst. Growth 1980, 49, 651.
12. [12]
  (12) Kojima, T.; Nishida, I.; Sakata, M. J. Cryst. Growth 1979, 47, 589.
13. [13]
  (13) Kawasumi, I.; Sakata, M.; Nishida, I.; Masumoto, K. J. Mater. Sci. 1981, 16, 355.
14. [14]
  (14) Nishida, I.; Masumoto, K.; Kawasumi, I.; Sakata, M. J. Less-Common Metals 1980, 71, 293.
15. [15]
  (15) Aoyama, I.; Fedorov, M. I.; Zaitsev, V.K.; Solomkin, F. Y.; Eremin, I. S.; Samunin, A. Y.; Mukoujima, M.; Sano, S.; Tsuji, T. Jpn. J. Appl. Phys. 2005, 44, 8562.
16. [16]
  (16) De Ridder, R.; Van Tendeloo, G.; Amelinckx, S. Phys. Status Solidi. -A 1976, 30, K99.
1. [1]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
2. [2]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
3. [3]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
4. [4]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
5. [5]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
6. [6]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
7. [7]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
8. [8]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
9. [9]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
10. [10]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
11. [11]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
12. [12]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
13. [13]
  Dongju Zhang . Exploring the Descriptions and Connotations of Basic Concepts of Teaching Crystal Structures. University Chemistry, 2024, 39(3): 18-22. doi: 10.3866/PKU.DXHX202304003
14. [14]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035
15. [15]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
16. [16]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
17. [17]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
18. [18]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
19. [19]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
20. [20]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489

Get Citation

PDF

XML

Metrics

PDF Downloads(840)
Abstract views(2937)
HTML views(138)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142