Citation: OUYANG Jing, SONG Xing-Lin, LIN Ming-Yue, ZOU Ju, LI Jing-Jing, ZHU Jiang-Ping, YANG Hua-Ming. Effect of Oxygen Vacancy on the Optical Properties of Porous Zirconia[J]. Acta Physico-Chimica Sinica, ;2011, 27(12): 2900-2906. doi: 10.3866/PKU.WHXB20112900 shu

Effect of Oxygen Vacancy on the Optical Properties of Porous Zirconia

1.
Department of Inorganic Materials, School of Minerals Processing & Bioengineering,Central South University, Changsha 410083, P. R. China

Received Date: 15 July 2011
Available Online: 20 October 2011
Fund Project: 国家自然科学基金(50774095) (50774095) 中央高校基本科研业务费-中南大学自由探索计划(2011QNZT075) (2011QNZT075)大学生创新性实验计划(LE10246)资助项目 (LE10246)

The effect of oxygen vacancy on the optical properties of porous zirconia (ZrO₂) was discussed based on the preparation and optical characterization of this material. The configuration coordinate diagram for a discussion of the optical performances of the ZrO₂ system was carefully amended. The samples used in the experiments were prepared by the hydrothermal method. The product possesses a porous structure constructed by amorphous zirconia particles and the specific surface area of the product was 151.9 m²·g^-1. Deconvolution was used to analyze the photoluminescence (PL) spectra and the results are different in some aspects compared with previous reports. The main PL bands of the as-prepared product were located in the violet to blue region while those of the samples after treatment by H₃PO₄ red-shifted to the blue-green region. Neither the porous structure nor the existence of phosphor reagents in ZrO₂ induced any new PL peaks. The oxygen vacancies in the samples formed a new energy level that trapped electrons to form a color center and then luminescent emissions were induced.
- Porous zirconia,
- Optical property,
- Configuration-coordinate,
- Oxygen vacancy
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