Citation: PAN Rui-Li, FAN Wei-Bin, LI Yu-Ping, LI Xiao-Feng, LI Sha, DOU Tao. Synthesis, Characterization of SSZ-33 Molecular Sieves and Their Performance for the Automobile Tailpipe Hydrocarbon Trap[J]. Acta Physico-Chimica Sinica, ;2011, 27(12): 2893-2899. doi: 10.3866/PKU.WHXB20112893 shu

Synthesis, Characterization of SSZ-33 Molecular Sieves and Their Performance for the Automobile Tailpipe Hydrocarbon Trap

PAN Rui-Li ^1,2 ,
FAN Wei-Bin ³ ,
LI Yu-Ping ⁴ ,
LI Xiao-Feng ¹ ,
LI Sha ¹ ,
DOU Tao ^1,5,

1.
1. Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, P. R. China;
2. Institute of Chemicaland Biological Technology, Taiyuan University of Science and Technology, Taiyuan 030021, P. R. China;
3. Institute of CoalChemistry, Chinese Academy of Sciences, Taiyuan 030001, P. R. China;
4. College of Materials Science and Engineering, TaiyuanUniversity of Technology, Taiyuan 030024, P. R. China;
5. CNPC Key Laboratory of Catalysis, College of Chemical Engineering,China University of Petroleum-Beijing, Beijing 102249, P. R. China

Received Date: 23 May 2011
Available Online: 19 September 2011
Fund Project: 国家自然科学基金(20973123)资助项目 (20973123)

Using N,N,N-trimethyl-8-ammonium tricyclo [5.2.1.0^2,6] decane iodide as a structure directing agent, B-SSZ-33 molecular sieves with an excellent price-performance ratio was successfully synthesized by process control over 3-4 days. The synthesis of Al-SSZ-33 was achieved by a post-modification procedure of B-SSZ-33 molecular sieves in an Al(NO₃)₃ solution. These materials were characterized in detail by various techniques such as X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), thermogravimetric (TG) analysis, inductively coupled plasma-atomic emission spectroscopy (ICP-AES), N₂ adsorption/desorption, temperature programmed desorption of NH₃ (NH₃-TPD), and solid state ²⁷Al nuclear magnetic resonance (²⁷Al NMR). The temperature programmed desorption characteristics of toluene for the B-SSZ-33 and Al-SSZ-33 samples were obtained to understand the efficacy of these materials as hydrocarbon traps. The results show that Al-SSZ-33 with framework Al was obtained after the post-modification procedures. Compared with B-SSZ-33, Al-SSZ-33 has a higher acid strength and shows a comparatively higher toluene desorption temperature (T_max). The presence of extra framework Al and Si species in Al-SSZ-33 modifies its pores and results in a higher desorption end temperature (T_end). Therefore, the synthesized Al-SSZ-33 is a novel catalyst for use as a hydrocarbon trap in automobile tailpipes.
- SSZ-33 molecular sieves,
- Automobile tailpipe,
- Process control method,
- Hydrocarbon trap,
- Temperature programmed desorption
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