Citation: LI Xiang-Hong, DENG Shu-Duan, FU Hui. Inhibition Effect of Nitrotetrazolium Blue Chloride on the Corrosion of Steel in Hydrochloric Acid Solution[J]. Acta Physico-Chimica Sinica, ;2011, 27(12): 2841-2848. doi: 10.3866/PKU.WHXB20112841 shu

Inhibition Effect of Nitrotetrazolium Blue Chloride on the Corrosion of Steel in Hydrochloric Acid Solution

1.
1. Faculty of Science, Southwest Forestry University, Kunming 650224, P. R. China;
2. Faculty of Materials Engineering, Southwest Forestry University, Kunming 650224, P. R. China

Received Date: 19 July 2011
Available Online: 30 September 2011

The inhibition effect of nitrotetrazolium blue chloride (NTBC) on the corrosion of cold rolled steel (CRS) in 1.0-5.0 mol·L^-1 HCl solution was investigated by weight loss method, potentiodynamic polarization curves, electrochemical impedance spectroscopy (EIS), and scanning electron microscopy (SEM). The results show that NTBC is a od inhibitor for CRS in 1.0 mol·L^-1 HCl solution and the adsorption of NTBC on the CRS surface obeys the Langmuir adsorption isotherm. Inhibition efficiency increases with inhibitor concentration while it decreases with hydrochloric acid concentration and temperature. The adsorption thermodynamic parameters (adsorption free energy ΔG⁰, adsorption enthalpy ΔH⁰, adsorption entropy ΔS⁰) and corrosion kinetic parameters (corrosion rate constant k, kinetic reaction constant B) were also calculated. Based on these parameters the inhibitive mechanism is discussed. Potentiodynamic polarization curves show that NTBC acts a mixed-type inhibitor. EIS spectra exhibit one capacitive loop at high frequency and this is followed by a small inductive loop at low frequency, and the charge transfer resistance increases with inhibitor concentrations. SEM clearly shows that the addition of NTBC can drastically retard the corrosion of steel in hydrochloric acid media.
- Corrosion inhibitor,
- Nitrotetrazolium blue chloride,
- Steel,
- Hydrochloric acid,
- Adsorption
1. [1]
  (1) Trabanelli, G. Corrosion 1991, 47, 410.
2. [2]
  (2) Bentiss, F.; Traisnel, M.; Gengembre, L.; Lagrenée, M. Appl. Surf. Sci. 2000, 161, 194.
3. [3]
  (3) Granese, S. L.; Rosales, B. M.; Oviedo, C.; Zerbino, J. O. Corros Sci. 1992, 33, 1439.
4. [4]
  (4) Kertit, S.; Hammouti, B. Appl. Surf. Sci. 1996, 93, 59.
5. [5]
  (5) Bensajjay, E.; Alehyen, S.; Achouri, M. E.; Kertit, S. Anti-Corros. Meth. Mater. 2003, 50, 402.
6. [6]
  (6) Morales-Gil, P.; Negrón-Silva, G.; Romero-Romoa, M.; ángeles-Chávez, C.; Palomar-Pardavé, M. Electrochim. Acta 2004, 49, 4733.
7. [7]
  (7) Li, X. H.; Deng, S. D.; Fu, H. Chin. J. Appl. Chem. 2009, 26, 1075. [李向红, 邓书端, 付惠. 应用化学, 2009, 26, 1075.]
8. [8]
  (8) Li, X. H.; Deng, S. D.; Fu, H. Corrosion Sci. 2009, 51, 1344.
9. [9]
  (9) Li, X. H.; Deng, S. D.; Fu, H. Mater. Chem. Phys. 2009, 115, 815.
10. [10]
  (10) Li, X. H.; Deng, S. D.; Fu, H. Corrosion Sci. 2010, 52, 2786.
11. [11]
  (11) Sekine, I.; Hirakawa, Y. Corrosion 1986, 42, 272.
12. [12]
  (12) Mu, G. N.; Li, X. H.; Qu, Q.; Zhou, J. Corrosion Sci. 2006, 48, 445.
13. [13]
  (13) Cano, E.; Polo, J. L.; Iglesia, A. L.; Bastidas, J. M. Adsorption 2004, 10, 219.
14. [14]
  (14) Wang, F. P.; Kang,W. L.; Jin, H. M. Corrosion Electrochemistry Mechanism, Methods and Applications; Chemical Industrial Engineering Press: Beijing, 2008; p 242. [王凤平, 康万利, 敬和民. 腐蚀电化学原理、方法及应用. 北京: 化学工业出版社, 2008: 242.]
15. [15]
  (15) Zhang, S. T.; Tao, Z. H.; Liao, S. G.;Wu, F. J. Corrosion Sci. 2010, 52, 3126.
16. [16]
  (16) Mathur, P. B.; Vasudevan, T. Corrosion 1982, 38, 171.
17. [17]
  (17) Cao, C. Corrosion Sci. 1996, 38, 2073.
18. [18]
  (18) Labjar, N.; Lebrini, M.; Bentiss, F.; Chihib, N. E.; El Hajjaji, S.; Jama, C. Mater. Chem. Phys. 2010, 119, 330.
19. [19]
  (19) Lenderink, H. J.W.; Linden, M. V. D.; DeWit, J. H.W. Electrochim. Acta 1993, 38, 1989.
20. [20]
  (20) Veloz, M. A.; n?alez, I. Electrochim. Acta 2002, 48, 135.
21. [21]
  (21) Amin, M. A.; Abd El-Rehim, S. S.; El-Sherbini, E. E. F.; Bayyomi, R. S. Electrochim. Acta 2007, 52, 3588.
22. [22]
  (22) Zhang, Q. B.; Hua, Y. X. Mater. Chem. Phys. 2010, 119, 57.
23. [23]
  (23) Singh, A. K.; Quraishi, M.A. Corrosion Sci. 2010, 52, 152.
24. [24]
  (24) Lebrini, M.; Lagrenée, M.; Vezin, H.; Traisnel, M.; Bentiss, F. Corros. Sci. 2007, 49, 2254.
25. [25]
  (25) Priya, A. R. S.; Muralidharam, V. S.; Subramania, A. Corrosion 2008, 64, 541.
26. [26]
  (26) Bommersbach, P.; Alemany-Dumont, C.; Millet, J. P.; Normand, B. Electrochim. Acta 2006, 51, 4011.
27. [27]
  (27) Qu, Q.; Hao, Z. Z.; Li, L.; Bai,W.; Liu, Y. J.; Ding, Z. T. Corrosion Sci. 2009, 51, 569.
28. [28]
  (28) Lagrenée, M.; Mernari, B.; Bouanis, M.; Traisnel, M.; Bentiss, F. Corrosion Sci. 2002, 44, 573.
29. [29]
  (29) Schweinsberg, D. P.; Ashworth, V. Corrosion Sci. 1988, 28, 539.
30. [30]
  (30) Banerjee, G.; Malhotra, S. N. Corrosion 1992, 48, 10.
31. [31]
  (31) Stassen, A.F.; Dova, E.; Ensling, J.; Schenk, H.; Gütlich, P.; Haasnoot, J. G.; Reedijk, J. Inorg. Chim. Acta 2002, 335, 61.
32. [32]
  (32) Hassan, N.;Weinberger, P.; Kubel, F.; Molnar, G.; Bousseksou, A.; Dlhan, L.; Bo?a, R.; Linert,W. Inorg. Chim. Acta 2009, 362, 3629.
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