Citation: GUO Pei-Zhi, JI Qian-Qian, ZHANG Li-Li, ZHAO Shan-Yu, ZHAO Xiu-Song. Preparation and Characterization of Peanut Shell-Based Microporous Carbons as Electrode Materials for Supercapacitors[J]. Acta Physico-Chimica Sinica, ;2011, 27(12): 2836-2840. doi: 10.3866/PKU.WHXB20112836 shu

Preparation and Characterization of Peanut Shell-Based Microporous Carbons as Electrode Materials for Supercapacitors

1.
1. Laboratory of New Fiber Materials and Modern Textile, the Growing Base for State Key Laboratory, School of Chemistry,Chemical Engineering and Environmental Sciences, Qingdao University, Qingdao 266071, Shandong Province,P. R. China;
2. Department of Chemical and Biomolecular Engineering, National University of Singapore,4 Engineering Drive 4, Singapore 117576

Received Date: 18 July 2011
Available Online: 13 October 2011
Fund Project: 国家自然科学基金(20803037, 21143006) (20803037, 21143006) 青岛市应用基础研究项目(11-2-4-2-(8)-jch) (11-2-4-2-(8)-jch)

Microporous carbons (PSC-1 and PSC-2) were obtained directly by the carbonization of peanut shells without and with NaOH solution pretreatment, respectively. Both samples have a main pore size of ~0.8 nm. The surface area increases from 552 m²·g^-1 for PSC-1 to 726 m²·g^-1 for PSC-2. Cyclic voltammograms (CVs) of the PSC-1 and PSC-2 electrodes and the symmetrical supercapacitors show almost rectangular shape indicating excellent capacitance features. The specific capacitances of PSC-1 and PSC-2 can reach 233 and 378 F·g^-1, respectively, at a current density of 0.1 A·g^-1 in a three-electrode system using porous carbon as the working electrode, a platinum electrode as the counter electrode and a Ag/AgCl electrode as the reference electrode. Furthermore, the electrodes in both three-electrode systems and supercapacitors show high stability and capacitance retainability after 1000 cycles. The formation mechanisms for the two microporous carbons and the relationship between the carbon materials and their electrochemical properties are discussed based on the experimental results.
- Supercapacitor,
- Electrode,
- Microporous carbon,
- Peanut shell,
- Capacitance
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