Citation: DONG Zhi-Long, DING Wei, LIU Kun, ZHANG Zhi-Wei, QU Guang-Miao, YU Tao. Adsorption Performance of Tetradecyl Aryl Sulfonates on Oil Sand from the Daqing Oilfield[J]. Acta Physico-Chimica Sinica, ;2011, 27(12): 2767-2772. doi: 10.3866/PKU.WHXB20112767 shu

Adsorption Performance of Tetradecyl Aryl Sulfonates on Oil Sand from the Daqing Oilfield

1.
Chemistry and Chemical Engineering School, Northeast University of Petroleum, Daqing 163318,Helongjiang Province, P. R. China

Received Date: 19 July 2011
Available Online: 20 September 2011
Fund Project: 国家重大科技专项基金(2008ZX05011) (2008ZX05011)国家重点基础研究发展规划项目(973) (2005CB221300) (973) (2005CB221300)黑龙江省研究生创新科研项目(YJSCX2008-044HLJ)资助 (YJSCX2008-044HLJ)

Three tetradecyl aryl sulfonates of high purity were synthesized. Their static adsorption performance on oil sand from the Daqing oilfield was studied and the influence of adsorption time, adsorption temperature, concentrations of sulfonate, NaCl, NaOH, and n-butyl alcohol on the efficiency of adsorption were investigated. The experimental results show that with an increase in the concentrations of the sulfonates the adsorption capacity initially increased and then remained constant. The adsorption capacity increased with the addition of NaCl and NaOH while it decreased with the addition of n-butyl alcohol and the increase of temperature. In the structural isomer, upon moving the aryl from the terminal to the center of the long alkyl chain, the adsorption capacity decreased and the impact of the additive was reduced. Thermodynamic results show that the adsorption of tetradecyl aryl sulfonates onto oil sand could be well described by the Langmuir isotherm. The constants of each equation were calculated from the experimental data and indicated the characteristics of oil sand adsorption. The dynamic results showed that the adsorption capacity changing with time as described by the Elovich equation.
- Alkyl aryl sulfonate,
- Additive,
- Solid/liquid adsorption,
- Adsorption thermodynamics,
- Adsorption dynamics
1. [1]
  (1) Yu, F.; Fan,W. Y.; Duan, Y. Z.; Li, S. P.; Nan, G. Z. Oilfield Chemistry 2007, 24, 347. [于芳, 范维玉, 段友智, 李水平, 南国枝. 油田化学, 2007, 24, 347.]
2. [2]
  (2) Jiang, X. M.; Zhang, L.; An, J. Y.; Zhao, S.; Yu, J. Y. Acta Phys. - Chim. Sin. 2005, 21, 1426. [姜小明, 张路, 安静仪, 赵濉, 俞稼镛. 物理化学学报, 2005, 21, 1426.]
3. [3]
  (3) Zhao, Y. Synthesis and Interfacial Properties of Pure Alkylbenzenesulfonates. Ph. D. Dissertation, Dalian University of Technology, Dalian, 2006. [赵宇. 系列烷基苯磺酸盐纯化合物的合成及界面性能的研究[D]. 大连: 大连理工大学, 2006.]
4. [4]
  (4) Yu, T.; Liu, H. J.; Ding,W.; Qu, G. M.; Guo, S. J. Chinese Journal of Applied Chemistry 2008, 25, 1107. [于涛, 刘红娟, 丁伟, 曲广淼, 国胜娟. 应用化学, 2008, 25, 1107.]
5. [5]
  (5) Wang, L.; ng, Q. T.;Wang, D. X.; Zhao, S.; An, J. Y.; Yu, J. Y. Petrochem Ican Tech 2004, 33, 104. [王琳, 宫清涛, 王东贤, 赵濉, 安静仪, 俞稼镛. 石油化工, 2004, 33, 104.]
6. [6]
  (6) ng, Q. T.; Jiang, X. M.;Wang, L.; Zhao, J. S.;Wang, D. X.; Zhang, L.; Zhao, S.; Yu, J. Y. Petrochem Ican Tech 2005, 34, 122. [宫清涛, 姜小明, 王琳, 赵金生, 王东贤, 张路, 赵濉, 俞稼镛. 石油化工, 2005, 34, 122.]
7. [7]
  (7) Jiang, X. M.; Xu, Z. C.; Shi, F. Q.; An, J. Y.; Zhao, S.; Yu, J. Y. Fine Chemistry 2004, 21, 808. [姜小明, 徐志成, 史福强, 安静仪, 赵濉, 俞稼镛. 精细化工, 2004, 21, 808.]
8. [8]
  (8) Zhang, S. B.; Qi, H. M.; Zhang, H.; Qiao,W. H.; Li, Z. S. Journal of Dalian Nationalities University 2005, 7, 15. [张树彪, 齐会勉, 张晗, 乔卫红, 李宗石. 大连民族学院学报, 2005, 7, 15.]
9. [9]
  (9) Li, Z. G.; Qiao,W. H.; Li, Z. S.;Wang, X. N. Journal of Dalian University of Technology 2002, 42, 531. [李志刚, 乔卫红, 李宗石, 王秀娜. 大连理工大学学报, 2002, 42, 531.]
10. [10]
  (10) Doe, P. H.; Emary, M. E. L.;Wade,W. H. J. Am. Oil Chem. Soc. 1978, 55, 505.
11. [11]
  (11) Dahanayake, M. D.; Coben, A.W.; Rosen, M. J. Phys. Chem. 1986, 90, 2413.
12. [12]
  (12) Hevalier, Y. Current Opinion in Colloids and Interface Science 2002, 7, 3.
13. [13]
  (13) Keisuke, M.; Yoshikiyo, M. Current Opinion in Colloid and Interface Science 2003, 8, 227.
14. [14]
  (14) Aksenenko, E. V.; Makievski, A. V.; Miller, R.; Fainerman, V. B. Colloids and Surfaces A: Physicochemical and Engineering Aspects 1998, 143, 311.
15. [15]
  (15) Shan, C. L.; Zong, L. P.; Xu, Y. S.; Chen, J.;Wu, X. L. China Foreign Energy 2006, 11, 45. [单存龙, 宗丽平, 徐艳姝, 陈劼, 伍晓林. 中外能源, 2006, 11, 45.]
16. [16]
  (16) Peltonen, L. J.; Yliruusi, J. J. Colloids Interface Sci. 2000, 227, 1.
17. [17]
  (17) Lorenzo, M. D.; Vinagre, H. M.; Joseph, D. D. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2001, 180, 121.
18. [18]
  (18) Ding,W.;Wang, R.; Yu, T.; Qu, G. M.;Wen, H. Y. Acta Petrolet. Sin. 2007, 23, 75. [丁伟, 王瑞, 于涛, 曲广淼, 温海飞. 石油学报, 2007, 23, 75.]
19. [19]
  (19) Qu, G. M.; Cheng, J. C.; Ding,W.; Yu, T.; Li, G. Q. Acta Petrolet Sinica (Petroleum Processing Section) 2010, 26, 208. [曲广淼, 程杰成, 丁伟, 于涛, 李国桥. 石油学报 (石油加工), 2010, 26, 208.]
20. [20]
  (20) Cross, J. Marcal Dekker 1998, 45.
21. [21]
  (21) Shinoda, K.; Masakata, H. J. Phys. Chem. 1973, 77, 378.
22. [22]
  (22) Zhao, G. X.; Zhu, B. Y. Principles of Surfactant Action; Beijing, 2003. [赵国玺, 朱瑶. 表面活性剂作用原理. 北京: 中国轻工业出版社, 2003.]
23. [23]
  (23) Yu, T.; Tong,W.; Su, Y. B.; Ding,W. Chinese Journal of Applied Chemistry 2010, 27, 466. [于涛, 童维, 宿雅彬, 丁伟. 应用化学, 2010, 27, 466.]
24. [24]
  (24) Zhao, G. Y.; Qin, Q.; Zhou, Q. Environmental Science and Technology 2006, 29, 84. [赵桂瑜, 秦琴, 周琪. 环境科学与技术, 2006, 29, 84.]
25. [25]
  (25) Tu, C. Tropical and Subtropical Soil Science 1994, 3, 175. [涂从. 热带亚热带土壤科学, 1994, 3, 175.]
26. [26]
  (26) Yao, T. Y.; Yao, F. Y.; Li, J. S. Oil Drilling & Production Technology 2008, 30, 82. [姚同玉, 姚风英, 李继山. 石油钻采工艺, 2008, 30, 82.]
27. [27]
  (27) Xiao, J. X.; Zhao, Z. G. Application Principle of Surfactant; Chemical Industry Press: Beijing, 2002; pp 93-97. [肖进新, 赵振国. 表面活性剂应用原理. 北京: 化学工业出版社, 2002: 93-97.]
28. [28]
  (28) Wang, P. Y.; Xu, B. C.;Wang, J. The Synthes, Property and Use of Surfactants; Chemical Industry Press: Beijing, 2007; pp 174-179. [王培义, 徐宝才, 王军. 表面活性剂——合成· 性能·应用. 北京: 化学工业出版社, 2007: 174-179.]
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