Citation: ZHAO Rong-Jiao, HE Jin-Long, LI Jing, GUO Chang-Sheng, DU Yong, HONG Zhi. Terahertz Time-Domain Spectroscopy of L- and DL-Fudosteine[J]. Acta Physico-Chimica Sinica, ;2011, 27(12): 2743-2748. doi: 10.3866/PKU.WHXB20112743
-
The absorption spectra of L- and DL-Fudosteine were measured using terahertz time-domain (THz-TDS) system at room temperature. Experimental results show that L- and DL-Fudosteine both have distinct fingerprint spectra in the THz region and their characteristics are different from each other. The absorption frequencies for the vibration and rotation of Fudosteine in the THz spectral range were simulated and the results are consistent with the experimental results. We also interpret the origin of the absorption peaks using a simulation. Finally, the absorption spectra of the Fudosteine capsule, pure L-Fudosteine and DL- Fudosteine are compared. The results verify that the main component of the capsule is L-Fudosteine. This study provides a reference for the analysis of the main ingredients of compounds.
-
-
[1]
(1) Xu, J. Z.; Zhang, X. C. Technology and Applications of Terahertz Wave; Peking University Press: Beijing, 2007; pp 1-5. [许景周, 张希成. 太赫兹科学技术和应用. 北京: 北京大学出版社, 2007: 1-5.]
-
[2]
(2) Li, J. R.; Li, J. S. Journal of the Chinese Cereals and Oils Association 2010, 25 (3), 112. [李建蕊, 李九生. 中国粮油学报, 2010, 25 (3), 112.]
-
[3]
(3) Siegel, P.H. IEEE Transactions on Microwave Theory and Techniques 2004, 52 (10), 2438.
-
[4]
(4) Walther, M.; Fischer, B.; Schall, M.; Helm, H.; Jepsen, P. U. Chem. Phys. Lett. 2000, 332, 389.
-
[5]
(5) Yamaguchi, M.; Miyamaru, F.; Yamamoto, K.; Tani, M.; Hangyo, M. Appl. Phys. Lett. 2005, 86 (5), 053903.
-
[6]
(6) Wang,W. N.; Yue,W.W.; Yan, H. T.; Zhang, C. L.; Zhao, G. Z. Chinese Science Bulletin 2005, 50 (15), 1561.
-
[7]
(7) Shi, Y. L.;Wang, L. J. Phys. D-Appl. Phys. 2005, 38, 3741.
-
[8]
(8) Ge, M.; Zhao, H.W.; Ji, T.; Yu, X. H.;Wang,W. F.; Li,W. X. Sci. China Ser. B- Chem. 2005, 35 (6), 441. [葛敏, 赵红卫, 吉特, 余笑寒, 王文锋, 李文新. 中国科学B辑: 化学, 2005, 35 (6), 441.]
-
[9]
(9) Gi, T.; Zhao, H.W.; Zhang, Z.Y.; Ge, M.;Wang,W. F.; Yu, X. H.; Xu, H. J. Acta Phys. -Chim. Sin. 2006, 22, 1159. [吉特, 赵红卫, 张增艳, 葛敏, 王文锋, 余笑寒. 徐洪杰. 物理化学学报, 2006, 22, 1159.]
-
[10]
(10) Xu, H.; Yu, X. H.; Zhang, Z. Y.; Han, J. G.; Li, Q. N.; Zhu, Z. Y.; Li,W. X. Journal of the Graduate School of the Chinese Academy of Sciences 2005, 22, 90. [徐慧, 余笑寒, 张增燕, 韩家广, 李晴暖, 朱志远, 李文新. 中国科学院研究生院学报, 2005, 22, 90.]
-
[11]
(11) Zhang, L.; Yao, T.W.; Zeng, S. Chinese Journal of Modern Applied Pharmacy 1999, 16 (2), 4. [章立, 姚彤炜, 曾苏. 中国现代应用药学杂志, 1999, 16 (2), 4.]
-
[12]
(12) Takahashi, K.; Kai, H.; Mizuno, H.; Koda, T.; Miyata, T. J. Pham. Phamacol 2001, 53 (6), 911.
-
[13]
(13) Wang, Y. J.; Liu, F. J. Tianjin Pharmacy 2006, 18 (5), 73. [王亚江, 刘福景. 天津药学, 2006, 18 (5), 73.]
-
[14]
(14) Timothy, D. D.; Richard, G. B.; Daniel, M. M. J. Opt. Soc. Am. A 2001, 18 (7), 1562.
-
[15]
(15) Duvillaret, L.; Garet, F.; Coutaz, J. L. IEEE J. Sel. Top. Quant 1996, 2 (3), 739.
-
[16]
(16) Markelz, A. G.; Roitberg, A.; Heilweil, E. J. Chem. Phys. Lett. 2000, 320, 42.
- [17]
- [18]
- [19]
-
[20]
(20) Anthony, P. S.; Leo, R. J. Chem. Phys. Lett. 1996, 100, 16502.
-
[21]
(21) Halls, M. D.; Velkovski, J.; Schlegel, H. B. Theor. Chem. Acc. 2001, 105, 413.
-
[22]
(22) Liu, J. Y.;Wu, S. B. Chemical Graphic Design and Molecular Calculations; South China Science and Technology University Press: Guangzhou, 2009; pp 253-256. [刘江燕, 武书彬. 化学图文设计与分子模拟计算. 广州: 华南理工大学出版社, 2009: 253-256.]
-
[23]
(23) Wong, M. Chem. Phys. Lett. 1996, 256, 391.
-
[24]
(24) Ma, J. L.; Xu, K. J.; Li, Z.; Jin, B. B.; Fu, R.; Zhang , C. H.; Ji, Z. M.; Zhang, C.; Chen, Z. X.; Chen, J.; Wu, P. H. Acta Physica Sinica. 2009, 58 (9), 6101. [马金龙, 徐开俊, 李哲, 金飚兵, 傅荣, 张彩虹, 吉争鸣, 张仓, 陈兆旭, 陈健, 吴培亨. 物理学报, 2009, 58 (9), 6101.]
-
[25]
(25) Takahashi, M.; Ishikawa, Y.; Nishizawa, J.; Hiromasa, I. Chem. Phys. Lett. 2005, 401, 475.
-
[26]
(26) Chen, Y. Q.; Liu, H. B; Zhang, X. C. Proceedings of SPIE 2006, 6212, 62120P-l.
-
[27]
(27) Walther, M.; Plochocka, P.; Fischer, B.; Helm, H.; Uhd, J. P. Biopolymers 2002, 67, 310.
-
[28]
(28) Chen, Y. Q.; Liu, H, B.; Deng, Y. Q.; Schauki, D.; Fitch, M. J.; Osiander, R.; Dodson, C.; Spicer, J. B.; Shur, M.; Zhang, X. C. Chem. Phys. Lett. 2004, 400, 357.
-
[29]
(29) Yu, B.; Zeng, F.; Yang, Y.; Xing, Q.; Chechin, A.; Xin, X.; Zeylikovich, I.; Alfano, R. R. Biophysical Journal 2004, 86, 1649.
-
[1]
-
-
[1]
Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO2 by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
-
[2]
Xiaochen Zhang , Fei Yu , Jie Ma . 多角度数理模拟在电容去离子中的前沿应用. Acta Physico-Chimica Sinica, 2024, 40(11): 2311026-. doi: 10.3866/PKU.WHXB202311026
-
[3]
Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
-
[4]
Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
-
[5]
Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034
-
[6]
Jingyi Chen , Fu Liu , Tiejun Zhu , Kui Cheng . Practice of Integrating Ideological and Political Education into Raman Spectroscopy Analysis Experiment Course. University Chemistry, 2024, 39(2): 140-146. doi: 10.3866/PKU.DXHX202310111
-
[7]
Chun-Lin Sun , Yaole Jiang , Yu Chen , Rongjing Guo , Yongwen Shen , Xinping Hui , Baoxin Zhang , Xiaobo Pan . Construction, Performance Testing, and Practical Applications of a Home-Made Open Fluorescence Spectrometer. University Chemistry, 2024, 39(5): 287-295. doi: 10.3866/PKU.DXHX202311096
-
[8]
Tianlong Zhang , Jiajun Zhou , Hongsheng Tang , Xiaohui Ning , Yan Li , Hua Li . Virtual Simulation Experiment for Laser-Induced Breakdown Spectroscopy (LIBS) Analysis. University Chemistry, 2024, 39(6): 295-302. doi: 10.3866/PKU.DXHX202312049
-
[9]
Wei Peng , Baoying Wen , Huamin Li , Yiru Wang , Jianfeng Li . Exploration and Practice on Raman Scattering Spectroscopy Experimental Teaching. University Chemistry, 2024, 39(8): 230-240. doi: 10.3866/PKU.DXHX202312062
-
[10]
Zhaoyue Lü , Zhehao Chen , Yi Ni , Duanbin Luo , Xianfeng Hong . Multi-Level Teaching Design and Practice Exploration of Raman Spectroscopy Experiment. University Chemistry, 2024, 39(11): 304-312. doi: 10.12461/PKU.DXHX202402047
-
[11]
Hua Hou , Baoshan Wang . Course Ideology and Politics Education in Theoretical and Computational Chemistry. University Chemistry, 2024, 39(2): 307-313. doi: 10.3866/PKU.DXHX202309045
-
[12]
Jia Yao , Xiaogang Peng . Theory of Macroscopic Molecular Systems: Theoretical Framework of the Physical Chemistry Course in the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 27-37. doi: 10.12461/PKU.DXHX202408117
-
[13]
Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
-
[14]
Mengyao Shi , Kangle Su , Qingming Lu , Bin Zhang , Xiaowen Xu . Determination of Potassium Content in Tobacco Stem Ash by Flame Atomic Absorption Spectroscopy. University Chemistry, 2024, 39(10): 255-260. doi: 10.12461/PKU.DXHX202404105
-
[15]
Hongyao Li , Youyan Liu , Luwei Dai , Min Yang , Qihui Wang . The Blessing of Indium Sulfide:Confronting the Narrow Path with Uric Acid. University Chemistry, 2024, 39(5): 325-335. doi: 10.3866/PKU.DXHX202311104
-
[16]
Chengxia Tong , Yajie Li , Jin Yan , Xuejian Qu , Shigang Wei , Yong Fan , Zhiguang Song , Yupeng Guo . The Construction and Practice of a Comprehensive and Three-Dimensional Practical Education Model. University Chemistry, 2024, 39(7): 49-55. doi: 10.12461/PKU.DXHX202404155
-
[17]
Junlin Yan , Changhao Wang , Quanguo Zhai , Chenghui Liu , Dong Xue . A New Construction Model and Practice of Demonstration Center for Experimental Chemistry Education. University Chemistry, 2024, 39(7): 64-68. doi: 10.12461/PKU.DXHX202405005
-
[18]
Weizhou Jiao , Zhiwei Liu , Chao Zhang , Zhiguo Yuan , Guisheng Qi , Jing Gao . Construction and Implementation of a Mode of Chemical Talent Training Driven by Practice and Innovation Ability. University Chemistry, 2024, 39(7): 76-81. doi: 10.12461/PKU.DXHX202405011
-
[19]
Yecang Tang , Shan Ling , Zhen Fang . Exploration of a Hierarchical and Integration-Oriented Talent Training Model in the Demonstration Center for Experimental Chemistry Education. University Chemistry, 2024, 39(7): 188-192. doi: 10.12461/PKU.DXHX202405107
-
[20]
Xu Liu , Chengfang Liu , Jie Huang , Xiangchun Li , Wenyong Lai . Research on the Application of Diversified Teaching Models in the Teaching of Physical Chemistry. University Chemistry, 2024, 39(8): 112-118. doi: 10.3866/PKU.DXHX202402021
-
[1]
Metrics
- PDF Downloads(748)
- Abstract views(3480)
- HTML views(112)