Citation: WU Qi, SU Yu-Feng, SUN Lan, WANG Meng-Ye, WANG Ying-Ying, LIN Chang-Jian. Preparation and Visible Light Photocatalytic Activity of Fe-N Codoped TiO₂ Nanotube Arrays[J]. Acta Physico-Chimica Sinica, ;2012, 28(03): 635-640. doi: 10.3866/PKU.WHXB201112231 shu

Preparation and Visible Light Photocatalytic Activity of Fe-N Codoped TiO₂ Nanotube Arrays

1.
Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received Date: 14 November 2011
Available Online: 23 December 2011
Fund Project: 国家自然科学基金(51072170, 21021002) (51072170, 21021002) 福建省自然科学基金(2011J01057) (2011J01057)国家基础科学人才培养基金(J1030415)资助项目 (J1030415)

Fe-N codoped TiO₂ nanotube arrays were fabricated by anodization of Ti, followed by wet immersion and annealing post-treatment. The doped TiO₂ nanotube array photocatalysts were characterized by field-emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Auger electron spectroscopy (AES). The results indicated that Fe and N dopants had almost no effect on the morphology and structure of TiO₂ nanotube arrays, and that Fe and N were doped into the TiO₂ lattice. UV-Vis diffuse reflectance spectra showed that the absorption band edge of Fe-N codoped TiO₂ nanotube arrays exhibited a red shift compared with that of pure TiO₂ nanotube arrays and Fe- or N-doped TiO₂ nanotube arrays. The photocatalytic activity of Fe-N codoped TiO₂ nanotube arrays was evaluated by their ability to degrade rhodamine B under visible light irradiation. The degradation rate of rhodamine B over Fe-N codoped TiO₂ nanotube arrays was obviously higher than that over pure TiO₂ nanotube arrays and Fe- or N-doped TiO₂ nanotube arrays, which is attributed to the synergistic effect of the Fe and N codopants.
- Fe and N,
- Codoping,
- TiO₂ nanotube array,
- Rhodamine B,
- Visible light
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Visible Light Photocatalytic Activity of Fe-N Codoped TiO2 Nanotube Arrays

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通讯作者: 陈斌, bchen63@163.com

Preparation and Visible Light Photocatalytic Activity of Fe-N Codoped TiO₂ Nanotube Arrays