Citation: LIU Jing-Ru, XU Jie, DONG Hong-Chao, YU Qiang. Effect of Hyperbranched Polyester on the Non-Isothermal Crystallization Behavior of Polyethylene Glycol[J]. Acta Physico-Chimica Sinica, ;2012, 28(03): 528-535. doi: 10.3866/PKU.WHXB201112202 shu

Effect of Hyperbranched Polyester on the Non-Isothermal Crystallization Behavior of Polyethylene Glycol

1.
School of Materials Science and Engineering, Changzhou University, Changzhou 213164, Jiangsu Province, P. R. China

Received Date: 20 October 2011
Available Online: 20 December 2011
Fund Project: 国家自然科学基金(20674032)资助项目 (20674032)

The effect of hyperbranched polyester (HBP) on the non-isothermal crystallization behavior of polyethylene glycol (PEG) was studied by differential scanning calorimetry (DSC), polarizing microscopy (POM), and Fourier transform infrared (FTIR) spectroscopy. The non-isothermal crystallization data for PEG and HBP/PEG were analyzed by the Ozawa, Jeziorny, and Mo Zhi-Shen methods. The results indicate that the non-isothermal crystallization processes of PEG and HBP/PEG may be described using the kinetic equations of Ozawa and Mo, but do not agree with the Jeziorny equation. The addition of HBP affected the crystallization process and crystal form of pure PEG, and slowed the rate of crystallization. The hydrogen bond formed between the carbonyl group of HBP and the terminated-hydroxyl group of PEG, and the larger size and highly branched structure of HBP are the main reasons for the slower crystallization.
- Polyethylene glycol,
- Non-isothermal crystallization,
- Hyperbranched polyester,
- Differential scanning calorimetry
1. [1]
  (1) Wang,W.; Shang, B. K.; Hu, S. Q.; Li, J. Chem. Propel. Polymer. Mater. 2004, 2 (5), 39. [王伟, 尚丙坤, 胡少强, 李洁. 化学推进剂与高分子材料, 2004, 2 (5), 39.]
2. [2]
  (2) Chen, F. T.; Duo, Y. Q.; Luo, S. G.; Luo, Y. J.; Tan, H. M. Propel. Explos. Pyrotech. 2003, 28 (1), 7.
3. [3]
  (3) Zhang, X. P.; Zhao, X. B.; Du, L.; Zheng, J. Acta Polym. Sin. 2004, No. 3, 388. [张小平, 赵孝彬, 杜磊, 郑剑. 高分子学报, 2004, No. 3, 388.]
4. [4]
  (4) Byoung, S. M. Propel. Explos. Pyrotech. 2008, 33 (2), 131.
5. [5]
  (5) Zhao, X. B.; Zhang, X. P.; Zheng, J.; Du, L. J. Propul. Technol. 2002, 23 (3), 252. [赵孝彬, 张小平, 郑剑, 杜磊. 推进技术, 2002, 23 (3), 252.]
6. [6]
  (6) Jian, X. X.; Xiao, L. Q.; Zhou,W. L.; Xu, F. M. J. Solid Rocket Technol. 2008, 31 (4), 377. [菅晓霞, 肖乐勤, 周伟良, 徐复铭. 固体火箭技术, 2008, 31 (4), 377.]
7. [7]
  (7) Liu, J. R.; Song, X. J.; Yang, Y. J. Solid Rocket Technol. 2010, 33 (1), 72. [刘晶如, 宋雪晶, 杨寅. 固体火箭技术, 2010, 33 (1), 72.]
8. [8]
  (8) Gao, C.; Yan, D. Y. Prog. Polym. Sci. 2004, 29 (3), 183.
9. [9]
  (9) Vukovic, J.; Steinmeier, D.; Lechner, M. D.; Jovanovic, S.; Bozic, B. Polym. Degrad. Stab. 2006, 91 (8), 1903.
10. [10]
  (10) Zagar, E.; Huskic, M.; Zi n, M. Macromol. Chem. Phys. 2007, 208 (13), 1379.
11. [11]
  (11) Dodds, J. M.; Luca, E. D.; Hutchings, L. R.; Clarke, N. J. Polym. Sci. Part B-Polym. Phys. 2007, 45 (19), 2762.
12. [12]
  (12) Jena, K. K.; Raju, K. V.; Prathab, B.; Aminabhavi, T. M. J. Phys. Chem. B 2007, 111 (30), 8801.
13. [13]
  (13) Fu, Q.; Liu, J. H.; Shi,W. F. Prog. Org. Coat. 2008, 63 (1), 100.
14. [14]
  (14) Ikladious, N. E.; Mansour, S. H.; Rozik, N. N.; Rozik, N. N.; Dirnberger, K.; Eisenbach, C. D. J. Polym. Sci. Part A-Polym. Chem. 2008, 46 (16), 5568.
15. [15]
  (15) Zhang, X. L. Polym. Int. 2011, 60 (2), 153.
16. [16]
  (16) Zagar, E.; Zi n, M. Prog. Polym. Sci. 2011, 36 (1), 53.
17. [17]
  (17) Tan, H. M.; Luo, Y. J. Hyperbranched Polymers; Chemical Industry Press: Beijing, 2005; pp 1-16. [谭惠民, 罗运军. 超支化聚合物. 北京: 化学工业出版社, 2005: 1-16.]
18. [18]
  (18) Liu, J. R.; Chao, L. L.; Yu, Q.; Zhu, M. B.; Gu, C. M. Spectrosc. Spectral. Anal. 2011, 31 (4), 983. [刘晶如, 巢玲玲, 俞强, 朱梦冰, 顾春苗. 光谱学与光谱分析, 2011, 31 (4), 983.]
19. [19]
  (19) Ozawa, T. Polymer 1971, 12 (3), 150.
20. [20]
  (20) Jeziorny, A. Polymer 1978, 19 (10), 1142.
21. [21]
  (21) Liu, J. P.; Mo, Z. S.; Qi, Y. C.; Zhang, H. F.; Chen, D. L. Acta Polym. Sin. 1993, No. 1, 1. [刘结平, 莫志深, 綦玉臣, 张宏放, 陈东霖. 高分子学报, 1993, No. 1, 1.]
22. [22]
  (22) Ren, M. Q.; Mo, Z. S.; Chen, Q. Y.; Zhang, H. F.; Song, J. B.; Zhang, H. L.; Sun, X. H. Acta Polym. Sin. 2005, No. 3, 374. [任敏巧, 莫志深, 陈庆勇, 张宏放, 宋剑斌, 张会良, 孙小红. 高分子学报, 2005, No. 3, 374.]
23. [23]
  (23) Mo, Z. S. Acta Polym. Sin. 2008, No. 7, 656. [莫志深. 高分子学报, 2008, No. 7, 656.]
24. [24]
  (24) Bian, J.; Ye, S. R.; Feng, L. X. Chem. J. Chin. Univ. 2000, 21 (9), 1481. [边界, 叶胜荣, 封麟先. 高等学校化学学报, 2000, 21 (9), 1481.]
25. [25]
  (25) Liu, J. R.; Yu, Q.; Chen, K. J.; Xie, L. J. Chem. Eng. Chin. Univ. 2011, 25 (3), 447. [刘晶如, 俞强, 陈科军, 谢磊. 高校化学工程学报, 2011, 25 (3), 447.]
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